金属热处理 ›› 2025, Vol. 50 ›› Issue (6): 102-106.DOI: 10.13251/j.issn.0254-6051.2025.06.016

• 组织与性能 • 上一篇    下一篇

N06625合金750 ℃长期时效后的组织与性能

欧新哲1,2, 马天军1   

  1. 1.宝武特种冶金有限公司, 上海 200940;
    2.核电关键材料全国重点实验室, 上海 200940
  • 收稿日期:2025-01-27 修回日期:2025-04-11 出版日期:2025-06-25 发布日期:2025-07-08
  • 作者简介:欧新哲(1981—),男,高级工程师,硕士,主要研究方向为特种不锈钢、镍基耐蚀合金新材料开发,E-mail: ouxinzhe@baosteel.com

Microstructure and properties of N06625 alloy after long-term aging at 750 ℃

Ou Xinzhe1,2, Ma Tianjun1   

  1. 1. Baowu Special Metallurgy Co., Ltd., Shanghai 200940, China;
    2. State Key Laboratory of Materials for Advanced Nuclear Energy, Shanghai 200940, China
  • Received:2025-01-27 Revised:2025-04-11 Online:2025-06-25 Published:2025-07-08

摘要: 研究了经1150 ℃×40 min固溶处理后的N06625合金无缝管材在750 ℃长期时效后的组织和性能变化。结果表明,750 ℃长期时效过程中,N06625合金晶粒尺寸变化不大,M23C6碳化物主要沿晶界析出,针状δ相优先在晶界和孪晶界析出,随后逐步布满整个晶内,且最终形成魏氏体状的δ相。在0~3000 h时效时间内,室温冲击性能降低比较明显而硬度增加较快,但随着时效时间的继续增加,室温冲击性能和硬度均趋于稳定。长期时效过程中,N06625合金室温冲击断裂模式由韧性断裂向脆性断裂转变,魏氏体状δ相的大量析出是影响室温冲击性能的主要因素。试验N06625合金管材750 ℃、10万小时的外推持久强度达到88.036 MPa,满足高温气冷堆的工程设计要求。

关键词: N06625合金, 组织, 性能, 长期时效

Abstract: Microstructural and property changes of N06625 alloy seamless tube after solution treatment at 1150 ℃ for 40 min and long-term aging at 750 ℃ were investigated. The results show that during long-term aging at 750 ℃, the grain size of the N06625 alloy remains relatively stable, M23C6 carbides primarily precipitate along the grain boundaries, while the needle-like δ-phase preferentially forms at the grain boundaries and twin boundaries, subsequently spreading throughout the grain interior, and eventually forming a Widmanstätten-like δ-phase structure. Within the aging time range of 0-3000 h, the room-temperature impact property decreases significantly, while the hardness increases rapidly. However, as the aging time continues to increase, both the room-temperature impact property and hardness tend to stabilize. During long-term aging, the room-temperature impact fracture mechanism of the N06625 alloy changes from ductile fracture to brittle fracture. The extensive precipitation of Widmanstatten-like δ-phase is identified as the primary factor influencing the room-temperature impact property. The N06625 alloy tube exhibits an extrapolated creep strength of 88.036 MPa at 750 ℃ for 100 000 h, satisfying the engineering design requirements of high-temperature gas-cooled reactor.

Key words: N06625 alloy, microstructure, properties, long-term aging

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