金属热处理 ›› 2025, Vol. 50 ›› Issue (6): 139-144.DOI: 10.13251/j.issn.0254-6051.2025.06.022

• 工艺研究 • 上一篇    下一篇

固溶温度对Cu-Cr-Zr合金组织与性能的影响

花思明1,2   

  1. 1.中国铁建电气化局集团有限公司, 北京 100043;
    2.中铁建电气化局集团康远新材料有限公司, 江苏 靖江 214500
  • 收稿日期:2024-12-29 修回日期:2025-03-15 出版日期:2025-06-25 发布日期:2025-07-08
  • 作者简介:花思明(1987—),男,高级工程师,博士,主要研究方向为高性能铜合金,E-mail:huasiming1987@126.com
  • 基金资助:
    中国铁建股份有限公司科技重大专项(2023-Z01)

Effect of solution temperature on microstructure and properties of Cu-Cr-Zr alloy

Hua Siming1,2   

  1. 1. China Railway Construction Electrification Bureau Group Co., Ltd., Beijing 100043, China;
    2. China Railway Construction Electrification Bureau Group Kangyuan New Material Co., Ltd., Jingjiang Jiangsu 214500, China
  • Received:2024-12-29 Revised:2025-03-15 Online:2025-06-25 Published:2025-07-08

摘要: 采用气氛保护上引连铸法制备Cu-0.8Cr-0.08Zr合金杆坯,并对其在室温进行变形量49%的拉拔。借助金相显微镜、能谱仪、涡流导电仪和硬度计,研究了固溶温度(700~980 ℃)对铸态及冷拉态Cu-0.8Cr-0.08Zr合金微观组织、硬度和导电率的影响。结果表明,随固溶温度升高,铸态Cu-0.8Cr-0.08Zr合金树枝状晶粒逐渐消失,晶粒尺寸变大。冷拉态Cu-0.8Cr-0.08Zr合金纤维状晶粒逐渐消失,出现大量孪晶。铸态和冷拉态Cu-0.8Cr-0.08Zr合金的硬度均先急剧下降后趋于平缓,导电率先下降后升高。铸态Cu-0.8Cr-0.08Zr合金的最佳固溶处理工艺为940 ℃保温1 h,硬度为58 HBW,导电率为52%IACS。冷拉态Cu-0.8Cr-0.08Zr合金的最佳固溶处理工艺为920~960 ℃保温1 h,硬度约为56 HBW,导电率约为55%IACS。

关键词: Cu-Cr-Zr合金, 固溶温度, 微观组织, 硬度, 导电率

Abstract: Cu-0.8Cr-0.08Zr copper alloy was prepared by upward continuous casting method with atmosphere protection, and drawing with deformation amount of 49% at room temperature was carried out on the alloy. The effect of solution temperature on microstructure, hardness, and conductivity of the Cu-0.8Cr-0.08Zr copper alloy was studied by means of metallographic microscopy, energy dispersive spectroscopy, eddy current conductivity meter, and hardness tester. The results show that with the increase of solution temperature, the dendritic grains of the as-cast Cu-0.8Cr-0.08Zr alloy gradually disappear, and the grain size increases. The fibrous grains of the cold-drawn Cu-0.8Cr-0.08Zr alloy gradually vanish, and a large number of twins appear. The hardness of both the as-cast and cold-drawn Cu-0.8Cr-0.08Zr alloys decreases sharply at first and then levels off, while the electrical conductivity first decreases and then increases. The optimal solution treatment process for the as-cast Cu-0.8Cr-0.08Zr alloy is to hold at 940 ℃ for 1 h, with the hardness of 58 HBW and conductivity of 52%IACS. The optimal solution treatment process for the cold-drawn Cu-0.8Cr-0.08Zr alloy is to hold at 920-960 ℃ for 1 h, with the hardness of approximately 56 HBW and conductivity of 55%IACS.

Key words: Cu-Cr-Zr alloy, solution temperature, microstructure, hardness, conductivity

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