固溶温度对冷轧HRX19奥氏体不锈钢组织与力学性能的影响

doi:10.13251/j.issn.0254-6051.2025.12.023

金属热处理 ›› 2025, Vol. 50 ›› Issue (12): 155-160.DOI: 10.13251/j.issn.0254-6051.2025.12.023

固溶温度对冷轧HRX19奥氏体不锈钢组织与力学性能的影响

张继舜¹, 赵吉庆¹, 王建强², 王利伟², 周华贸², 杨钢¹

1.钢铁研究总院有限公司特殊钢研究院, 北京 100081;
2.攀钢集团江油长城特殊钢有限公司, 四川江油 621704

收稿日期:2025-07-09 修回日期:2025-10-12 发布日期:2026-01-06
通讯作者: 赵吉庆,工程师,博士,E-mail: zhaojiqing@nercast.com
作者简介:张继舜(1994—),男,博士,主要研究方向为材料的氢脆,E-mail: jihsun0707@foxmail.com。
基金资助:
国家新材料生产应用示范平台项目(22T60130)

Effect of solution treatment temperature on microstructure and mechanical properties of cold-rolled HRX19 austenitic stainless steel

Zhang Jishun¹, Zhao Jiqing¹, Wang Jianqiang², Wang Liwei², Zhou Huamao², Yang Gang¹

1. Research Institute of Special Steels, Central Iron and Steel Research Institute Co., Ltd., Beijing 100081, China;
2. Jiangyou Changcheng Special Steel Co., Ltd., of Pangang Group, Jiangyou Sichuan 621704, China

Received:2025-07-09 Revised:2025-10-12 Published:2026-01-06

摘要/Abstract

摘要： 通过OM、SEM、TEM等显微表征手段以及拉伸、冲击试验等性能测试对1050~1150 ℃×1 h固溶处理后的冷轧HRX19奥氏体不锈钢的组织与力学性能进行了研究。结果表明,冷轧HRX19奥氏体不锈钢的力学性能主要受晶粒尺寸与Z相含量的影响。当固溶温度低于1100 ℃时,不锈钢的组织与力学性能均变化较小,仅表现出强度略有降低;当固溶温度达到1100 ℃时, Z相含量开始明显减少,导致硬度下降,韧性显著提升;进一步提升固溶温度至1150 ℃,Z相含量持续减少,同时晶粒尺寸显著增大,强度与硬度随之降低。1100 ℃固溶处理后,冷轧HRX19奥氏体不锈钢可获得较好的强韧性匹配。

关键词: HRX19奥氏体不锈钢, 固溶处理, Z相, 力学性能

Abstract: Microstructure and mechanical properties of cold-rolled HRX19 austenitic stainless steel subjected to solution treatment at different temperatures of 1050-1150 ℃ for 1 h were investigated using microscopic characterization techniques, including OM, SEM, and TEM, alongside tensile and impact property tests. The results indicate that the mechanical properties of the cold-rolled HRX19 austenitic stainless steel are primarily influenced by grain size and Z phase content. When the solution treatment temperature is below 1100 ℃, the microstructure and mechanical properties exhibit minimal changes, with only a slight reduction in strength. At 1100 ℃, the Z phase content begins to decrease, leading to a significant improvement in toughness and a reduction in hardness. Further increasing the solution treatment temperature to 1150 ℃ causes a continued reduction in Z phase content and a marked increase in grain size, resulting in decreased strength and hardness. After solution treatment at 1100 ℃, the cold-rolled HRX19 austenitic stainless steel can achieve a good combination of strength and toughness.

Key words: HRX19 austenitic stainless steel, solution treatment, Z phase, mechanical properties

中图分类号:

TG161

张继舜, 赵吉庆, 王建强, 王利伟, 周华贸, 杨钢. 固溶温度对冷轧HRX19奥氏体不锈钢组织与力学性能的影响[J]. 金属热处理, 2025, 50(12): 155-160.

Zhang Jishun, Zhao Jiqing, Wang Jianqiang, Wang Liwei, Zhou Huamao, Yang Gang. Effect of solution treatment temperature on microstructure and mechanical properties of cold-rolled HRX19 austenitic stainless steel[J]. Heat Treatment of Metals, 2025, 50(12): 155-160.

参考文献

[1]周池楼, 何默涵, 郭晋, 等. 高压氢环境奥氏体不锈钢焊件氢脆研究进展[J]. 化工进展, 2022, 41(2): 519-536.
Zhou Chilou, He Mohan, Guo Jin, et al. Review on hydrogen embrittlement of austenitic stainless steel weldments in high pressure hydrogen atmosphere[J]. Chemical Industry and Engineering Progress, 2022, 41(2): 519-536.
[2]程旺军, 崔栋栋, 孙耀宁, 等. 基于液氢储运的超低温不锈钢微观组织演变与力学性能研究进展[J]. 太阳能学报, 2024, 45(6): 117-124.
[3]张慧云, 孟宪明, 郑留伟, 等. 敏化处理对不同状态304奥氏体不锈钢氢脆敏感性的影响[J]. 金属热处理, 2021, 46(8): 164-169.
Zhang Huiyun, Meng Xianming, Zheng Liuwei, et al. Effect of sensitization on hydrogen embrittlement sensitivity of 304 austenitic stainless steel in different states[J]. Heat Treatment of Metals, 2021, 46(8): 164-169.
[4]燕春光, 陈胜虎, 李雅平, 等. 氢对316H不锈钢拉伸性能的影响[J]. 钢铁研究学报, 2019, 31(11): 1004-1011.
Yan Chunguang, Chen Shenghu, Li Yaping, et al. Influence of hydrogen on tension property of 316H stainless steel[J]. Journal of Iron and Steel Research, 2019, 31(11): 1004-1011.
[5]廖振洋, 张继舜, 赵吉庆, 等. 超高压临氢环境用抗氢钢研究进展[J]. 钢铁研究学报, 2023, 35(9): 1053-1064.
Liao Zhenyang, Zhang Jishun, Zhao Jiqing, et al. Research progress of hydrogen-resistant steels used in ultra-high pressure hydrogen environment[J]. Journal of Iron and Steel Research, 2023, 35(9): 1053-1064.
[6]中村潤, 浄德佳奈, 大村朋彦, 等. 高圧水素用高強度ステンレス鋼 HRX19©[J]. まてりあ, 2018, 57(2): 69-71.
[7]Wang Shunheng, Zhang Cunshuai, Liu Jimeng, et al. Effect of solution treatment on microstructures and mechanical properties of high nitrogen stainless steel[J]. Rare Metal Materials and Engineering, 2022, 51(8): 2761-2768.
[8]Zhang X, Xun M, Ma J, et al. Effects of heat treatment on precipitation and corrosion resistance of cerium-containing super austenitic stainless steel S31254[J]. Corrosion Communications, 2022, 8: 1-8.
[9]Li J, Shen W, Lin P, et al. Effect of solution treatment temperature on microstructural evolution, precipitation behavior, and comprehensive properties in UNS S32750 super duplex stainless steel[J]. Metals, 2020, 10(11): 1481.
[10]曹铁山, 赵津艺, 程从前, 等. 冷变形和固溶温度对HR3C钢中σ相析出行为的影响[J]. 金属学报, 2020, 56(5): 673-682.
Cao Tieshan, Zhao Jinyi, Cheng Congqian, et al. Effect of cold deformation and solid solution temperature on σ-phase precipitation behavior in HR3C heat resistant steel[J]. Acta Metallurgica Sinica, 2020, 56(5): 673-682.
[11]Kim J M, Kim S J, Kang J H. Effects of short-range ordering and stacking fault energy on tensile behavior of nitrogen-containing austenitic stainless steels[J]. Materials Science and Engineering A, 2022, 836: 142730.
[12]李阳, 张威, 袁刚. 冷变形及退火工艺对低温用奥氏体不锈钢组织性能的影响[J]. 金属热处理, 2023, 48(2): 219-223.
Li Yang, Zhang Wei, Yuan Gang. Effects of cold deformation and annealing process on microstructure and properties of austenitic stainless steel for low temperature[J]. Heat Treatment of Metals, 2023, 48(2): 219-223.
[13]杨壹, 刘让贤, 杨浩坤, 等. 固溶温度对轻质高锰钢组织及性能的影响[J]. 金属热处理, 2023, 48(8): 113-118.
Yang Yi, Liu Rangxian, Yang Haokun, et al. Effects of solution temperature on microstructure and properties of lightweight high manganese steel[J]. Heat Treatment of Metals, 2023, 48(8): 113-118.
[14]Macadre A, Tsuchiyama T, Takaki S. Control of hydrogen-induced failure in metastable austenite by grain size refinement[J]. Materialia, 2019, 8: 100514.
[15]Khalid H, Shunmugasamy V C, DeMott R W, et al. Effect of grain size and precipitates on hydrogen embrittlement susceptibility of nickel alloy 718[J]. International Journal of Hydrogen Energy, 2024, 55: 474-490.
[16]Danielsen H K, Hald J, Grumsen F B, et al. On the crystal structure of Z-phase Cr(V, Nb)N[J]. Metallurgical and Materials Transactions A, 2006, 37(9): 2633-2640.
[17]Zhou Y, Liu Y, Zhou X, et al. Precipitation and hot deformation behavior of austenitic heat-resistant steels: A review[J]. Journal of Materials Science & Technology, 2017, 33(12): 1448-1456.
[18]马凯, 杨庚蔚, 付至祥, 等. 回火温度对热轧Ti-Mo-V钢第二相析出行为的影响[J]. 钢铁, 2025, 60(2): 84-93.
Ma Kai, Yang Gengwei, Fu Zhixiang, et al. Effect of tempering temperature on the second phase precipitation behavior of hot-rolled Ti-Mo-V steel[J]. Iron and Steel, 2025, 60(2): 84-93.

固溶温度对冷轧HRX19奥氏体不锈钢组织与力学性能的影响

Effect of solution treatment temperature on microstructure and mechanical properties of cold-rolled HRX19 austenitic stainless steel

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