金属热处理 ›› 2025, Vol. 50 ›› Issue (9): 181-190.DOI: 10.13251/j.issn.0254-6051.2025.09.029

• 工艺研究 • 上一篇    下一篇

冷轧及退火工艺对新能源电池用铝塑膜箔组织与性能的影响

付世强1, 张江2, 廖斌3, 蒋桂2   

  1. 1.重庆城市科技学院 电气工程与智能制造学院, 重庆 402167;
    2.招商局新材料科技(重庆)有限公司, 重庆 402181;
    3.南南铝业股份有限公司, 广西 南宁 530200
  • 收稿日期:2025-03-05 修回日期:2025-06-28 出版日期:2025-09-25 发布日期:2025-10-13
  • 通讯作者: 张 江,工程师,学士,E-mail: 19252808@qq.com
  • 作者简介:付世强(1979—),男,高级工程师,硕士,主要研究方向为材料及成型加工方面教学和铝板带箔工艺技术质量控制,E-mail: 29470725@qq.com。
  • 基金资助:
    南宁市科学研究与技术开发计划(20241024);重庆城市科技学院2022年度校级科研项目(CKKY2022008)

Effect of cold rolling and annealing process on microstructure and properties of aluminium-plastic film foils for new energy batteries

Fu Shiqiang1, Zhang Jiang2, Liao Bin3, Jiang Gui2   

  1. 1. School of Electrical Engineering and Intelligent Manufacturing, Chongqing Metropolitan College of Science and Technology, Chongqing 402167, China;
    2. China Merchants New Material Technology (Chongqing) Co., Ltd., Chongqing 402181, China;
    3. Alnan Aluminium Co., Ltd., Nanning Guangxi 530200, China
  • Received:2025-03-05 Revised:2025-06-28 Online:2025-09-25 Published:2025-10-13

摘要: 采用半连续铸锭热轧AA8021合金板,设计了多种冷轧及中间退火工艺,制备了0.04 mm厚度的AA8021合金铝箔,研究了冷轧及退火工艺对铝塑膜箔组织和性能的影响。结果表明,在热轧后和冷轧前增加中间退火,对箔材最终的深冲成形性没有明显改善,甚至可能导致成品箔材晶粒长大和不均匀。冷轧道次间必须要有一次完全再结晶的中间退火过程,确保Fe、Si等溶质原子能够得到更充分沉淀、聚集而析出,以保证最终成品退火时可获得更加细小的晶粒尺寸。中间退火和成品退火的升温速度对晶粒尺寸的影响不显著,但退火温度对其有较大影响,350 ℃中间退火温度比380 ℃有更细小的晶粒尺寸,250 ℃成品退火温度比310 ℃有更细小的晶粒尺寸。冷箔轧可明显破碎和细化热轧坯料的晶粒尺寸,但很难或较少破碎第二相,控制冷轧中间退火前后的冷轧加工率均衡程度,以及中间退火后冷箔轧时的料卷温度和润滑油温度,可避免在冷箔轧过程中发生加工软化问题,细化成品晶粒组织而改善成品性能。

关键词: 铝塑膜, AA8021合金, 铝箔, 微观组织, 力学性能

Abstract: AA8021 alloy aluminum foils with a thickness of 0.04 mm were prepared by using semi continuous ingot hot-rolled AA8021 alloy sheet and multiple cold rolling+intermediate annealing processes, then the effects of cold rolling and annealing processes on the microstructure and properties of the aluminum-plastic film foil were studied. The results indicate that adding intermediate annealing between the hot rolling and cold rolling does not significantly improve the final deep drawing formability of the foil, and may even lead to grain growth and unevenness in the finished foil material. In order to ensure that the final product can obtain finer grain size during annealing, a complete recrystallization intermediate annealing process between the cold rolling passes is necessary to ensure that the solute atoms such as Fe and Si can be more fully precipitated. The heating rate of intermediate annealing and finished annealing has no significant effect on grain size, but the annealing temperature has a significant impact on it. The intermediate annealing temperature at 350 ℃ has a smaller grain size than that at 380 ℃, and the finished annealing temperature at 250 ℃ leads to a smaller grain size than that at 310 ℃. The cold foil rolling can significantly break and refine the grains of hot-rolled billets, but it is difficult or less likely to break the second phase particles. Controlling the balance of cold rolling processing rate before and after intermediate annealing, as well as the temperature of the coil and lubricating oil during cold foil rolling after intermediate annealing, can minimize the occurrence of processing softening problems during cold foil rolling, refine the grain structure of the finished product, and improve product performance.

Key words: aluminium-plastic film, AA8021 alloy, aluminium foil, microstructure, mechanical properties

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