金属热处理 ›› 2021, Vol. 46 ›› Issue (3): 125-129.DOI: 10.13251/j.issn.0254-6051.2021.03.026

• 材料研究 • 上一篇    下一篇

固溶处理AZ91-xCu合金的组织与腐蚀性能

桑恒, 敬和民, 宋广生, 陈政   

  1. 安徽工业大学 材料科学与工程学院, 安徽 马鞍山 243032
  • 收稿日期:2020-11-28 出版日期:2021-03-25 发布日期:2021-05-08
  • 通讯作者: 敬和民,副教授,博士,E-mail:2540842798@qq.om
  • 作者简介:桑恒(1995—),男,硕士研究生,主要研究方向为轻金属新材料的铸造,E-mail:2369064042@qq.com。

Microstructure and corrosion properties of solution treated AZ91-xCu alloys

Sang Heng, Jing Hemin, Song Guangsheng, Chen Zheng   

  1. School of Materials Science and Engineering, Anhui University of Technology, Ma'anshan Anhui 243032, China
  • Received:2020-11-28 Online:2021-03-25 Published:2021-05-08

摘要: 以真空熔炼方法制备的AZ91-xCu(x=0、0.5、1、2)合金为研究对象,对其进行400 ℃保温12 h固溶处理,利用X射线衍射、扫描电镜、浸泡失重法及极化曲线测试等手段对合金的微观结构和腐蚀性能进行了研究。结果表明:铸态与固溶态AZ91-xCu合金基体主要由α-Mg与β-Mg17Al12相组成,Cu的添加使基体产生了Mg2Cu、Cu5Zn8等相,其中固溶态AZ91-2Cu合金中出现了新相Al2Cu;固溶处理时合金中的β-Mg17Al12相大量溶入基体,晶界明显,剩余第二相主要分布于晶界处,少量弥散分布于晶内;添加Cu与固溶处理均加快AZ91合金的腐蚀速率,其中固溶态AZ91-2Cu合金腐蚀速率最大。

关键词: AZ91-xCu合金, 固溶处理, 第二相, 腐蚀速率

Abstract: AZ91-xCu (x=0, 0.5, 1, 2) alloy was prepared by vacuum melting method, and solid solution treated at 400 ℃ for 12 h. The phase, microstructure and corrosion properties of the alloy were studied by means of X-ray diffraction, scanning electron microscopy, immersion mass loss method and polarization curve test. The results show that the substrates of as-cast and solid solution treated AZ91-xCu alloys are mainly composed of α-Mg and β-Mg17Al12 phases, and the addition of Cu leads to Mg2Cu and Cu5Zn8 phases precipitation in the substrates, among which a new phase Al2Cu appears in the solid solution treated AZ91-2Cu alloy. During the solid solution treatment, the β-Mg17Al12 phase of the alloy is largely dissolved into the substrate and the grain boundary is obvious. The remaining second phase is mainly distributed at the grain boundary and a little disperses in the grain. The addition of Cu and the solution treatment both accelerate the corrosion rate of AZ91 alloy, among which the corrosion rate of the solution treated AZ91-2Cu alloy is the highest.

Key words: AZ91-xCu alloys, solid solution treatment, second phase, corrosion rate

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