金属热处理 ›› 2026, Vol. 51 ›› Issue (2): 118-125.DOI: 10.13251/j.issn.0254-6051.2026.02.019

• 材料研究 • 上一篇    下一篇

氧含量及退火处理对低氧铜力学性能的影响

赵国1,2, 郑万1,2, 陈学文3, 冯北军3, 随钦钦4, 胡仕琴1,2, 严子瑞1,2, 周玉茹1,2   

  1. 1.武汉科技大学 耐火材料与冶金国家重点实验室, 湖北 武汉 430081;
    2.武汉科技大学 钢铁冶金与资源利用教育部重点实验室, 湖北 武汉 430081;
    3.黄石晟祥铜业有限公司, 湖北 黄石 435000;
    4.大冶有色金属集团控股有限公司, 湖北 黄石 435005
  • 收稿日期:2025-08-21 修回日期:2025-12-10 发布日期:2026-03-05
  • 通讯作者: 郑 万,教授,博士,E-mail:zhengwan@wust.edu.cn
  • 作者简介:赵 国(1999—),男,硕士研究生,主要研究方向为连铸连轧工艺与质量控制,E-mail:1174781404@qq.com。

Effect of oxygen content and annealing treatment on mechanical properties of low oxygen copper

Zhao Guo1,2, Zheng Wan1,2, Chen Xuewen3, Feng Beijun3, Sui Qinqin4, Hu Shiqin1,2, Yan Zirui1,2, Zhou Yuru1,2   

  1. 1. The State Key Laboratory of Refractories and Metallurgy, Wuhan University of Science and Technology, Wuhan Hubei 430081, China;
    2. The Key Laboratory for Ferrous Metallurgy and Resources Utilization of Ministry of Education, Wuhan University of Science and Technology, Wuhan Hubei 430081, China;
    3. Huangshi Shengxiang Copper Industry Co., Ltd., Huangshi Hubei 435000, China;
    4. Daye Nonferrous Metals Group Holdings Co., Ltd., Huangshi Hubei 435005, China
  • Received:2025-08-21 Revised:2025-12-10 Published:2026-03-05

摘要: 利用不同氧含量(222、288、337和439 mg/kg)的8 mm低氧铜杆冷轧制备2.9 mm厚的薄铜条,并经500 ℃×10 min的退火处理,通过拉伸试验、光学显微镜、扫描电镜和能谱仪研究氧含量及退火处理对低氧铜显微组织、力学性能和断口形貌的影响。结果表明,冷轧后微观组织由等轴晶变为纤维组织;随氧含量增加,抗拉强度降低、显微硬度增加。退火后薄铜条中形成再结晶晶粒和孪晶,伸长率提高,抗拉强度和显微硬度降低。随着氧含量增加,退火态薄铜条的抗拉强度和伸长率下降,显微硬度的变化较小。拉伸断口分析表明,冷轧铜断口为韧性断口;随着氧含量的增加,韧窝形状变得更加不规则,大小差异增大,分布更加不均匀,断口变得更加粗糙。退火处理前后的断口形貌相似,颈缩程度较未退火处理的更大,表明塑性更好。实际生产中,氧含量控制在220~240 mg/kg区间,低氧铜杆延展性最佳。

关键词: 低氧铜, 氧含量, 微细铜丝, 退火, 延展性

Abstract: 2.9 mm thick thin copper strips were manufactured by cold rolling of 8 mm low oxygen copper rods with different oxygen contents (222, 288, 337 and 439 mg/kg). After annealing at 500 ℃ for 10 min, effects of oxygen content and annealing treatment on the microstructure, mechanical properties, and fracture morphology of low oxygen copper were investigated by means of tensile testing, optical microscope, scanning electron microscope, and energy dispersive spectroscopy. The results show that after cold-rolling, the microstructure changes from equiaxed grain to fiber structure. With the increase of oxygen content, the tensile strength decreases, while the microhardness increases. Recrystallized grains and twinning are formed in the thin copper strip after annealing, and the elongation improves, but the tensile strength and microhardness reduce. As the oxygen content increases, the tensile strength and elongation of annealed thin copper strips decrease, while the change in microhardness is relatively small. The tensile fracture analysis shows that the cold-rolled copper fracture is a ductile fracture. As the oxygen content increases, the shape of the dimples becomes more irregular, the size difference increases, the distribution becomes more uneven, and the fracture becomes rougher. The fracture morphology before and after annealing is similar, the necking degree is greater than that of the unannealed, indicating better plasticity. In actual production, the oxygen content is controlled within the range of 220-240 mg/kg, the low oxygen copper rod can achieve the best ductility.

Key words: low oxygen copper, oxygen content, thin copper wire, annealing, ductility

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