金属热处理 ›› 2025, Vol. 50 ›› Issue (9): 202-207.DOI: 10.13251/j.issn.0254-6051.2025.09.032

• 工艺研究 • 上一篇    下一篇

固溶时效处理对34Cr24Ni11Mn4Nb2奥氏体气阀钢组织与性能的影响

王天宏, 陈洪美, 朱治愿, 贾俊波, 赵守忠, 徐锦文, 苑庆德   

  1. 江苏科技大学 材料科学与工程学院, 江苏 镇江 212100
  • 收稿日期:2025-04-08 修回日期:2025-07-25 出版日期:2025-09-25 发布日期:2025-10-13
  • 通讯作者: 朱治愿,教授,博士,E-mail:salanganezhu@just.edu.cn
  • 作者简介:王天宏(1999—),男,硕士,主要研究方向为高温合金,E-mail:1794406234@qq.com。

Effect of solution and aging treatment on microstructure and properties of 34Cr24Ni11Mn4Nb2 austenitic valve steel

Wang Tianhong, Chen Hongmei, Zhu Zhiyuan, Jia Junbo, Zhao Shouzhong, Xu Jinwen, Yuan Qingde   

  1. School of Materials Science and Engineering, Jiangsu University of Science and Technology, Zhenjiang Jiangsu 212100, China
  • Received:2025-04-08 Revised:2025-07-25 Online:2025-09-25 Published:2025-10-13

摘要: 采用金相显微镜、扫描电镜及电子万能试验机研究了固溶和时效处理对34Cr24Ni11Mn4Nb2奥氏体气阀钢组织与性能的影响。结果表明,经1040~1190 ℃固溶30 min后,随固溶温度的提高,奥氏体晶粒发生明显长大,1160 ℃固溶30 min后,较多的原始锻态一次未溶相基本固溶到基体中,合金硬度逐渐下降。固溶时效处理后,合金晶内以及晶界处析出较多的二次相,随着时效温度(700~850 ℃)的增高以及时间(1~6 h)的延长,颗粒状的M23C6相在晶界处逐渐析出,对合金晶界起到良好的钉扎作用,抑制晶粒的再次长大。800 ℃以上较高温度时效时,合金基体中出现层状析出物,导致合金塑性严重下降。合金在时效过程中,硬度整体上表现为先升高后降低的趋势,750 ℃时效4 h后,合金硬度达到最大值324.5 HV,抗拉强度达到了1159.4 MPa,屈强比较锻态降低了19.1%,断裂总延伸率达到了29.52%。

关键词: 奥氏体气阀钢, 固溶时效, 组织, 析出相, 性能

Abstract: Effect of solution and aging treatment on microstructure and properties of 34Cr24Ni11Mn4Nb2 austenitic valve steel was investigated by using metallographic microscope, scanning electron microscope, and electronic universal testing machine. The results show that after solution treatment at 1040-1190 ℃ for 30 min, the austenite grains grow significantly with the increase of solution temperature. After solution treatment at 1160 ℃ for 30 min, most of the primary undissolved phases in the original forged state are basically dissolved into the matrix, and the hardness of the alloy decreases gradually. After solution and aging treatment, a large number of secondary phases precipitate in the grain and at the grain boundaries. With the increase of aging temperature(700-850 ℃) and time (1-6 h), granular M23C6 phases gradually precipitate at the grain boundaries, which plays a good pinning role on the grain boundaries and inhibits the re-growth of grains. When aged at a relatively high temperature above 800 ℃, lamellar precipitates appear in the alloy matrix, leading to a significant decrease in the plasticity of the alloy. During the aging process, the hardness of the alloy shows an overall trend of first increasing and then decreasing. After aging at 750 ℃ for 4 h, the hardness of the alloy reaches a maximum of 324.5 HV, the tensile strength reaches 1159.4 MPa, the yield ratio is 19.1% lower than that of the as-forged, and the total extension after fracture reaches 29.52%.

Key words: austenitic valve steel, solution and aging treatment, microstructure, precipitated phase, properties

中图分类号: