金属热处理 ›› 2024, Vol. 49 ›› Issue (3): 7-14.DOI: 10.13251/j.issn.0254-6051.2024.03.002

• 工艺研究 • 上一篇    下一篇

回火温度对Nb、V合金化低合金高强度钢氢脆敏感性的影响

李晓亮, 程晓英, 王兆丰, 任毓文, 曾繁宇   

  1. 上海大学 材料研究所, 上海 200072
  • 收稿日期:2023-08-26 修回日期:2024-01-06 出版日期:2024-03-25 发布日期:2024-04-24
  • 通讯作者: 程晓英,研究员,博士,E-mail:chengxy@staff.shu.edu.cn
  • 作者简介:李晓亮(1997—),男,硕士研究生,主要研究方向为低合金高强度钢的氢脆,E-mail:lxlptyy@shu.edu.cn。
  • 基金资助:
    国家自然科学基金(51871145)

Effect of tempering temperature on hydrogen embrittlement sensitivity of a low-alloy high-strength steel with Nb and V

Li Xiaoliang, Cheng Xiaoying, Wang Zhaofeng, Ren Yuwen, Zeng Fanyu   

  1. Institute of Materials, Shanghai University, Shanghai 200072, China
  • Received:2023-08-26 Revised:2024-01-06 Online:2024-03-25 Published:2024-04-24

摘要: 为了提高钢强度的同时降低氢脆敏感性,研制了一种同时添加0.11wt%Nb和0.55wt%V元素的低合金高强度钢。运用光学显微镜(OM)、X射线衍射仪(XRD)和透射电镜(TEM)等表征手段,并通过双电解池氢渗透技术和慢应变速率拉伸试验,研究了3种 不同回火温度(560、600、640 ℃)对试验钢显微组织、氢扩散行为和氢脆敏感性的影响。结果表明,随着回火温度的升高,铁素体晶粒尺寸增大,位错密度降低,弥散析出的碳化物粗化,因此抗拉强度降低而伸长率增加;另一方面,可逆氢陷阱密度降低,扩散激活能降低,氢扩散系数增大,因此氢脆敏感性降低。

关键词: 低合金高强度钢, 回火温度, 位错密度, 氢扩散, 氢脆

Abstract: In order to improve strength and simultaneously reduce hydrogen embrittlement sensitivity, a low-alloy high-strength steel with 0.11wt%Nb and 0.55wt%V was developed. The effect of three different tempering temperatures (560, 600, 640 ℃) on the microstructure, hydrogen diffusion behavior and hydrogen embrittlement sensitivity of the tested steel was characterized and studied by using optical microscope (OM), X-ray diffraction (XRD), transmission electron microscope (TEM), hydrogen permeation technique of double electrolytic cells and slow strain rate tensile test. The results show that with the increase of tempering temperature, the ferrite grain size increases while the dislocation density reduces, and the carbides precipitated become coarse, hence the tensile strength decreases and the elongation increases. Meanwhile, with the increase of tempering temperature, the density of hydrogen reversible traps reduces and the activation energy of hydrogen diffusion decreases, as well as the hydrogen diffusion coefficient increases, hence the hydrogen embrittlement sensitivity becomes lower.

Key words: low-alloy high-strength steel, tempering temperature, dislocation density, hydrogen diffusion, hydrogen embrittlement

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