热处理对铜铝低温钎焊的影响

doi:10.13251/j.issn.0254-6051.2022.06.014

金属热处理 ›› 2022, Vol. 47 ›› Issue (6): 78-84.DOI: 10.13251/j.issn.0254-6051.2022.06.014

热处理对铜铝低温钎焊的影响

徐新犬¹, 方舟², 刘新宽¹, 王子延³

1.上海理工大学材料与化学学院, 上海 200093;
2.华纬科技股份有限公司, 浙江诸暨 311800;
3.坤同勃志智能科技(上海)有限公司, 上海 201207

收稿日期:2022-01-27 修回日期:2022-04-03 出版日期:2022-06-25 发布日期:2022-07-05
通讯作者: 刘新宽,副教授,E-mail:xinkuanliu@163.com
作者简介:徐新犬(1996—),男,硕士研究生,主要研究方向为钎焊工艺,E-mail:xqxu0623@163.com。

Effect of heat treatment on low temperature brazing of copper and aluminum

Xu Xinquan¹, Fang Zhou², Liu Xinkuan¹, Wang Ziyan³

1. School of Materials Science and Engineering, University of Shanghai for Science and Technology, Shanghai 200093, China;
2. Huawei Technology Co., Ltd., Zhuji Zhejiang 311800, China;
3. Kun Tong Bo Zhi Intelligent Technology (Shanghai) Co., Ltd., Shanghai 201207, China

Received:2022-01-27 Revised:2022-04-03 Online:2022-06-25 Published:2022-07-05

摘要/Abstract

摘要： 研究了热处理温度和保温时间对低温钎焊Al/Sn-Bi/Cu接头强度的影响,采用光学显微镜和扫描电镜对接头界面显微组织和断口表面形貌进行了分析。结果表明,随着热处理温度的增加,焊接件的剪切强度表现出增加的趋势。随着热处理时间的增加,Al/Sn-Bi/Cu接头的剪切强度呈现出先增大后减小的趋势。钎焊时铜铝元素进入到钎焊层当中,主要以Cu-Al固溶体的形式存在,并随着热处理时间延长而聚集。热处理使钎缝内粗大的脆性Sn-Bi共晶组织变得细小且覆盖面积减小,从而增加接头强度,Cu-Al固溶体聚集和生长会降低接头强度。

关键词: 铜铝复合材料, 低温钎焊, Sn-Bi钎料, 显微组织

Abstract: Effect of heat treatment temperature and holding time on strength of Al/Sn-Bi/Cu joints brazed at low temperature was studied. The microstructure of the joint interface and the fracture surface morphology were analyzed by means of optical microscope and scanning electron microscopy. The results show that with the increase of heat treatment temperature, the shear strength of welded parts shows an increasing trend. With the increase of heat treatment time, the shear strength of Al/Sn-Bi/Cu joints increases first and then decreases. During brazing, copper and aluminum elements enter the brazing layer, mainly exist in the form of Cu-Al solid solution, and accumulate with the prolongation of heat treatment time. Heat treatment makes the coarse and brittle Sn-Bi eutectic structure in the brazing seam finer and reduces the coverage area to increase the strength of the joint. The aggregation and growth of Cu-Al solid solution decrease the strength of the joint.

Key words: copper aluminum compound materials, low temperature brazing, Sn-Bi solder, microstructure

中图分类号:

徐新犬, 方舟, 刘新宽, 王子延. 热处理对铜铝低温钎焊的影响[J]. 金属热处理, 2022, 47(6): 78-84.

Xu Xinquan, Fang Zhou, Liu Xinkuan, Wang Ziyan. Effect of heat treatment on low temperature brazing of copper and aluminum[J]. Heat Treatment of Metals, 2022, 47(6): 78-84.

参考文献

[1]路希龙, 刘平, 刘新宽, 等. 铪与铜钎焊接头的组织与强度[J]. 稀有金属, 2014, 38(1): 22-27.
Lu Xilong, Liu Ping, Liu Xinkuan, et al. Microstructure and strength of hafnium and copper brazing joints[J]. Rare Metals, 2014, 38(1): 22-27.
[2]王征, 刘平, 刘新宽, 等. 铜热浸镀铝扩散层生长动力学模型[J]. 功能材料, 2015, 46(2): 2080-2083.
Wang Zheng, Liu Ping, Liu Xinkuan, et al. Growth dynamics model of diffusion layer of copper hot dip aluminum plating[J]. Functional Materials, 2015, 46(2): 2080-2083.
[3]Lacaze J, Tierce S, Lafont M C, et al. Study of the microstructure resulting from brazed aluminum materials used in heat exchangers[J]. Materials Science and Engineering, 2005, 413(12): 317-321.
[4]刘小娣, 杨毅, 李凤生. 化学镀法制备纳米Cu/Al复合粉末[J]. 功能材料, 2006, 37(8): 1335-1337.
Liu Xiaodi, Yang Yi, Li Fengsheng. Preparation of Cu/Al nanocomposite powders by electroless plating[J]. Functional Materials, 2006, 37(8): 1335-1337.
[5]Pourahmad P. Materials flow and phase transformation in friction stir welding of Al6013/Mg[J]. Chinese Journal of Nonferrous Metals, 2013, 23(5): 1253-1261.
[6]Bahmanpour H, Kauffmann A, Khoshkhoo M S, et al. Effect of stacking fault energy on deformation behavior of cryo-rolled copper and copper alloys[J]. Materials Science and Engineering A, 2011, 35(529): 230-236.
[7]刘帅洋, 王爱琴, 吕世敬, 等. 铜铝层状复合材料界面特性及深加工研究进展[J]. 材料导报, 2018, 32(5): 828-835.
Liu Shuaiyang, Wang Aiqin, Lü Shijing, et al. Research progress on interface properties and deep processing of copper aluminum laminated composites[J]. Materials Review, 2018, 32(5): 828-835.
[8]曹凯, 刘平, 刘新宽, 等. 无镀镍铜铝低温钎焊工艺研究[J]. 有色金属材料与工程, 2018, 39(6): 1-6.
Cao Kai, Liu Ping, Liu Xinkuan, et al. Study on low-temperature brazing technology of copper and aluminum without nickel plating[J]. Nonferrous Metal Materials and Engineering, 2018, 39(6): 1-6.
[9]Liu Yun, Yu Weiyuan, Liu Yingzong, et al. Effect of ultrasound on dissolution of Al in Sn[J]. Ultrasonics Sonochemistry, 2019, 50: 67-73.
[10]于汉臣, 张汇文, 闫久春. 5A06铝合金/T2紫铜镶嵌结构件超声波复合钎焊[J]. 机械工程师, 2020, 54(8): 18-23.
Yu Hanchen, Zhang Huiwen, Yan Jiuchun. Ultrasonic composite brazing of 5A06 aluminum alloy/T2 copper mosaic structure[J]. Mechanical Engineer, 2020, 54(8): 18-23.
[11]张洋, 闫久春, 陈晓光. SiC_P/A356 复合材料超声波辅助钎焊[J]. 焊接学报, 2009, 30(3): 89-92.
Zhang Yang, Yan Jiuchun, Chen Xiaoguang. Ultrasonic assisted brazing of SiC_P/A356 composites[J]. Transactions of the China Welding Institution, 2009, 30(3): 89-92.
[12]Jáňa M, Turňa M, MarÔnek M, et al. Application of a ternary Zn-based solder alloy for joining of AZ31B magnesium alloy with ultrasonic support[J]. Advanced Materials Research, 2015, 1077: 82-88.
[13]左晓姣. 铜铝复合板界面扩散层组织结构与性能的研究[D]. 沈阳: 沈阳工业大学, 2017.
Zuo Xiaojiao. Study on microstructure and properties of interfacial diffusion layer of copper-aluminum composite plate[D]. Shenyang: Shenyang University of Technology, 2017.
[14]曹飞. Al/Cu双金属复层材料界面扩散行为及微观组织演变[D]. 大连: 大连理工大学, 2018.
Cao Fei. Diffusion behavior and microstructural evolution on interfaces in Al/Cu bimetal[D]. Dalian: Dalian University of Technology, 2018.
[15]宁江天. 低熔点锡铋合金无铅钎料脆性机理及韧化机制的研究[J]. 焊接技术, 2019, 48(5): 80-85.
Ning Jiangtian. Study on brittleness mechanism and toughening mechanism of low melting point Sn-Bi alloy lead-free solder[J]. Welding Technology, 2019, 48(5): 80-85.
[16]Zhang Huiwen, Cui Wei, He Jingshan, et al. Formation and evolution of intermetallic compounds at interfaces of Cu/Al joints by ultrasonic-assisted soldering[J]. Journal of Materials Processing Technology, 2015, 33(223): 1-7.
[17]林国标, 王自东, 张伟, 等. 热处理对锡青铜合金组织和性能的影响[J]. 铸造, 2011, 60(3): 287-289, 293.
Lin Guobiao, Wang Zidong, Zhang Wei, et al. Effects of heat treatment on microstructure and performance of tin bronze alloy[J]. Foundry, 2011, 60(3): 287-289, 293.
[18]肖勇. 超声波辅助Cu/Al液相钎焊接头冶金连接机制及性能研究[D]. 哈尔滨: 哈尔滨工业大学, 2014.
Xiao Yong. Study on the metallurgic bonding mechanism and properties of liquid phase brazed Cu/Al joints with the assistance of ultrasound[D]. Harbin: Harbin Institute of Technology, 2014.

热处理对铜铝低温钎焊的影响

Effect of heat treatment on low temperature brazing of copper and aluminum

PDF

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	田亚强, 赵志浩, 杨子旋, 徐海卫, 韩赟, 郑小平, 李红斌, 陈连生. 温轧温度对中碳钢组织与力学性能的影响[J]. 金属热处理, 2022, 47(6): 19-24.
[2]	白兴红, 赵席春, 赵德利, 王大鹏, 南玉静. 冷却速度对支承辊用Cr5钢显微组织与力学性能的影响[J]. 金属热处理, 2022, 47(6): 69-71.
[3]	韩颢源, 杨涛, 邱娟, 杨刚, 余万华, 翟月雯, 周乐育. 固溶处理对TC4合金组织和硬度的影响[J]. 金属热处理, 2022, 47(6): 93-97.
[4]	赵天生, 方羽, 孙誉宾. 成形速度对7050铝合金锻件力学性能和断口形貌的影响[J]. 金属热处理, 2022, 47(6): 103-106.
[5]	何春静, 庞庆海, 李洁, 殷立涛, 聂新林. 模拟正火温度对Q355E钢锻件组织和性能的影响[J]. 金属热处理, 2022, 47(6): 123-127.
[6]	刘少尊, 车洪艳, 李欧, 梁晨, 桂舜, 王铁军. 淬火工艺对粉末冶金马氏体不锈钢组织与性能的影响[J]. 金属热处理, 2022, 47(6): 128-132.
[7]	李阳, 张建伟, 朱鹏凯, 杨扬. 碳含量及冷却速率对钢件淬火残余应力的影响[J]. 金属热处理, 2022, 47(6): 192-195.
[8]	莫金强, 冯光宏, 徐梅, 张威, 李阳. 化学成分对316L奥氏体不锈钢组织及变形行为的影响[J]. 金属热处理, 2022, 47(5): 81-86.
[9]	刘璇, 黄国平, 刘海定, 何曲波, 张楠. 固溶处理对Ni48Cr21Cu2Mo合金组织与力学性能的影响[J]. 金属热处理, 2022, 47(5): 105-110.
[10]	刘丹, 陈杰, 刘文鉴, 周文浩, 罗登, 张青学. 回火温度对Q1100超高强钢组织和性能的影响[J]. 金属热处理, 2022, 47(5): 111-117.
[11]	宿鹏吉, 麻永林, 董丽丽, 温铠, 罗家豪, 刘宝志. 磁场预退火对取向硅钢二次再结晶组织及织构的影响[J]. 金属热处理, 2022, 47(5): 131-135.
[12]	张春雨, 颜瑜, 陈贤帅, 杜如虚. 真空退火处理对选区激光熔化TA2纯钛显微组织及力学性能的影响[J]. 金属热处理, 2022, 47(5): 155-160.
[13]	张明皓, 韩颢源, 徐跃明, 李俏, 高直, 周乐育. 真空渗碳18CrNiMo7-6钢中碳化物的析出规律[J]. 金属热处理, 2022, 47(5): 171-176.
[14]	沈统, 杨丽, 李振, 冯凌宵. 渗扩时间比对AISI 316不锈钢渗氮层组织与性能的影响[J]. 金属热处理, 2022, 47(5): 183-188.
[15]	陈今良, 冯中学, 张利民, 易健宏. 冷轧变形对CrCoNi合金组织与性能的影响[J]. 金属热处理, 2022, 47(5): 204-207.