金属热处理 ›› 2026, Vol. 51 ›› Issue (2): 136-144.DOI: 10.13251/j.issn.0254-6051.2026.02.021

• 材料研究 • 上一篇    下一篇

Cu对15Cr超级马氏体不锈钢组织与性能的影响

杜丽萍1,2, 赵吉庆2, 龚志华1, 杨钢2   

  1. 1.内蒙古科技大学 材料科学与工程学院, 内蒙古 包头 014010;
    2.钢铁研究总院有限公司 特殊钢研究院, 北京 100081
  • 收稿日期:2025-08-26 修回日期:2025-12-27 发布日期:2026-03-05
  • 通讯作者: 赵吉庆,高级工程师,博士,E-mail:zhaojiqing@nercast.com
  • 作者简介:杜丽萍(1998—),女,硕士研究生,主要从事新型叶片钢的开发及应用工作,E-mail:1293817221@qq.com。

Effect of Cu on microstructure and properties of 15Cr super martensitic stainless steel

Du Liping1,2, Zhao Jiqing2, Gong Zhihua1, Yang Gang2   

  1. 1. School of Materials Science and Engineering, Inner Mongolia University of Science & Technology, Baotou Inner Mongolia 014010, China;
    2. Research Institute of Special Steels, Central Iron and Steel Research Institute Co., Ltd., Beijing 100081, China
  • Received:2025-08-26 Revised:2025-12-27 Published:2026-03-05

摘要: 为研究Cu元素对125 ksi钢级15Cr马氏体不锈钢组织与力学性能的影响,利用光学显微镜(OM)、扫描电镜(SEM)、透射电镜(TEM)、洛氏硬度计以及电子万能试验机等研究了500~550 ℃回火后1.00%~1.50%Cu试验钢的显微组织与性能的变化。结果表明:1.00%~1.50%Cu试验钢的显微组织和SEM图像没有明显差异,通过TEM观察可知,随Cu含量的增加,马氏体板条逐渐粗化,强化作用增强,抗回火能力变弱。试验钢中的析出相主要为Laves相、χ相、σ相、少量M23C6以及微量富Cu相,且随着Cu含量的增加,奥氏体相区逐渐扩大。富Cu相的析出温度随Cu含量的增加由667 ℃逐渐提高为706 ℃,析出量由0.008增至0.012,由椭球状转变为棒状。钢中Cu含量的增加,对χ相、Laves相以及M23C6相的影响不大。Cu含量按1.25%控制较合适,控制范围在1.20%~1.40%,可以在较宽泛的回火工艺范围内调整强度与韧性。

关键词: 125 ksi钢级, 超级马氏体不锈钢, Cu含量, 组织, 力学性能

Abstract: To investigate the effect of Cu element on the microstructure and mechanical properties of 125 ksi grade 15Cr martensitic stainless steel, the changes in microstructure and properties of 1.00%-1.50%Cu tested steels tempered at 500-550 ℃ were studied by means of optical microscope (OM), scanning electron microscope (SEM), transmission electron microscope (TEM), Rockwell hardness tester, and electron universal testing machine. The results show that there is no obvious difference between the metallographic structure and SEM images of 1.00%-1.50% Cu tested steels. The TEM observation shows that with the increase of Cu content, the martensitic lath gradually coarsens, the strengthening effect increases, but the tempering resistance weakens. The precipitated phases in the tested steels are mainly Laves phase, χ phase, σ phase, a small amount of M23C6, and trace amounts of Cu-rich phase, and the austenite phase region gradually expands with the increase of Cu content. The precipitation temperature of the Cu-rich phase gradually increases from 667 ℃ to 706 ℃ with the increase of Cu content, and the precipitation amount increases from 0.008 to 0.012, transforming from ellipsoidal to rod-shaped. The increase of Cu content in the tested steel has little effect on the χ phase, Laves phase, and M23C6 phase. It is more appropriate to control the Cu content at 1.25%, and with a control range of 1.20% to 1.40%, which can adjust the strength and toughness within a wide range of tempering processes.

Key words: 125 ksi steel grade, super martensitic stainless steel, Cu content, microstructure, mechanical properties

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