高黏附性超疏水表面的制备及耐腐蚀性

doi:10.13251/j.issn.0254-6051.2022.02.035

金属热处理 ›› 2022, Vol. 47 ›› Issue (2): 193-199.DOI: 10.13251/j.issn.0254-6051.2022.02.035

高黏附性超疏水表面的制备及耐腐蚀性

林宏春¹, 马丹丹¹, 于盛旺¹, 马永¹, 周兵¹, 高洁¹, 黑鸿君¹, 薛彦鹏²

1.太原理工大学材料科学与工程学院, 山西太原 030024;
2.北京科技大学国家材料服役安全科学中心, 北京 100083

收稿日期:2021-10-17 修回日期:2021-12-27 出版日期:2022-02-25 发布日期:2022-04-01
通讯作者: 于盛旺,教授, E-mail:yushengwang@tyut.edu.cn
作者简介:林宏春(1996—),男,硕士研究生,主要研究方向为表面处理,E-mail:1102972603@qq.com。
基金资助:
山西省科技重大专项(20181102013);山西省“1331工程”工程研究中心(PT201801);中央高校基础研究基金(FRF-TP-20-049A2)

Preparation and corrosion resistance of highly adhesive superhydrophobic surface

Lin Hongchun¹, Ma Dandan¹, Yu Shengwang¹, Ma Yong¹, Zhou Bing¹, Gao Jie¹, Hei Hongjun¹, Xue Yanpeng²

1. College of Materials Science and Engineering, Taiyuan University of Technology, Taiyuan Shanxi 030024, China;
2. National Center for Materials Service Safety, University of Science and Technology Beijing, Beijing 100083, China

Received:2021-10-17 Revised:2021-12-27 Online:2022-02-25 Published:2022-04-01

摘要/Abstract

摘要： 利用电化学沉积技术在碳钢基底上制备了Co-Ni过渡层,再通过双辉等离子表面合金化技术(DGPSA)在过渡层上沉积了Cr涂层,经全氟辛基三氯硅烷(PFTEOS)溶液修饰后,制备出了具有高黏附性的超疏水表面。利用扫描电镜(SEM)、EDS、X射线衍射仪(XRD)、X射线光电子能谱仪(XPS)、接触角测量仪、电化学测试等方法表征了涂层的形貌、物相组成、润湿性能、粘附性以及耐腐蚀性能,探究了DGPSA技术不同沉积时间对Cr涂层表面形貌和润湿性能的影响。结果表明,在沉积温度为750 ℃,沉积时间30 min 时,制备出了具有微纳米乳突状结构的高黏附性超疏水表面,水滴接触角达到159°,水滴在样品倾斜180°也不发生滚落。电化学测试结果证明制备的超疏水表面具有出色的耐腐蚀性能,对碳钢基底起到了良好的腐蚀防护作用。

关键词: 表面合金化, 电化学沉积, 超疏水表面, 高黏附力, 耐腐蚀性

Abstract: Co-Ni transition layer was prepared on carbon steel substrate using electrochemical deposition, then Cr coating was deposited on the Co-Ni transition layer by double glow plasma surface alloying technique (DGPSA). After modification by PFTEOS solution, a superhydrophobic coating with high adhesion was prepared. The morphology, phase composition, wetting performance, adhesion property and corrosion resistance of the coating were characterized by means of scanning electron microscope (SEM), energy dispersive X-ray spectroscopy (EDS), X-ray diffractometer (XRD), X-ray photoelectron spectrometer (XPS), contact angle measuring instrument and electrochemical test, respectively. The influence of deposition time of DGPSA technique on surface morphology and wetting performance was explored. The results show that the superhydrophobic surface with a papillary structure and high adhesion is prepared under the deposition temperature of 750 ℃ for 30 min. The water contact angle reaches 159° and the water droplet don't roll off even if the specimen is tilted 180°. The electrochemical test results demonstrate that the as-prepared superhydrophobic surface exhibits excellent corrosion protection for carbon steel substrate.

Key words: surface alloying, electrochemical deposition, superhydrophobic surface, high adhesion, corrosion resistance

中图分类号:

TB304

林宏春, 马丹丹, 于盛旺, 马永, 周兵, 高洁, 黑鸿君, 薛彦鹏. 高黏附性超疏水表面的制备及耐腐蚀性[J]. 金属热处理, 2022, 47(2): 193-199.

Lin Hongchun, Ma Dandan, Yu Shengwang, Ma Yong, Zhou Bing, Gao Jie, Hei Hongjun, Xue Yanpeng. Preparation and corrosion resistance of highly adhesive superhydrophobic surface[J]. Heat Treatment of Metals, 2022, 47(2): 193-199.

参考文献

[1]Latthe S S, Terashima C, Nakata K, et al. Superhydrophobic surfaces developed by mimicking hierarchical surface morphology of lotus leaf[J]. Molecules, 2014, 19(4): 4256-4283.
[2]Vazirinasab E, Jafari R, Momen G. Application of superhydrophobic coatings as a corrosion barrier: A review[J]. Surface and Coatings Technology, 2018, 341: 40-56.
[3]Cheng M, Zhang S, Dong H, et al. Improving the durability of a drag-reducing nanocoating by enhancing its mechanical stability[J]. ACS Applied Materials & Interfaces, 2015, 7(7): 4275-4282.
[4]Xu Z, Jiang D, Wei Z, et al. Fabrication of superhydrophobic nano-aluminum films on stainless steel meshes by electrophoretic deposition for oil-water separation[J]. Applied Surface Science, 2018, 427: 253-261.
[5]Feng L, Zhang Y A, Xi J M, et al. Petal effect: A superhydrophobic state with high adhesive force[J]. Langmuir, 2008, 24(8): 4114-4119.
[6]Zhu H, Hu W, Xu Y, et al. Gradient structure based dual-robust superhydrophobic surfaces with high-adhesive force[J]. Applied Surface Science, 2019, 463: 427-434.
[7]Qiu Y, Jiang L, Liu K. Peanut leaves with high adhesive superhydrophobicity and their biomimetic materials[J]. Scientia Sinica Chimica, 2011, 41(2): 403-408.
[8]强小虎, 张红霞, 王彦平, 等. 强黏附性超疏水氧化铝的表面结构和黏附机理[J]. 材料工程, 2013(3): 55-60.
Qiang Xiaohu, Zhang Hongxia, Wang Yanping, et al. Structure and adhesive mechanism of superhydrophobic alumina surface with high adhesive force[J]. Materials Engineering, 2013(3): 55-60.
[9]黄勇, 张平则, 魏东博, 等. γ-TiAl合金表面辉光等离子Ni-Cr共渗层的组织与性能[J]. 金属热处理, 2012, 37(3): 58-61.
Huang Yong, Zhang Pingze, Wei Dongbo, et al. Microstructure and properties of nickel-chromizing layer on γ-TiAl alloy surface by double-glow plasma technique[J]. Heat Treatment of Metals, 2012, 37(3): 58-61.
[10]程东, 高原, 唐光辉. 3Cr13不锈钢低温双辉等离子渗铬[J]. 金属热处理, 2009, 34(12): 58-60.
Cheng Dong, Gao Yuan, Tang Guanghui. Double-glow plasma chromizing at low temperature for 3Cr13 steel[J]. Heat Treatment of Metals, 2009, 34(12): 58-60.
[11]杨晶晶, 缪强, 梁文萍, 等. Ti-2AlNb基O相合金双辉等离子渗碳层摩擦磨损性能[J]. 金属热处理, 2013, 38(6): 110-113.
Yang Jingjing, Miu Qiang, Liang Wenping, et al. Friction and wear properties of double glow plasmacarburized layer of Ti2AlNb base O phase alloy[J]. Heat Treatment of Metals, 2013, 38(6): 110-113.
[12]Xue Y P, Wang S Q, Bi P, et al. Super-hydrophobic Co-Ni coating with high abrasion resistance prepared by electrodeposition[J]. Coatings, 2019, 9(4): 232-246.
[13]Ebert D, Bhushan B. Wear-resistant rose petal-effect surfaces with superhydrophobicity and high droplet adhesion using hydrophobic and hydrophilic nanoparticles[J]. Journal of Colloid & Interface Science, 2012, 384(1): 182-188.
[14]Yuan S, Lin N, Zeng Q, et al. Recent developments in research of double glow plasma surface alloying technology: A brief review[J]. Journal of Materials Research and Technology, 2020, 9(3): 6859-6882.
[15]Xue Y P, Wang S Q, Zhao G C, et al. Fabrication of Ni-Co coating by electrochemical deposition with high super-hydrophobic properties for corrosion protection[J]. Surface and Coatings Technology, 2019, 363: 352-361.
[16]Bhushan B, Her E K. Fabrication of superhydrophobic surfaces with high and low adhesion inspired from rose petal[J]. Langmuir, 2010, 26(11): 8207-8217.
[17]Lai D L, Kong G, Li X C, et al. Corrosion resistance of ZnO nanorod superhydrophobic coatings with rose petal effect or lotus leaf effect[J]. Journal of Nanoscience and Nanotechnology, 2019, 19(7): 3919-3928.
[18]Song Y, Liu Y, Jiang H, et al. Biomimetic super hydrophobic structured graphene on stainless steel surface by laser processing and transfer technology[J]. Surface and Coatings Technology, 2017, 328: 152-160.
[19]Lin X, Heo J, Choi M, et al. Simply realizing durable dual Janus superwettable membranes integrating underwater low-oil-adhesive with super-water-repellent surfaces for controlled oil-water permeation[J]. Journal of Membrane Science, 2019, 580: 248-255.
[20]Peng Y, Zhu W, Shen S, et al. Strain-induced surface micro/nanosphere structure: A new technique to design mechanically robust superhydrophobic surfaces with rose petal-like morphology[J]. Advanced Materials Interfaces, 2017, 4(20): 1700497-1700505.
[21]Su F, Yao K. Facile fabrication of superhydrophobic surface with excellent mechanical abrasion and corrosion resistance on copper substrate by a novel method[J]. ACS Appl Mater Interfaces, 2014, 6(11): 8762-8770.
[22]Liu Q, Chen D, Kang Z. One-step electrodeposition process to fabricate corrosion-resistant superhydrophobic surface on magnesium alloy[J]. Acs Applied Materials & Interfaces, 2015, 7(3): 1859-1867.
[23]Liu Y C, Zhang P Z, Wei D B, et al. Corrosion behavior of tantalum alloying on γ-TiAl by double-glow plasma surface metallurgy technique[J]. Surface and Interface Analysis, 2017, 49(7): 674-681.

高黏附性超疏水表面的制备及耐腐蚀性

Preparation and corrosion resistance of highly adhesive superhydrophobic surface

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