银铜箔轧制用银铜板的退火组织与性能

doi:10.13251/j.issn.0254-6051.2021.12.029

摘要/Abstract

摘要： 采用光学显微镜、电子背散射衍射技术、维氏硬度计和电化学工作站等研究了轧制银铜板在退火过程中的组织、织构演变规律及其对维氏硬度、耐腐蚀性能的影响。结果表明:轧制银铜板退火时,晶粒形态由轧态的长条状演变为等轴晶组织,且平均晶粒尺寸增大,织构类型由铜型织构、黄铜型织构、S织构和R织构等形变织构演变为立方织构和{025}<001>等退火织构;随退火温度的升高,银铜板维氏硬度减小,银铜板小角度晶界含量降低,∑3晶界含量升高,耐腐蚀性能先减弱后增强。银铜板在300 ℃保温10 min时,立方织构含量最多,硬度为60 HV0.3,耐腐蚀性能较好。

关键词: 银铜板, 显微组织, 织构, 硬度, 耐腐蚀性能

Abstract: Evolution of microstructure and microtexture, and their effects on Vickers hardness and corrosion resistance of rolled silver-copper plate during the annealing process were studied by means of optical microscope, electron backscattering diffraction technique, Vickers hardness tester and electrochemical workstation. The results show that during the annealing process, the average grain size increases. Moreover, the grain morphology evolves from rolled strip grains to equiaxed grains, at the same time, the texture type develops from deformed texture (copper texture, brass texture, S texture and R texture) to annealed texture (cube texture and {025}<001> texture). With the increase of annealing temperature, the content of small-angle grain boundary and the Vickers hardness of the silver-copper plate decrease, simultaneously, the content of ∑3 grain boundary increases, and the corrosion resistance first weakens and then increases. The content of cube texture is capable of reaching the highest when the silver-copper plate is heated at 300 ℃ for 10 min. Under this condition, the silver-copper plate exhibits excellent corrosion resistance, and the Vickers hardness reaches 60 HV0.3.

Key words: silver-copper plate, microstructure, texture, hardness, corrosion resistance

中图分类号:

TG146.1⁺1

孙玉梅, 王晓文, 宫本奎, 冯锐, 费翔昱, 赵维超. 银铜箔轧制用银铜板的退火组织与性能[J]. 金属热处理, 2021, 46(12): 180-186.

Sun Yumei, Wang Xiaowen, Gong Benkui, Feng Rui, Fei Xiangyu, Zhao Weichao. Microstructure and properties of annealed silver-copper plate for silver-copper foil rolling[J]. Heat Treatment of Metals, 2021, 46(12): 180-186.

参考文献

[1]Li J K, Ren X P, Zhang Y L, et al. Microstructural response of copper foil to a novel double-cross rolling process[J]. Journal of Materials Research and Technology, 2020, 9(6): 15153-15163.
[2]Li J K, Ren X P, Ling Z, et al. Improving bending property of copper foil by the combination of double-rolling and cross rolling[J]. Journal of Materials Research and Technology, 2020, 9(3): 6922-6927.
[3]吴恒, 张鸿, 吕佳峰, 等. 连续纤维晶纯铜高温短时退火的组织和性能[J]. 材料热处理学报, 2017, 38(1): 31-36.
Wu Heng, Zhang Hong, lü Jiafeng, et al. Microstructure and properties of pure copper with continuous fibrous crystal after annealing at high temperature for short time[J]. Transactions of Materials and Heat Treatment, 2017, 38(1): 31-36.
[4]Engler O, Knarbakk K. Temper rolling to control texture and earing in aluminium alloy AA 5050A[J]. Journal of Materials Processing Technology, 2020, 288: 116910.
[5]李万印, 陈亮维, 杨钢, 等. 1235铝合金铸轧坯料在加工过程中的织构演变[J]. 轻金属, 2016(9): 48-52.
Li Wanyin, Chen Liangwei, Yang Gang, et al. Texture evolution of cast rolling 1235 Al alloy blank during process[J]. Light Metals, 2016(9): 48-52.
[6]岳有成, 杨钢, 陈亮维, 等. 超薄双零铝箔用坯料铸轧-冷轧过程中晶粒取向演变规律[J]. 材料热处理学报, 2014, 35(9): 1-5.
Yue Youcheng, Yang Gang, Chen Liangwei, et al. Evolution of grain orientation in ultra-thin aluminum foil blank by casting-rolling and cold-rolling[J]. Transactions of Materials and Heat Treatment, 2014, 35(9): 1-5.
[7]王运雷. 退火过程中高纯铝箔微观组织演变及其再结晶行为的研究[D]. 重庆: 重庆大学, 2016.
Wang Yunlei. Research on the evolution of microstructures and recrystallization behavior of high purity aluminum foils during annealing processing[D]. Chongqing: Chongqing University, 2016.
[8]严旭东. 铜带冷轧润滑过程中的磨损与电化学腐蚀行为研究[D]. 北京: 北京科技大学, 2020.
Yan Xudong. Research on wear and electrochemical corrosion behavior of copper strip during cold rolling lubrication[D]. Beijing: University of Science and Technology Beijing, 2020.
[9]谢建新, 刘雪峰, 汪汐涌, 等. 一种高挠性超薄压延铜箔的成形方法: CN102716908B[P]. 2014-02-26.
[10]Mao Z N, Gu R C, Liu F, et al. Effect of equal channel angular pressing on the thermal-annealing-induced microstructure and texture evolution of cold-rolled copper[J]. Elsevier, 2016, 674: 186-192.
[11]夏柳, 徐春, 白清领, 等. 退火后终轧压下量对铝合金轧板织构和深冲性能的影响[J]. 上海金属, 2019, 41(2): 29-34.
Xia Liu, Xu Chun, Bai Qingling, et al. Effect of finishing rolling reduction on texture and deep drawability of rolled aluminum alloy sheet after annealing[J]. Shanghai Metals, 2019, 41(2): 29-34.
[12]Li Y Q, Chen L, Tang J W, et al. Effects of asymmetric feeder on microstructure and mechanical properties of high strength Al-Zn-Mg alloy by hot extrusion[J]. Journal of Alloys and Compounds, 2018, 749: 293-304.
[13]Liu W C, Morris J G. Comparison of the texture evolution in cold rolled DC and SC AA 5182 aluminum alloys[J]. Materials Science and Engineering A, 2003, 339(1): 183-193.
[14]李慧中, 高峰, 李鹏伟, 等. 退火温度对冷轧5083铝合金织构及塑性各向异性的影响[J]. 材料热处理学报, 2020, 41(5): 57-65.
Li Huizhong, Gao Feng, Li Pengwei, et al. Effect of annealing temperature on texture and plastic anisotropy of cold-rolled 5083 aluminum alloy[J]. Transactions of Materials and Heat Treatment, 2020, 41(5): 57-65.
[15]华连庚. 稀土电子铝箔制备工艺研究[D]. 包头: 内蒙古科技大学, 2009.
Hua Liangeng. Study on the preparation technology of the re-aluminum foil[D]. Baotou: Inner Mongolia University of Science and Technology, 2009.
[16]翟新生. 异步轧制高压电子铝箔织构演化行为及机制研究[D]. 沈阳: 东北大学, 2013.
Zhai Xinsheng. Study on texture evolution and mechanisms of cross shear rolled high voltage electronic aluminum foils[D]. Shenyang: Northeastern University, 2013.
[17]杨平. 电子背散射衍射技术及其应用[M]. 北京: 冶金工业出版社, 2007: 37-38.
[18]Wu X Y, Suo H L, Ji Y T, et al. Systematical analysis on the grain orientation evolution of pure nickel under plastic deformation by using in-situ EBSD[J]. Materials Science and Engineering A, 2020, 792: 139722.
[19]刘晓欢, 李彦生, 满意, 等. 高压扭转制备的Mg-Sm-Ca合金组织演变及时效硬化行为[J]. 材料导报, 2021, 35(6): 6120-6125.
Liu Xiaohuan, Li Yansheng, Man Yi, et al. Microstructure evolution and age-hardening behavior of Mg-Sm-Ca alloy processed by high pressure torsion[J]. Materials Reports, 2021, 35(6): 6120-6125.
[20]刘思萌, 商剑. 晶粒取向对金属材料摩擦及腐蚀性能影响的研究进展[J]. 润滑与密封, 2021, 46(10): 155-162.
Liu Simeng, Shang Jian. Research progress of grain orientation on friction and corrosion resistance of metal materials[J]. Lubrication Engineering, 2021, 46(10): 155-162.
[21]Zhang H M, Dong X H, Wang Q, et al. Micro-bending of metallic crystalline foils by non-local dislocation density based crystal plasticity finite element model[J]. Transactions of Nonferrous Metals Society of China, 2013, 23(11): 3362-3371.
[22]周蕾, 史庆南, 蔡晓兰, 等. 大变形退火超细晶铜中的晶界特征分布[J]. 材料热处理学报, 2017, 38(6): 25-30.
Zhou Lei, Shi Qingnan, Cai Xiaolan, et al. Grain boundary characteristics distribution of ultra-fine grained copper prepared by severe plastic deformation and annealing[J]. Transactions of Materials and Heat Treatment, 2017, 38(6): 25-30.
[23]He C L, Li R, Meng X D, et al. Effect of quenching condition on corrosion behavior of 6063 Al alloy[C]//Proceedings of the 6^th International Conference on Manufacturing Science and Engineering. 2015: 1873-1876.