球磨工艺和退火处理对机械合金化制备FeCrNiMo高熵合金粉末微观结构的影响

doi:10.13251/j.issn.0254-6051.2025.04.004

金属热处理 ›› 2025, Vol. 50 ›› Issue (4): 28-33.DOI: 10.13251/j.issn.0254-6051.2025.04.004

球磨工艺和退火处理对机械合金化制备FeCrNiMo高熵合金粉末微观结构的影响

伽亮亮¹, 张金伟², 赵奔奔², 张曼^1,2

1.湖北工程学院化学与材料科学学院, 湖北孝感 432000;
2.武汉轻工大学土木工程与建筑学院, 湖北武汉 430023

收稿日期:2024-11-14 修回日期:2025-02-20 发布日期:2025-06-13
通讯作者: 张曼,讲师,博士,E-mail:manzhangmz@126.com
作者简介:伽亮亮(1986—),男,硕士,主要研究方向为材料加工,E-mail:qieliang1010@163.com。
基金资助:
国家自然科学基金(52001118);湖北省教育厅科学研究计划科技创新服务项目(F2023019);孝感市自然科学计划项目(XGKJ2022010086)

Influence of ball milling process and annealing treatment on microstructure of FeCrNiMo high-entropy alloy powder via mechanical alloying

Qie Liangliang¹, Zhang Jinwei², Zhao Benben², Zhang Man^1,2

1. School of Chemistry and Materials Science, Hubei Engineering University, Xiaogan Hubei 432000, China;
2. School of Civil Engineering and Architecture, Wuhan Polytechnic University, Wuhan Hubei 430023, China

Received:2024-11-14 Revised:2025-02-20 Published:2025-06-13

摘要/Abstract

摘要： 采用机械合金化制备FeCrNiMo高熵合金粉末,研究了球磨过程控制剂添加量、球磨时间和退火处理对FeCrNiMo高熵合金粉末的制备和其微观结构的影响。结果表明,在球磨过程中加入适量质量分数的无水乙醇可以提升高熵合金粉末经机械合金化后的出粉率。随着球磨时间的延长,衍射峰峰位出现偏移,峰形变宽,高熵合金粉末发生冷焊现象。当球磨50 h时,峰形基本不再发生改变,高熵合金粉末颗粒分布较均匀,且具有较好的细化效果。FeCrNiMo高熵合金粉末经400、500和600 ℃退火1 h后,粉末相组成未发生改变,仍由FCC+BCC相组成。随着退火温度的继续升高,高熵合金粉末中析出Co₇Mo₆和Mo_1.24Ni_0.76相,且粉末颗粒团聚增大。

关键词: 高熵合金, 机械合金化, 球磨工艺, 退火

Abstract: FeCrNiMo high-entropy alloy powder was prepared via mechanical alloying, and the effects of ball milling control agent content, milling time and annealing on the preparation and microstructure of the FeCrNiMo high-entropy alloy powder were investigated. The results show that the addition of an appropriate mass fraction of anhydrous ethanol during the ball milling process improves the powder productivity after mechanical alloying of the high-entropy alloy powder. With the extension of ball milling time, the diffraction peak position shifts, and the peak broadens due to the occurrence of cold welding in the high-entropy alloy powder. After ball milling for 50 h, the peak shape nearly remains unchanged, the distribution of high-entropy alloy powder particles becomes more uniform, and a good refinement effect is achieved. After annealing at 400 ℃, 500 ℃, and 600 ℃ for 1 h, the phase composition of the FeCrNiMo high-entropy alloy powder remains unchanged and still consists of FCC and BCC phases. With the annealing temperature further increases, Co₇Mo₆ and Mo_1.24Ni_0.76 phases precipitate in the high-entropy alloy powder, and the powder particles agglomerate and increase in size.

Key words: high-entropy alloy, mechanical alloying, ball milling process, annealing

中图分类号:

TG135

伽亮亮, 张金伟, 赵奔奔, 张曼. 球磨工艺和退火处理对机械合金化制备FeCrNiMo高熵合金粉末微观结构的影响[J]. 金属热处理, 2025, 50(4): 28-33.

Qie Liangliang, Zhang Jinwei, Zhao Benben, Zhang Man. Influence of ball milling process and annealing treatment on microstructure of FeCrNiMo high-entropy alloy powder via mechanical alloying[J]. Heat Treatment of Metals, 2025, 50(4): 28-33.

参考文献

[1] Zhang L S, Ma G L, Fu L C, et al. Recent progress in high-entropy alloys[J]. Advanced Materials Research, 2013, 631: 227-232.
[2] 李天昕, 王书道, 卢一平, 等. 高熵合金材料研究进展与展望[J]. 中国工程科学, 2023, 25(3): 170-181.
Li Tianxin, Wang Shudao, Lu Yiping, et al. Research progress and prospect of high-entropy alloy materials[J]. Strategic Study of CAE, 2023, 25(3): 170-181.
[3] Tokarewicz M, Gradzka-Dahlke M. Review of recent research on AlCoCrFeNi high-entropy alloy[J]. Metals, 2021, 11(8): 1302.
[4] Alcalá M D, Real C, Fombella I, et al. Effects of milling time, sintering temperature, Al content on the chemical nature, microhardness and microstructure of mechanochemically synthesized FeCoNiCrMn high entropy alloy[J]. Journal of Alloys and Compounds, 2018, 749: 834-843.
[5] Huang W, Wang X, Qiao J, et al. Microstructures and mechanical properties of TiZrHfNbTaW_x refractory high entropy alloys[J]. Journal of Alloys and Compounds, 2022, 914: 165187.
[6] 张艳, 许波, 许林杰, 等. Mo元素对CoCrFeMnNi高熵合金组织与性能的影响[J]. 江苏科技大学学报, 2023, 37(2): 24-28.
Zhang Yan, Xu Bo, Xu Linjie, et al. Effects of Mo on the microstructure and properties of CoCrFeMnNi high entropy alloys[J]. Journal of Jiangsu University of Science and Technology, 2023, 37(2): 24-28.
[7] Yang C C, Chau J L H, Weng C J, et al. Preparation of high-entropy AlCoCrCuFeNiSi alloy powders by gas atomization process[J]. Materials Chemistry and Physics, 2017, 202: 151-158.
[8] Alshataif Y A, Sivasankaran S, Al-Mufadi F A, et al. Manufacturing methods, microstructural and mechanical properties evolutions of high-entropy alloys: A review[J]. Metals and Materials International, 2020, 26: 1099-1133.
[9] Vaidya M, Muralikrishna G M, Murty B S. High-entropy alloys by mechanical alloying: A review[J]. Journal of Materials Research, 2019, 34(5): 664-686.
[10] 张勇. 高熵合金的发现和发展[J]. 四川师范大学学报, 2022, 45(6): 711-722, 708.
Zhang Yong. Discovery and development of high entropy alloys[J]. Journal of Sichuan Normal University, 2022, 45(6): 711-722, 708.
[11] 张超, 刘杰, 王晓花, 等. 烧结方式对CoCrNi中熵合金组织及力学性能的影响[J]. 稀有金属材料与工程, 2022, 51(7): 2673-2680.
Zhang Chao, Liu Jie, Wang Xiaohua, et al. Effect of sintering methods on microstructure and mechanical properties of CoCrNi medium entropy alloy[J]. Rare Metal Materials and Engineering, 2022, 51(7): 2673-2680.
[12] 郭宝昌, 姜凤阳, 王俊勃, 等. 退火工艺对FeCrMnNiAl_0.1高熵合金显微组织及力学性能的影响[J]. 金属热处理, 2023, 48(5): 246-252.
Guo Baochang, Jiang Fengyang, Wang Junbo, et al. Effect of annealing process on microstructure and mechanical properties of FeCrMnNiAl_0.1 high-entropy alloy[J]. Heat Treatment of Metals, 2023, 48(5): 246-252.
[13] Huang M, Jiang J, Wang Y, et al. Effects of milling process parameters and PCAs on the synthesis of Al_0.8Co_0.5Cr_1.5CuFeNi high entropy alloy powder by mechanical alloying[J]. Materials and Design, 2022, 217: 110637.
[14] Yang S, Liu G, Zhong Y. Revisit the VEC criterion in high entropy alloys (HEAs) with high-throughput ab initio calculations: A case study with Al-Co-Cr-Fe-Ni system[J]. Journal of Alloys and Compounds, 2022, 916: 165477.
[15] Ogura M, Fukushima T, Zeller R, et al. Structure of the high-entropy alloy Al_xCrFeCoNi: FCC versus BCC[J]. Journal of Alloys and Compounds, 2017, 715: 454-459.
[16] Zhang B, Duan Y, Cui Y, et al. Improving electromagnetic properties of FeCoNiSi0.4Al0.4 high entropy alloy powders via their tunable aspect ratio and elemental uniformity[J]. Materials and Design, 2018, 149: 173-183.
[17] Qiao Y, Tang Y, Li S, et al. Preparation of TiZrNbTa refractory high-entropy alloy powder by mechanical alloying with liquid process control agents[J]. Intermetallics, 2020, 126: 106900.
[18] Zhang Z, Wang Q, Mu D, et al. Microstructure evolution and mechanical properties of CoCrFeNiAl_0.3 high entropy alloy produced by ball milling in combination with thermomechanical consolidation[J]. Materials Characterization, 2022, 187: 111833.
[19] Liu X, Duan Y, Guo Y, et al. Microstructure design of high-entropy alloys through a multistage mechanical alloying strategy for temperature-stable megahertz electromagnetic absorption[J]. Nano-Micro Letters, 2022, 14(1): 142.
[20] Wang H T, Li C J, Yang G J, et al. Cold spraying of Fe/Al powder mixture: Coating characteristics and influence of heat treatment on the phase structure[J]. Applied Surface Science, 2008, 255(5): 2538-2544.
[21] Chen Y L, Hu Y H, Hsieh C A, et al. Competition between elements during mechanical alloying in an octonary multi-principal-element alloy system[J]. Journal of Alloys and Compounds, 2009, 481(1/2): 768-775.
[22] Cao Yuankui, Liu Yong, Liu Bin, et al. Effects of Al and Mo on high temperature oxidation behavior of refractory high entropy alloys[J]. Transactions of Nonferrous Metals Society of China, 2019, 29(7): 1476-1483.
[23] Huan C, He Y, Su Q, et al. Properties of AlFeNiCrCoTi_0.5 high-entropy alloy particle-reinforced 6061Al composites prepared by extrusion[J]. Metals, 2022, 12(8): 1325.
[24] Zhuang Y X, Xue H D, Chen Z Y, et al. Effect of annealing treatment on microstructures and mechanical properties of FeCoNiCuAl high entropy alloys[J]. Materials Science and Engineering A, 2013, 572: 30-35.
[25] Niu B, Ji W, Li N, et al. Alloying and thermal behaviour of CoCrFeNiMn_0.5Ti_0.5 high-entropy alloy synthesised by mechanical alloying[J]. Materials Science and Technology, 2016, 32(1): 94-98.

球磨工艺和退火处理对机械合金化制备FeCrNiMo高熵合金粉末微观结构的影响

Influence of ball milling process and annealing treatment on microstructure of FeCrNiMo high-entropy alloy powder via mechanical alloying

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