关键词: 新型铁镍基高温合金, 高温蠕变性能, 蠕变寿命预判, 组织表征

Abstract: A novel Fe-Ni-based superalloy, intended for ultra-supercritical thermal power generating units, was evaluated under constant load conditions at 700 ℃ with varying stress levels of 250 MPa and 200 MPa. The service limit and creep life of the alloy were predicted, and the microstructure evolution during creep was analyzed. The results indicate that the creep life of the alloy at 700 ℃/250 MPa and 700 ℃/200 MPa is 2378 h and 12 716 h, respectively. Based on the Larson-Miller equation, the alloy can withstand stresses of approximately 152 MPa after 100 000 h and 134 MPa after 260 000 h at 700 ℃, fully meeting the service requirements (stress of 35 MPa, creep life of 100 000 h). Microstructure analysis reveals that high-density dislocations are distributed in the 700 ℃/250 MPa specimen, whereas fewer dislocations are observed in the 700 ℃/200 MPa specimen. The MC carbides with larger size within the grains predominantly exhibit blocky or rod-like morphologies, with faster growth rates under higher stress conditions. The smaller M₂₃C₆ carbides at grain boundaries precipitate primarily in chain form, and their width increases with prolonged creep exposure. The γ′ phase within the grains remains spherical but undergoes coarsening during creep. Notably, some grain boundary γ′ phases exhibit abnormal growth, forming PFZs/DCZs, which adversely affect the alloy's high-temperature creep performance.

Key words: novel Fe-Ni based superalloy, high temperature creep property, creep life prediction, microstructure characterization