固溶温度及时间对高氮不锈钢耐蚀性能的影响

doi:10.13251/j.issn.0254-6051.2022.08.023

金属热处理 ›› 2022, Vol. 47 ›› Issue (8): 141-147.DOI: 10.13251/j.issn.0254-6051.2022.08.023

固溶温度及时间对高氮不锈钢耐蚀性能的影响

张存帅^1,2, 刘吉猛^1,2, 李皓^1,2, 赵定国^1,2, 王书桓², 倪国龙^1,2

1.华北理工大学冶金与能源学院, 河北唐山 063210;
2.唐山市特种冶金及材料制备重点实验室, 河北唐山 063210

收稿日期:2022-03-15 修回日期:2022-06-02 出版日期:2022-08-25 发布日期:2022-09-19
通讯作者: 刘吉猛,讲师,博士,E-mail:1094147789@qq.com
作者简介:张存帅(1997—),男,硕士研究生,主要研究方向为高强耐蚀海工用钢,E-mail:2621782676@qq.com。
基金资助:
河北省科技计划(20311003D);国家自然科学基金(51774139);河北省自然科学基金(E2020209014);河北省自然科学基金重点项目(E2019209597)

Effect of solution treatment temperature and time on corrosion resistance of high nitrogen stainless steel

Zhang Cunshuai^1,2, Liu Jimeng^1,2, Li Hao^1,2, Zhao Dingguo^1,2, Wang Shuhuan², Ni Guolong^1,2

1. College of Metallurgy and Energy, North China University of Science and Technology, Tangshan Hebei 063210, China;
2. Tangshan Key Laboratory of Special Metallurgy and Materials Preparation, Tangshan Hebei 063210, China

Received:2022-03-15 Revised:2022-06-02 Online:2022-08-25 Published:2022-09-19

摘要/Abstract

摘要： 使用真空感应炉+电渣重熔炉在0.08 MPa下制备了氮含量0.54%的高氮无镍奥氏体不锈钢,热轧后分别在800、900、1000、1100、1200 ℃下保温不同时间,研究在不同固溶工艺下试验钢的显微组织和耐蚀性。采用动电位极化曲线研究不同固溶工艺下高氮不锈钢在3.5%NaCl溶液中的耐蚀性能,并在6%FeCl₃溶液中浸泡8 d后计算其质量损失率和腐蚀速率。结果表明,固溶对高氮不锈钢组织及耐蚀性能的影响很大,经1000、1100 ℃热处理后的试验钢为单一的奥氏体组织;未经热处理和经800、900 ℃热处理的试验钢组织中存在析出相Cr₂N;经1200 ℃热处理的试验钢从奥氏体中析出了铁素体组织;1100 ℃下保温1 h的试验钢耐蚀性最好,腐蚀速率仅为1.35×10^-5 g·cm^-2·h^-1;800 ℃保温3 h后试验钢的耐蚀性最差,腐蚀速率高达8.18×10^-4 g·cm^-2·h^-1;而316L不锈钢的耐蚀性能介于两者之间,腐蚀速率为1.24×10^-4 g·cm^-2·h^-1。

关键词: 高氮奥氏体不锈钢, 热处理, 极化曲线, 腐蚀速率

Abstract: High nitrogen nickel-free austenitic stainless steel with 0.54%N was prepared by vacuum induction furnace+electroslag remelting furnace under 0.08 MPa. After hot rolling, the tested steel was solution treated at 800, 900, 1000, 1100 and 1200 ℃ for different time, respectively. The microstructure and corrosion resistance of the tested steel were studied with different solution treatment processes, in which the corrosion resistance was studied in 3.5% NaCl solution by potentiodynamic polarization curve, and the mass loss ratio and corrosion rate were calculated after soaking in 6% FeCl₃ solution for 8 days. The results show that solution treatment has a great influence on microstructure and corrosion resistance of the high nitrogen stainless steel. The tested steel after solution treatment at 1000 ℃ and 1100 ℃ has a single austenite structure. The precipitation phase Cr₂N exists in the microstructure of the tested steel without heat treatment and in that solution treated at 800 ℃ and 900 ℃. In the tested steel solution treated at 1200 ℃, the ferrite structure is precipitated from the austenite. The tested steel heated at 1100 ℃ for 1 h has the best corrosion resistance, and the corrosion rate is only 1.35×10^-5 g·cm^-2·h^-1. While the corrosion resistance of the tested steel heated at 800 ℃ for 3 h is the worst, the corrosion rate is as high as 8.18×10^-4 g·cm^-2·h^-1. The corrosion resistance of 316L stainless steel is somewhere in between, and the corrosion rate is 1.24×10^-4 g·cm^-2·h^-1.

Key words: high nitrogen austenitic stainless steel, heat treatment, polarization curve, corrosion rate

中图分类号:

TF764⁺.1

张存帅, 刘吉猛, 李皓, 赵定国, 王书桓, 倪国龙. 固溶温度及时间对高氮不锈钢耐蚀性能的影响[J]. 金属热处理, 2022, 47(8): 141-147.

Zhang Cunshuai, Liu Jimeng, Li Hao, Zhao Dingguo, Wang Shuhuan, Ni Guolong. Effect of solution treatment temperature and time on corrosion resistance of high nitrogen stainless steel[J]. Heat Treatment of Metals, 2022, 47(8): 141-147.

参考文献

[1]Li Huabing, Jiao Weichao, Feng Hao, et al. Influence of austenitizing temperature on the microstructure and corrosion resistance of 55Cr18Mo1VN high-nitrogen plastic mould steel[J]. Acta Metallurgica Sinica (English Letters), 2016, 29(12): 1148-1160.
[2]Han Chao, Wei Yinghua, Zhang Haifeng, et al. Corrosion resistance and electrochemical behaviour of amorphous Ni_84.9Cr_7.4Si_4.2Fe_3.5 alloy in alkaline and acidic solutions[J]. Acta Metallurgica Sinica (English Letters), 2019, 32(11): 1421-1436.
[3]何壮, 王兴平, 刘子涵, 等. 316L和HR-2不锈钢在盐酸液膜环境中的钝化与点蚀[J]. 中国腐蚀与防护学报, 2020, 40(1): 17-24.
He Zhuang, Wang Xingping, Liu Zihan, et al. Passivation and pitting of 316L and HR-2 stainless steel in hydrochloric acid liquid membrane environment[J]. Journal of Chinese Society Corrosion and Protection, 2020, 40(1): 17-24.
[4]王晶, 尚新春, 路民旭, 等. 316L不锈钢在不同环境中点蚀形核研究[J]. 材料工程, 2015, 43(9): 12-18.
Wang Jing, Shang Xinchun, Lu Minxu, et al. Pitting nucleation of 316L stainless steel in different environments[J]. Journal of Materials Engineering, 2015, 43(9): 12-18.
[5]吴浩, 徐桂芳, 严羽, 等. 新型高氮低镍奥氏体不锈钢的点蚀性能[J]. 金属热处理, 2015, 40(12): 11-16.
Wu Hao, Xu Guifang, Yan Yu, et al. Pitting corrosion resistance of a new high nitrogen and low nickel austenitic stainless steel[J]. Heat Treatment of Metals, 2015, 40(12): 11-16.
[6]陈晓秋, 王智勇, 尚峰, 等. 固溶处理对06Cr23Mn22MoN高氮无镍奥氏体不锈钢耐腐蚀性能的影响[J]. 材料热处理学报, 2019, 40(9): 83-88.
Chen Xiaoqiu, Wang Zhiyong, Shang Feng, et al. Effect of solution treatment on corrosion resistance of 06Cr23Mn22MoN high nitrogen nickel-free austenitic stainless steel[J]. Transactions of Materials and Heat Treatment, 2019, 40(9): 83-88.
[7]张秀丽, 陈明昕, 刘振宝, 等. 热处理工艺对15-5PH沉淀硬化不锈钢的力学性能与耐蚀性的影响[J]. 钢铁, 2014, 49(8): 70-75.
Zhang Xiuli, Chen Mingxin, Liu Zhenbao, et al. Effect of heat treatment on mechanical properties and corrosion resistance of 15-5PH stainless steel[J]. Iron and Steel, 2014, 49(8): 70-75.
[8]Shi Feng, Gao Ruohan, Guan Xianjun, et al. Application of grain boundary engineering to improve intergranular corrosion resistance in a Fe-Cr-Mn-Mo-N high-nitrogen and nickel-free austenitic stainless steel[J]. Acta Metallurgica Sinica (English Letters), 2020, 33(6): 789-798.
[9]黄桂桥, 金威贤, 侯文泰. 不锈钢在海水中的耐蚀性与腐蚀电位的关系[J]. 中国腐蚀与防护学报, 2000, 4(1): 35-40.
Huang Guiqiao, Jin Weixian, Hou Wentai. A study on relationship between corrosion resistance and corrosion potential of stainless steels in seawater[J]. Journal of Chinese Society Corrosion and Protection, 2000, 4(1): 35-40.
[10]黄伟林, 向红亮, 陈彤, 等. 氮含量对29Cr铸造超级双相不锈钢深冷组织和性能的影响[J]. 腐蚀与防护, 2015, 36(8): 711-716.
Huang Weilin, Xiang Hongliang, Chen Tong, et al. Effects of nitrogen on microstructure and properties of 29Cr cast super duplex stainless steel after cryogenic treatment[J]. Corrosion and Protection, 2015, 36(8): 711-716.

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固溶温度及时间对高氮不锈钢耐蚀性能的影响

Effect of solution treatment temperature and time on corrosion resistance of high nitrogen stainless steel

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