金属热处理 ›› 2021, Vol. 46 ›› Issue (3): 86-89.DOI: 10.13251/j.issn.0254-6051.2021.03.017

• 工艺研究 • 上一篇    下一篇

冷轧Cu-Cr-Zr-Co-Si合金的时效行为

帅歌旺, 王智, 刘金辉, 周清泉   

  1. 南昌航空大学 航空制造与工程学院, 江西 南昌 330063
  • 收稿日期:2020-11-02 出版日期:2021-03-25 发布日期:2021-05-08
  • 作者简介:帅歌旺(1978—),男,副教授,博士,主要研究方向为新型金属材料设计及其制备工艺,E-mail:shuaigw@nchu.edu.cn
  • 基金资助:
    国家自然科学基金(51305193)

Aging behavior of cold-rolled Cu-Cr-Zr-Co-Si alloy

Shuai Gewang, Wang Zhi, Liu Jinhui, Zhou Qingquan   

  1. School of Aeronautical Manufacturing Engineering, Nanchang Hangkong University, Nanchang Jiangxi 330063, China
  • Received:2020-11-02 Online:2021-03-25 Published:2021-05-08

摘要: 通过测量Cu-Cr-Zr-Co-Si冷轧合金在等温时效过程中导电率的动态变化,基于合金导电性能与析出相转化率间的近似线性关系,建立了不同冷变形量下合金时效析出过程的动力学Avrami方程及曲线,在此基础上分析了再结晶与时效析出的相互影响。结果表明:Cu-Cr-Zr-Co-Si合金形变时效过程中,随变形量和时效时间的增加,导电率及析出相转化率均增加,这是时效过程中再结晶与时效析出相互影响、共同作用的结果。随冷变形量增加,强化相析出进程明显加快,但时效析出没有明显阻止或延缓再结晶软化过程的发生,因此大冷变形+短时时效使合金获得更高的硬度峰值,但无法同时获得最优的导电性能。只有在时效析出提前于再结晶启动,且形成的第二相对再结晶存在明显阻碍的前提下,采用冷变形+时效工艺,时效强化型铜合金才能达到最佳效果。

关键词: Cu-Cr-Zr-Co-Si合金, 形变时效, 再结晶, 析出, 导电率, 硬度

Abstract: By measuring the dynamic changes of the electrical conductivity of cold-rolled Cu-Cr-Zr-Co-Si alloy during isothermal aging, based on the approximate linear correlation between the electrical conductivity of the precipitation-strengthened alloy and the transformation ratio of precipitation transformation, the Avrami kinetic equations and curves of the aging precipitation process of the alloy with different cold deformation were established, on which the interaction between recrystallization and aging precipitation was analyzed. The results show that the electrical conductivity and transformation ratio of precipitation transformation of the alloy increase with the increase of deformation and aging time, which is the result of interaction of recrystallization and aging precipitation during aging. With the increase of cold deformation, the precipitation of strengthening phase is obviously accelerated, but the aging precipitation does not significantly prevent or delay the recrystallization softening process. Therefore, heavy cold deformation and short-term aging can lead to higher hardness peaks, but the optimum conductivity can't be obtained at the same time. Only on the premise that the precipitation starts earlier than the recrystallization, and the precipitates can significantly prevent the recrystallization, the best effect can be achieved by using the combined deformation and aging.

Key words: Cu-Cr-Zr-Co-Si alloy, deformation aging, recrystallization, precipitation, electrical conductivity, hardness

中图分类号: