瓷质氧化预处理对6061铝合金弱酸性介质中微弧氧化膜的影响

doi:10.13251/j.issn.0254-6051.2021.03.006

金属热处理 ›› 2021, Vol. 46 ›› Issue (3): 28-32.DOI: 10.13251/j.issn.0254-6051.2021.03.006

瓷质氧化预处理对6061铝合金弱酸性介质中微弧氧化膜的影响

伍宇昊, 魏晓伟, 谢晓伟

西华大学材料科学与工程学院, 四川成都 610039

收稿日期:2020-11-20 出版日期:2021-03-25 发布日期:2021-05-08
通讯作者: 魏晓伟,教授,博士,E-mail:weixiaowei90@yeah.net
作者简介:伍宇昊(1990—),男,硕士研究生,主要研究方向为铝合金微弧氧化膜层,E-mail:wuyh002@163.com。
基金资助:
四川省重点学科材料加工工程项目(SZD0502-09);四川省重点学科平台项目(SZD1112-1)

Effect of ceramic anodizing pretreatment on micro-arc oxidation film of 6061 aluminum alloy in weak-acid electrolyte

Wu Yuhao, Wei Xiaowei, Xie Xiaowei

School of Materials Science and Engineering, Xihua University, Chengdu Sichuan 610039, China

Received:2020-11-20 Online:2021-03-25 Published:2021-05-08

摘要/Abstract

摘要： 以6061铝合金为研究对象,对其在弱酸性介质中的微弧氧化膜的成分及性能进行了分析,探讨瓷质氧化预处理对微弧氧化膜的影响。结果表明:在弱酸性介质中,6061铝合金瓷质氧化预处理+微弧氧化膜的主要成分是γ-Al₂O₃和α-Al₂O₃,同时由于残留的瓷质氧化膜,无定型的Al₂O₃也存在于氧化膜中;其厚度和硬度分别为25.3 μm、1690 HV0.1,对比未预处理的微弧氧化膜,瓷质氧化预处理可显著提高氧化膜的厚度、硬度及耐腐蚀性。

关键词: 微弧氧化, 6061铝合金, 瓷质氧化预处理

Abstract: Taking 6061 aluminum alloy as the research object, the composition and performance of its micro-arc oxidation (MAO) film in weak-acid electrolyte were analyzed, and the influence of ceramic anodizing pretreatment on the MAO film was discussed. The results show that in weak-acid electrolyte, the 6061 aluminum alloy MAO film with ceramic anodizing pretreatment is mainly composed of γ-Al₂O₃ and α-Al₂O₃, while amorphous Al₂O₃ also exists due to the residual ceramic anodizing film. Compared with the non-pretreated MAO film, the ceramic anodizing pretreatment can significantly increase the thickness, hardness and corrosion resistance of the oxidation film, of which the thickness and hardness after the pretreatment are 25.3 μm and 1690 HV0.1, respectively.

Key words: micro-arc oxidation, 6061 aluminum alloy, ceramic anodizing pretreatment

中图分类号:

TG146.21

伍宇昊, 魏晓伟, 谢晓伟. 瓷质氧化预处理对6061铝合金弱酸性介质中微弧氧化膜的影响[J]. 金属热处理, 2021, 46(3): 28-32.

Wu Yuhao, Wei Xiaowei, Xie Xiaowei. Effect of ceramic anodizing pretreatment on micro-arc oxidation film of 6061 aluminum alloy in weak-acid electrolyte[J]. Heat Treatment of Metals, 2021, 46(3): 28-32.

参考文献

[1] Huang H J,Wei X W,Yang J X,et al.Influence of surface micro grooving pretreatment on MAO process of aluminum alloy[J].Applied Surface Science,2016,389:1175-1181.
[2] Arunnellaiappan T,Ashfaq M,Krishna L R,et al.Fabrication of corrosion-resistant Al₂O₃-CeO₂ composite coating on AA7075 via plasma electrolytic oxidation coupled with electrophoretic deposition[J].Ceramics International,2016,42(5):5897-5905.
[3] Shen D,Li G,Guo C,et al.Microstructure and corrosion behavior of micro-arc oxidation coating on 6061 aluminum alloy pre-treated by high-temperature oxidation[J].Applied Surface Science,2013,287:451-456.
[4] Wen L,Wang Y,Zhou Y,et al.Microstructure and corrosion resistance of modified 2024 Al alloy using surface mechanical attrition treatment combined with microarc oxidation process[J].Corrosion Science,2011,53(1):473-480.
[5] Curran J A,Clyne T W.Thermo-physical properties of plasma electrolytic oxide coatings on aluminium[J].Surface and Coatings Technology,2005,199(2/3):168-176.
[6] Cheng Y L,Xue Z G,Wang Q,et al.New findings on properties of plasma electrolytic oxidation coatings from study of an Al-Cu-Li alloy[J].Electrochimica Acta,2013,107:358-378.
[7] Cheng Y,Wang T,Li S,et al.The effects of anion deposition and negative pulse on the behaviours of plasma electrolytic oxidation (PEO)—A systematic study of the PEO of a Zirlo alloy in aluminate electrolytes[J].Electrochimica Acta,2017,225:47-68.
[8] 郝建民,李波,王利捷,等.弱酸性介质中铝合金微弧氧化研究[J].轻合金加工技术,2005,33(6):32-34.
Hao Jianmin,Li Bo,Wang Lijie,et al.Study on the micro-arc oxidation of aluminum alloy in weak-acid electrolyte[J].Light Alloy Fabrication Technology,2005,33(6):32-34.
[9] Dehnavi V,Luan B L,Shoesmith D W,et al.Effect of duty cycle and applied current frequency on plasma electrolytic oxidation (PEO) coating growth behavior[J].Surface and Coatings Technology,2013,226:100-107.
[10] Curran J A,Kalkanc H,Magurova Y,et al.Mullite-rich plasma electrolytic oxide coatings for thermal barrier applications[J].Surface and Coatings Technology,2007,201(21):8683-8687.
[11] Al Bosta M M S,Ma K J.Influence of electrolyte temperature on properties and infrared emissivity of MAO ceramic coating on 6061 aluminum alloy[J].Infrared Physics and Technology,2014,67:63-72.
[12] Matykina E,Arrabal R,Skeldon P,et al.AC PEO of aluminium with porous alumina precursor films[J].Surface and Coatings Technology,2010,205(6):1668-1678.
[13] 陈梁,廖重重.6061铝合金瓷质阳极氧化工艺研究[J].浙江化工,2016,47(4):31-34.
Chen Liang,Liao Chongchong.Study of ceramic anodizing of 6061 aluminum alloy[J].Zhejiang Chemical Industry,2016,47(4):31-34.
[14] Tillous K,Toll-Duchanoy T,Bauer-Grosse E,et al.Microstructure and phase composition of microarc oxidation surface layers formed on aluminium and its alloys 2214-T6 and 7050-T74[J].Surface and Coatings Technology,2009,203(19):2969-2973.
[15] Zhu L,Guo Z,Zhang Y,et al.A mechanism for the growth of a plasma electrolytic oxide coating on Al[J].Electrochimica Acta,2016,208:296-303.

瓷质氧化预处理对6061铝合金弱酸性介质中微弧氧化膜的影响

Effect of ceramic anodizing pretreatment on micro-arc oxidation film of 6061 aluminum alloy in weak-acid electrolyte

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