金属热处理 ›› 2020, Vol. 45 ›› Issue (7): 73-77.DOI: 10.13251/j.issn.0254-6051.2020.07.015

• 工艺研究 • 上一篇    下一篇

固溶时效处理对TC20钛合金α相演变和硬度的影响

吴立凡1, 李涛2, 李振亮2   

  1. 1. 包头钢铁职业技术学院 冶金化工系, 内蒙古 包头 014010;
    2. 内蒙古科技大学 材料与冶金学院, 内蒙古 包头 014010
  • 收稿日期:2019-12-05 出版日期:2020-07-25 发布日期:2020-09-07
  • 作者简介:吴立凡(1974—), 女, 高级讲师, 硕士, 主要研究方向为合金钢冶炼等, E-mail:wuhuangmi20547@126.com
  • 基金资助:
    国家自然科学基金(51364032)

Effect of solid solution and aging on α-phase microstructure evolution and hardness of TC20 titanium alloy

Wu Lifan1, Li Tao2, Li Zhenliang2   

  1. 1. Department of Metallurgy and Chemical Engineering, Baotou Iron and Steel Vocational College, Baotou Inner Mongolia 014010, China;
    2. College of Materials and Metallurgy, Inner Mongolia University of Science and Technology, Baotou Inner Mongolia 014010, China
  • Received:2019-12-05 Online:2020-07-25 Published:2020-09-07

摘要: 采用SEM、TEM、XRD和硬度等技术对先固溶(840 ℃×0.5 h)后不同时效(460 ℃×4 h;320 ℃×15 min→460 ℃×4 h;320 ℃×10 min;460 ℃×10 min)热处理工艺的TC20合金试样进行了观察与表征,研究TC20合金的α相对时效过程中β→α相转变。结果表明:热轧态组织由α相与β相共同组成,固溶态组织相中生成了许多小尺寸α相。采用460 ℃×4 h进行处理试样内形成了片状分布的α相,采用320 ℃×15 min→460 ℃× 4 h处理试样内形成了具有更小长宽比的α相,并且该试样内的大部分α相尺寸均接近100 nm。两种时效方法形成的第二相都是α相,采用320 ℃×15 min→460 ℃×4 h处理具有尺寸更加细小的α相。当温度到达460 ℃时更多α相可以通过ω相进行形核,从而在β基体上形成致密均匀分布状态。采用320 ℃×15 min→460 ℃×4 h处理后合金中的ω相已不存在,同时析出了更多的α相,合金硬度高达503 HV,显著高于β基体的硬度,α相可以促进合金硬度的大幅提升。

关键词: TC20合金, 时效, α相, 硬度, 组织演变

Abstract: TC20 alloy specimens treated by different heat treatment processes, as well as first initial solution (840 ℃× 0.5 h) and then different aging treatment (460 ℃× 4 h, 320 ℃× 15 min→460 ℃× 4 h, 320 ℃× 10 min, 460 ℃× 10 min) were tested and characterized by SEM, TEM, XRD and hardness tester,and β→αphase transformation of TC20 alloy during α relative aging was studied. The results show that the hot rolled microstructure is composed of α and β phase, and many small α phases are formed in the solid solution structure. The lamellar-distributed α phase in the specimen is formed at 460 ℃ for 4 h, and the α phase with smaller length-width ratio is formed in the specimen when aged at 320 ℃ for 15 min→460 ℃ for 4 h, and most of the size of fine α phases is close to 100 nm. The second phase formed by the two aging methods is α phase, and the α phase with smaller size is obtained at 320 ℃ for 15 min→460 ℃ for 4 h. When the temperature reaches 460 ℃, a multitude of α phase nucleated in the β matrix can be carried out by ω phase, thus formed a dense and uniform distribution. The ω phase in the alloy is no longer exists after 320 ℃ for 15 min→460 ℃ for 4 h treatment, and more α phase is precipitated at the same time. The alloy hardness is up to 503 HV, which is significantly higher than that of β matrix, and the hardness of the alloy can be improved by the precipitation of α phase substantially.

Key words: TC20 alloy, aging, α phase, hardness, microstructure evolution

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