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  • OVERVIEW
    “Thought” of metallic materials
    Yuan Zhizhong, Dai Qixun, Wang Andong, Ju Yulin, Cao Fuyang, Luo Rui
    2023, 48(5):  1-5.  doi:10.13251/j.issn.0254-6051.2023.05.001
    Abstract ( 131 )   PDF (1390KB) ( 103 )  
    “Thought” of metallic materials is refined from the systematic and comprehensive perspectives. The contradictory law of the evolution process of metallic materials properties is revealed. The complexity of the role of alloy elements is summarized. The quantitative and qualitative change law of microstructure evolution of metallic materials is expounded, and the multidirectional variability of heat treatment processes is illustrated as well.
    MICROSTRUCTRE AND PROPERTIES
    Microstructure and properties of WTaVNbMo refractory high-entropy alloy layer on W surface
    Huang Tianyang, Zheng Jiasheng, Tian Linhai, Lin Naiming, Wang Zhenxia, Qin Lin, Wu Yucheng
    2023, 48(5):  6-11.  doi:10.13251/j.issn.0254-6051.2023.05.002
    Abstract ( 83 )   PDF (2249KB) ( 105 )  
    WTaVNbMo refractory high-entropy alloy layers were prepared on the surface of pure tungsten by double-glow plasma surface metallurgy technology with powder metallurgy W18Ta18V20Nb18Mo26 alloy as source target. The temperature of workpiece was 1200 ℃, and the voltage difference between the source and cathode was 300 V, 400 V and 500 V, respectively. The microstructure and phase composition of the alloy layers were examined by scanning electron microscope with attached energy dispersive spectrometer and X-ray diffractometer. The hardness and corrosion resistance of the alloy layers were tested by microhardness tester and electrochemical workstation. The irradiation resistance of the alloy layer was simulated by SRIM software. The results show that the WTaVNbMo high-entropy alloy layers with BCC structure are formed on the surface of pure tungsten under different voltage differences. When the voltage difference is 400 V, the thickness of alloy layer is more than 100 μm. The alloy layer prepared under voltage difference of 500 V has uniform surface, compact structure and the highest hardness, which can reach 1635 HV0.05. The corrosion resistance is good, and the self-corrosion current density decreases by nearly two orders of magnitude compared with that of the W substrate. The irradiation simulation results show that compared with pure tungsten, the damage range of the high-entropy alloy layer is more concentrated, the projected range is shorter, the electronic stopping power is greater, and the ionization loss rate is faster.
    Microstructure and hardness of laser clad zirconium coating on austenitic stainless steel
    Wu Yu, Tang Qi, Su Xiaofeng, Jiang Wenlong, Zhou Danqing
    2023, 48(5):  12-17.  doi:10.13251/j.issn.0254-6051.2023.05.003
    Abstract ( 79 )   PDF (4859KB) ( 68 )  
    In order to improve the surface properties of commonly used austenitic stainless steels, extend their service life, and broaden their use value, the laser cladding technology was used to prepare a zirconium coating on the surface of a typical austenitic stainless steel. The microstructure of the clad coating was characterized by means of metallographic microscopy, XRD, ECC and EDS, and the hardness of the coating and substrate was tested by means of Vickers hardness tester. The results show that the laser clad zirconium coating has good metallurgical bonding with the stainless steel substrate, the coating grains mainly exhibit a dendritic morphology, while the substrate grains mainly exhibit an equiaxed morphology containing annealing twins. In the laser clad coating, Zr and Si elements are mainly concentrated within the dendrites, while Fe and Cr elements are mainly concentrated between the dendrites, and the distribution of Ni and Mn elements is relatively uniform. The hardness of the coating (about 743.2 HV0.1) is significantly higher than that of the substrate (about 230.5 HV0.1), being about 3.2 times that of the substrate, which may be related to the microstructure of the dendritic structure formed in the coating and the segregation of elements therein. In addition, the contribution from second phase strengthening cannot be ignored.
    Comparison of microstructure stability and corrosion resistance of nickel based alloys Inconel 740H and 617B
    Hou Shixiang, Liu Yan, Liu Dongyu
    2023, 48(5):  18-24.  doi:10.13251/j.issn.0254-6051.2023.05.004
    Abstract ( 58 )   PDF (4262KB) ( 62 )  
    Nickel based superalloys Inconel 740H and 617B were aged at 750 ℃ and 780 ℃ for 5000 h, and then corroded in simulated coal-fired environment. The surface and cross sectional microstructures were characterized by TEM, EDS and SEM. The results show that the size of intragranular γ′ phase in the Inconel 740H alloy is about 5 nm before aging, while after aging at 750 ℃ and 780 ℃ for 5000 h, the average size of γ′ phase is about 70 nm and 95 nm, respectively. The intragranular γ′ phase in the 617B alloy is not observed before aging, while after aging, the γ′ phase is precipitated and grows to about 100 nm and 130 nm, respectively, which shows that the microstructure stability of the Inconel 740H alloy is better than that of the 617B alloy. The corrosion test results in simulating coal-fired environment at 750 ℃ and 780 ℃ show that the Inconel 740H alloy has better corrosion resistance than 617B alloy, so the 617B alloy cannot replace Inconel 740H alloy at present.
    Behavior of grain boundary precipitates of P91 steel during creep process
    Gu Baolan, Liu Jiachen, Sun Haoyu, Liu Wang, Yu Haiyang
    2023, 48(5):  25-31.  doi:10.13251/j.issn.0254-6051.2023.05.005
    Abstract ( 44 )   PDF (4910KB) ( 36 )  
    Microstructure evolution and change law of grain boundary precipitates of P91 steel during the 600 ℃ and 650 ℃ creep rupture tests were studied. The results show that during the creep process, martensite lath tends to disperse gradually with the increase of creep rupture time, and the number and size of grain boundary precipitates increase. The grain boundary precipitates are mainly M23C6 and Laves(Fe2Mo) phases, the nucleating location of Laves phase is mainly at the interface of M23C6 phase on the grain boundary, because M23C6 phase on grain boundary has a higher content of Mo than that in the matrix, providing favorable conditions for the formation and coarsening of Laves phase. At the same time, the segregation of Si on grain boundary increases the self diffusion coefficient of the steel, promotes the formation of Laves phase, and also makes the coarsening rate of Laves phase higher than that of M23C6 phase. During the creep process, the hardness of the P91 steel decreases with the extension of creep rupture time, and the higher the test temperature, the more obvious the decrease of the hardness.
    Dynamic recrystallization behavior of 34CrNi3MoV alloy steel
    Zou Zhipeng, Xu Dong, Ren Yicheng, Wang Yiqun, Zheng Lei, Pang Hongxuan
    2023, 48(5):  32-40.  doi:10.13251/j.issn.0254-6051.2023.05.006
    Abstract ( 44 )   PDF (4619KB) ( 43 )  
    Single-pass isothermal compression test with maximum deformation of 50% was conducted by using Gleeble-1500 thermo-mechanical simulator, and the true stress-strain curves for 34CrNi3MoV steel were obtained at deformation temperature of 800-1200 ℃ and strain rate of 0.01-10 s-1. The results show that, at 800 ℃ and 900 ℃ (1, 10 s-1), the 34CrNi3MoV steel undergoes dynamic recovery only, while at 1000-1200 ℃ and 900 ℃(0.01, 0.1 s-1) undergoes dynamic recrystallization. By using Arrhenius equation to calculate the activation energy Q under different strains, the corresponding relationship between activation energy Q and strain is obtained by using the quintic polynomial Q=331.78+1401.47ε-10 233.34ε2+33 725.26ε3-52 745.07ε4+31 981.48ε5. The relationships between critical eigenvalues (εc, εp) and Z parameter are constructed by using work-hardening rate, and based on which a kinetic model for the 34CrNi3MoV steel to predict dynamic recrystallization volume fraction is established: XDRX=1-exp[-0.564((ε-εc)/εp)1.945].
    Microstructure and strengthening mechanism of a novel 700 MPa grade high strength anchor steel
    Meng Yasen, Pan Lifang, Zhang Hongxu, Liu Peng, Ren Zhifeng, Liu Guangming
    2023, 48(5):  41-48.  doi:10.13251/j.issn.0254-6051.2023.05.007
    Abstract ( 43 )   PDF (3111KB) ( 37 )  
    Microstructure and mechanical properties of a self-designed 700 MPa grade high strength anchor steel were investigated systematically by means of optical microscope, scanning electron microscope as well as transmission electron microscope, etc, and the strengthening mechanisms of the tested steel were further quantitatively discussed. The results show that the microstructure of the tested anchor steel is composed of banded laminated pearlite and fine equiaxed ferrite, the volume fraction of pearlite is about 43%, and in the ferrite there are a large amount of nano-sized V(C, N) precipitated particles (<20 nm). In addition, the tested steel has good comprehensive properties, with the yield strength, tensile strength, and elongation after fracture being respectively about 734 MPa, 936 MPa, and 15.1%, and the yield ratio being about 0.78. The strengthening mechanism of the tested anchor steel is a coupling of grain refining strengthening, solid solution strengthening, dislocation strengthening, and precipitation strengthening, where the contributions induced by grain refining strengthening and solid solution strengthening account for about 73% of the total strength.
    Strength evolution law of electric heat treated commercially pure Al wire
    Zhang Yi, Hou Jiapeng, Yuan Qulong, Zhang Zhenjun, Chen Ling, Zhang Zhefeng
    2023, 48(5):  49-53.  doi:10.13251/j.issn.0254-6051.2023.05.008
    Abstract ( 40 )   PDF (3454KB) ( 59 )  
    Traditionally annealing and electric heat treatment of commercially pure Al wire were carried out by using drying oven and current-providing device, respectively. The influence law and mechanism of traditionally annealing and electrical heat treatment at different temperatures on strength and microstructure of the commercially pure Al wire were investigated. The results show that when the heat treatment temperature is the same, the tensile strength and the grain size of the electric heated commercially pure Al wire is respectively lower and larger than those of the traditionally annealed, the main mechanism of which is the overheating caused by local Joule heating effect on grain boundaries in the commercially pure Al wire.
    Effect of ultrafine grain ferrite bimodal structure on mechanical properties of medium carbon steel
    Zhang Jiahao, Li Hongbin, Zhao Zhihao, Xu Haiwei, Han Yun, Tian Yaqiang, Chen Liansheng
    2023, 48(5):  54-59.  doi:10.13251/j.issn.0254-6051.2023.05.009
    Abstract ( 45 )   PDF (4849KB) ( 60 )  
    A medium carbon steel with 0.49%C was quenched at different temperatures in two-phase zone, then cold rolled 50% and annealed to obtain the ferritic bimodal structure. The microstructure was characterized by means of scanning electron microscope (SEM) and electron backscattered diffraction(EBSD), and the effect of the bimodal structure on mechanical properties was analyzed by tensile experiments at room temperature. The results show that the average grain size of the ferrite decreases with the increase of the quenching temperature in the two-phase zone. The strength of the tested steel is the highest when quenched at 770 ℃, the elongation is the highest at 750 ℃, and the product of strength and elongation is the highest at 760 ℃. When the proportion of submicron grains is 31.4% and the peak grain sizes of coarse grains and fine grains are respectively 2.51 and 0.79 μm, the tested steel has better matching of strength and elongation.
    Micro and nano mechanical properties and corrosion resistance of SLM-printed Al0.5CoCrFeNiTi0.5/316L composites
    Sun Ying, Zheng Liuwei, Zhang Huiyun
    2023, 48(5):  60-65.  doi:10.13251/j.issn.0254-6051.2023.05.010
    Abstract ( 29 )   PDF (3835KB) ( 34 )  
    316L stainless steel was selected as the matrix material and Al0.5CoCrFeNiTi0.5 high-entropy alloy (HEA) powder was used as the particle reinforcement. The 316L stainless steel matrix composites with different HEA contents were prepared by selective laser melting (SLM). The microstructure, micro and nano mechanical properties and corrosion resistance of the prepared composites were studied. The results show that there is no hole, crack and other defects in the 316L stainless steel and its composites printed by SLM. The remelted zone is mainly composed of fine cellular grains, while the non-remelted zone is composed of cellular grains and equiaxed grains, which is caused by the temperature gradient of the molten pool during solidification. With the increase of HEA content in the composite, both the hardness and the elastic modulus of the composite show an increasing trend, and the strengthening mechanisms are mainly solid solution strengthening and fine grain strengthening. With the addition of HEA alloy, the self-corrosion potential of the composites moves first to negative and then to positive direction, and the self-corrosion tendency increases first and then decreases.
    Cause analysis of AS14 annealed microstructure in 4Cr5Mo2V flat steel
    Chen Jianli, Chu Baoshuai, Zhang Xiaokun
    2023, 48(5):  66-69.  doi:10.13251/j.issn.0254-6051.2023.05.011
    Abstract ( 32 )   PDF (2476KB) ( 44 )  
    Austenitizing at different temperatures+isothermal treatment at bainite transformation temperature+spheroidizing annealing were used to simulate the formation process of AS14 annealed microstructure in the 4Cr5Mo2V flat steel. Leica optical microscope was used to observe the microstructure, 438VP/KEVEX scanning electron microscope/energy dispersive spectrometer were used to analyze the chemical composition in the micro-area of the specimen, and the impact properties of flat steel with different microstructure were tested. The results show that, high final forging temperature leads to the formation of coarse bamboo leaf-like bainite in the steel due to staying within the bainite transformation temperature range or slow cooling after forging. During annealing, carbides nucleate and grow along the interface of coarse bainite, while fewer carbides precipitate between bamboo leaves, forming an AS14 annealed microstructure. The AS14 annealed microstructure has strong structural heritability, which can significantly reduce the transverse impact property of the flat steel. Lower final forging temperature and avoiding staying in the bainite transformation temperature range or slow cooling during cooling process can prevent the formation of AS14 annealed microstructure in the 4Cr5Mo2V flat steel.
    MATERLALS RESEARCH
    Effect of rare earth Y on microstructure and properties of H13 steel
    Shu Ruixi, Yang Zhongmin, Cao Yanguang, Li Zhaodong, Chen Ying, Wang Huimin
    2023, 48(5):  70-77.  doi:10.13251/j.issn.0254-6051.2023.05.012
    Abstract ( 54 )   PDF (4866KB) ( 38 )  
    Effect of different rare earth Y contents on microstructure and properties of H13 die steel was studied. The laboratory used electroslag remelting to obtain H13 steel electroslag ingots with rare earth Y mass fractions of 0.0008%, 0.0060%, and 0.0120%, respectively. The effect of rare earth Y on microstructure was studied by means of OM, SEM, TEM and thermodynamic calculation. The effect of rare earth Y on properties was investigated by using impact testing machine and microhardness tester. The results show that the morphology of cryptocrystalline martensite in the H13 steel changes into dog-bone shape with the addition of rare earth Y. With the increase of Y content, the cryptocrystalline martensites show a local fine and dispersed distribution trend. The concentration of elements in the retained liquid phase in the H13 steel at the solidification end point reaches the concentration of high carbon and high alloy steel, resulting in the formation of liquidus carbide. When the content of rare earth Y is 0.0120%, the segregation degree of C element in the steel decreases from 1.292 to 0.529, the segregation degree of alloy elements Cr, Mo and V also decreases; the proportion of carbides with size larger than 5 μm in the steel is the lowest, and the average size of carbides is 3.13 μm; the transverse impact absorbed energy of the steel after heat treatment is 19.5 J, and the Vickers hardness after annealing and tempering are 244.4 and 525.5 HV0.5, respectively.
    Effects of rare earth elements Ce and Y on high temperature oxidation behavior of JG4246A alloy
    Chen Chonglin, Wang Jun'an, Yu Jianbo, Tu Yuguo, Zhang Meng, Li Mengli
    2023, 48(5):  78-82.  doi:10.13251/j.issn.0254-6051.2023.05.013
    Abstract ( 37 )   PDF (2724KB) ( 63 )  
    In the secondary generation superalloy JG4246A, rare earth elements Ce and Y were added to obtain four kinds of tested alloy ingots with addition of 0.012Ce (mass fraction, %, the same below), 0.017Ce, 0.034Y and 0.061Y, respectively. The effects of Ce and Y on high temperature oxidation resistance of these alloys at 1100 ℃ were studied. The phase composition and the morphology of oxidized surface were analyzed by means of X-ray diffractometer (XRD) and scanning electron microscope (SEM). The results indicate that the oxidation mass gain of the JG4246A alloy can be reduced by adding rare earth elements during the isothermal oxidation process at 1100 ℃ in air, and the oxidation kinetics of the JG4246A alloys conforms to parabolic law. Compared to the rare earth element Y, Ce has a more significant effect on slowing down the high temperature oxidation rate of the JG4246A alloy. The addition of rare earth elements does not change the surface morphology of the oxide film, but the spinel oxide makes the oxide film more compact, which can inhibit the outward diffusion of cations and reduce the oxidation reaction rate, thus improving the oxidation resistance at high temperature.
    Effect of chemical composition on heat treatment properties of X32 steel for bimetal saw blade
    Zeng Bin, Wang Jing, Liang Liang, Chen Gang, Su Bin
    2023, 48(5):  83-89.  doi:10.13251/j.issn.0254-6051.2023.05.014
    Abstract ( 31 )   PDF (4321KB) ( 78 )  
    Two X32 steels with different contents of C and N were prepared in order to develop novel X32 steel material with lower alloy content and more economical production cost. The feasibility was discussed through the characterization of properties and microstructure. The static CCT curves of two X32 steels were presented, and microstructure and mechanical properties of the hot rolled intermediate billet of these two steels after heat treatment were studied. The heat treatment experimental result was verified by industrial trial production of the two X32 steel cold strips. The research shows that X32 steel can achieve obvious microstructure refinement, strength and hardness improvement by increasing C and N content by adopting V-C and V-N microalloying technology. Therefore, without affecting quality, it is feasible to reduce the content of Ni, Cr and Mo alloy but increasing the content of C and N by using V-C and V-N microalloying technology, which points out the direction for developing new X32 steel with more economic production cost.
    Effects of Sn and cryogenic drawing on microstructure and properties of Cu-Cr-Zr alloys
    Chen Jinshui, Wang Chong, Guo Chengjun, Peng Bingfeng, Zhang Jianbo, Xiao Xiangpeng, Yang Bin
    2023, 48(5):  90-97.  doi:10.13251/j.issn.0254-6051.2023.05.015
    Abstract ( 37 )   PDF (6521KB) ( 21 )  
    Cu-Cr-Zr-xSn alloys with different Sn contents were prepared by vacuum casting. Optical microscope (OM), scanning electron microscope (SEM) and transmission electron microscope(TEM) were used to analyze the microstructure evolution of the Cu-Cr-Zr-xSn alloys in the process of multi-stage thermo-mechanical treatment (rod blank→first drawing→950 ℃ solution treatment for 1 h→secondary drawing→peak aging at 450 ℃→room temperature drawing or cryogenic drawing→450 ℃ annealing), and the corresponding tensile strength and conductivity were measured. The effects of Sn element and cryogenic drawing on microstructure and properties of Cu-Cr-Zr alloy were mainly studied. The results show that both the Sn element and the cryogenic drawing can significantly improve the tensile strength of Cu-Cr-Zr alloy without causing too much loss of conductivity, where the Sn element will promote the formation of the Cr-rich primary phase. During the thermo-mechanical treatment process, the Cr-rich primary phase will be drawn into a fiber shape, which has the effect of fibre strengthening. Cryogenic drawing can improve the deformation resistance, resulting in a smaller deformed grain size, and also promote the Cr-rich primary phase to transform into a fibrous shape, which further improves the strength of the alloy.
    Effect of La on microstructure and properties of niobiumized layer on H13 steel
    Tan Shenlu, Zhang Yue, Zhang Mengjiu, Xie Aijun, Shang Jian
    2023, 48(5):  98-103.  doi:10.13251/j.issn.0254-6051.2023.05.016
    Abstract ( 36 )   PDF (4255KB) ( 62 )  
    Effect of La content on microstructure and tribological properties of niobium carbide infiltration layer on H13 steel prepared by solid powder embedding method and niobiumizing agent with La addition was studied by means of optical microscope, scanning electron microscope, energy dispersive spectrometer and X-ray diffractometer. The results show that under different La content (0%-5%) conditions, the infiltration layer on the 3H13 steel is mainly composed of NbC. The addition of appropriate amount of La is beneficial for improving the density, hardness and tribological properties of the infiltration layer. With the increase of La content, the microhardness of the infiltration layer first increases and then decreases. When the La content is 3%, the microstructure of the infiltration layer is uniform and dense, with thickness of 7-9 μm and higher hardness (1669 HV0.2). Under corresponding friction conditions, as the La content increases, the average friction coefficient of the infiltration layer decreases first and then increases, and the wear resistance is the best when the rare earth La content is 3%.
    Effect of low Ti content (0-0.15%) on wear resistance of high strength steel
    Lu Chunjie, Shao Chunjuan, Zhen Fan, Qu Jinbo
    2023, 48(5):  104-109.  doi:10.13251/j.issn.0254-6051.2023.05.017
    Abstract ( 38 )   PDF (2873KB) ( 74 )  
    Effect of low Ti content in range of 0-0.15% on wear resistance of a high strength tested steel was investigated by using a universal wear testing machine, and the microstructure, precipitate and wear morphology were analyzed. The results show that the precipitates in the tested steels are mainly TiC, with polygonal, oval, rectangular and circular shapes. The sizes of the precipitates can be classified into three levels based on their cross sectional area: large-sized (>100 μm2), micron-sized (1-100 μm2), and submicron-sized (<1 μm2). The micron-sized precipitates play a major role in improving wear resistance, while the effect of submicron-sized precipitates is less, and the large-sized precipitates have a negative effect. With the increase of Ti content, both the amounts of submicron- and micron-sized precipitates increase linearly, while the large-sized precipitates begin to appear when the Ti content is ≥0.10%. Accordingly, the highest wear resistance is obtained when the Ti content is 0.10%.
    Microstructure and properties of novel nitrogen-alloyed corrosion resistant plastic die steel Cr13
    Zhang Hao, Chi Hongxiao, Wang Chengxi, Ma Dangshen, Fan Yi, Xie Guanli
    2023, 48(5):  110-115.  doi:10.13251/j.issn.0254-6051.2023.05.018
    Abstract ( 24 )   PDF (3848KB) ( 64 )  
    Microstructure and properties of novel N-alloyed and the traditional Cr13 corrosion resistant plastic die steels were investigated and compared by means of optical microscope, scanning electron microscope, hardness test, impact test and salt spray corrosion test. The results show that the novel N-alloyed Cr13 steel contains, except for the N, other alloying elements such as Ni, Mo and V. The difference in cleanliness between the novel N-alloyed Cr13 steel and traditional Cr13 steel is not significant, but the annealed novel N-alloyed Cr13 steel has a more uniform microstructure, lower hardness and thus the better cutting performance. Under the same heat treatment, the microstructure of the novel N-alloyed Cr13 corrosion resistant plastic die steel is more uniform, the amount of undissolved carbides reduces. The conventional Cr13 steel has a hardness of 52.7 HRC and an impact absorbed energy of 6.9 J, while the novel N-alloyed Cr13 steel has a comparable hardness with the value of 51.8 HRC but a much better toughness (12.3 J). After salt spray corrosion for 120 h, the novel N-alloyed Cr13 steel has fewer corrosion pits and the corrosion rate is 0.0594 g/(m2·h), while there are obvious corrosion pits on surface of the traditional Cr13 corrosion resistant plastic die steel and the corrosion rate is 0.1136 g/(m2·h), which means that the corrosion resistance of the novel N-alloyed Cr13 steel is better than that of the conventional Cr13 steel.
    Effect of rare earth on low temperature impact property of L360 pipeline steel
    Wang Hongli, Feng Liang, Fan Xuanyu, Yu Yanchong
    2023, 48(5):  116-120.  doi:10.13251/j.issn.0254-6051.2023.05.019
    Abstract ( 33 )   PDF (2272KB) ( 25 )  
    L360RE pipeline steel was industrial produced, and the effect of trace rare earth elements on inclusion modification, hot rolled microstructure and low temperature impact property of the L360 pipeline steel was studied. The results show that adding 0.0062% rare earth, the content of O and S in the L360 pipeline steel is sharply reduced, the cleanliness of molten steel is significantly improved. The type of inclusions changes from MnS inclusions and Al2O3-CaO composite inclusions to RE2O2S rare earth inclusions, and the original large-size strip-shaped or irregular inclusions become small-size spherical inclusions, and the grain size decreases and the microstructure is refined, the transverse impact absorbed energy from room temperature to -60 ℃ is increased. At -60 ℃, the transverse impact absorbed energy of the L360RE pipeline steel is 19.2% higher than that of L360 pipeline steel.
    Diffusion mechanism and rules of nickel on surface of low carbon steel
    Zhang Shixian, Xu Mingyue, Zhao Xiaoping, Li Yungang
    2023, 48(5):  121-128.  doi:10.13251/j.issn.0254-6051.2023.05.020
    Abstract ( 23 )   PDF (7014KB) ( 21 )  
    Nickel/low carbon steel surface composites were successfully prepared by means of aqueous solution electrodeposition+high temperature solid diffusion method. The diffusion mechanism of nickel on the surface of low carbon steel was studied. The diffusion rules of nickel on the surface of low carbon steel at different temperatures were obtained by using Den Broeder method. The results show that high temperature solid diffusion annealing realizes the metallurgical combination of nickel deposit layer and low carbon steel. Nickel atoms mainly diffuse along the grain boundary of low carbon steel, and its diffusion inhibits the growth of grains. Carbon, silicon, manganese, sulfur and phosphorus atoms have little influence on the diffusion of nickel atoms. The solid state diffusion rule of nickel atom on surface of the low carbon steel is DNi=-3.53×10-21T4+1.75×10-17T3 -3.22×10-14T2+2.60×10-11T -7.81×10-9. During solid state diffusion at 973-1373 K, the average interdiffusion coefficient of nickel atoms increases first, then decreases and then increases with the increase of temperature. The crystal structure has a great influence on the diffusion of nickel atoms, and the diffusion speed of nickel atoms in the body centered cubic crystal structure is obviously higher than that in the face centered cubic crystal structure.
    NUMERICAL SIMULATION
    Numerical simulation of temperature uniformity of hub bearing inner ring during induction tempering process
    Wei Wenting, Zhao Tianyi, Ke Jinzhe, Liu Qinglong
    2023, 48(5):  129-137.  doi:10.13251/j.issn.0254-6051.2023.05.021
    Abstract ( 77 )   PDF (3417KB) ( 29 )  
    Coupling calculation simulation model of electromagnetic field and temperature field was used to study the influence of induction heating process parameters on tempering temperature field of inner ring of the special-shaped automobile wheel hub bearing, and the interaction of the induction tempering process parameters was analyzed by using the response surface methodology. The results show that as the frequency and current density of the induction coil decrease, the temperature difference between the core and the surface of the bearing inner ring decreases, and the overall heating rate decreases. According to the significance of the influence on temperature difference and heating rate, the order of induction heating process parameters is current density, frequency, and air gap. Induction tempering process parameters with better temperature uniformity obtained based on response surface method are the frequency of 10 kHz, the current density of 19.6×106 A/m2, the air gap between the outer induction coil and the parts of 8.5 mm, and the effectiveness of temperature field numerical simulation is verified through experiments. With equivalent tempering parameters, isothermal tempering and induction tempering experiments find that the hardness obtained by the two processes is similar.
    Finite element analysis of quenching process of large forging of Cr-Ni-Mo-V medium carbon heat-resistant high-strength steel
    Yang Hongtao, Liu Kehong, Jia Qihui, Wu Runsheng, Zhao Ziheng, Li Wei
    2023, 48(5):  138-144.  doi:10.13251/j.issn.0254-6051.2023.05.022
    Abstract ( 33 )   PDF (4474KB) ( 35 )  
    To avoid the phenomenon of quenching cracking due to uneven microstructure of large forging, the temperature, stress and microstructure fields of large forging made of medium carbon Cr-Ni-Mo-V heat-resistant high-strength steel during quenching at 940 ℃ were numerically simulated using DEFORM finite element software. The results show that the temperature difference between core and surface of the Cr-Ni-Mo-V steel large forging exceeds 600 ℃ during quenching process, and the internal stress is mainly concentrated at the step position. According to the simulation results, the adopting of the quenching process of “water quenching for 14 min+air cooling for 10 min+water quenching” can greatly reduce the internal stress in the step position and avoid quenching cracking of the forging while ensuring the microstructure is similar to that of conventional water cooling.
    Temperature field simulation of pressure quenching process of 20Cr2Ni4A steel ring gear
    Chen Jianwen, Yuan Wufeng, Zou Wei, Liu Ke, Ouyang Xuemei, Wang Xinming
    2023, 48(5):  145-150.  doi:10.13251/j.issn.0254-6051.2023.05.023
    Abstract ( 29 )   PDF (3573KB) ( 24 )  
    Based on the experimental measurement of the cooling curve of the ring gear made of 20Cr2Ni4A steel during the pressure quenching process under different flow rates and the calculation of the corresponding heat transfer coefficients, corresponding finite element numerical simulation was carried out, and the effect of different flow rate combinations on temperature field distribution of the ring gear during pressure quenching process was studied. The results show that the heat transfer coefficients corresponding to 189-1136 L/min flow rates all show a trend of increasing first and then decreasing with the decrease of temperature, and the maximum value of heat transfer coefficient increases with the increase of flow rate. Among the four representative flow rate combinations, the slow-fast-fast flow rate combination can better reduce the temperature difference between the inside and outside of the ring gear. Comparing with the temperature measurement results, it is found that the simulation results are in good agreement with the experimental data, and the established pressure quenching temperature field model is reliable, which can provide theoretical guidance for optimization of the pressure quenching process.
    Microstructure evolution and temperature field simulation of Inconel 718 super alloy during isothermal compression
    Wang Chao, Ren Yonghai, Han Senlin, Cheng Zhi, Wang Longxiang, Zhao Fei, Tan Yuanbiao
    2023, 48(5):  151-157.  doi:10.13251/j.issn.0254-6051.2023.05.024
    Abstract ( 35 )   PDF (4538KB) ( 28 )  
    Microstructure evolution and temperature field simulation of the Inconel 718 superalloy in the temperature range of 950-1150 ℃ and strain rate range of 0.1-10 s-1 were investigated by means of Gleeble 3800 thermal compression tester, Deform-3D finite element software and optical microscope. The results show that at low deformation temperature and high strain rate, the flow stress increases rapidly to the peak at the initial stage with the increase of deformation strain. After reaching the peak stress, the flow curve exhibits an obvious softening phenomenon. Also at low deformation temperature and high strain rate, the deformation heat is larger, leading to a fact that dynamic recrystallization is prone to occur in the deformed alloy, the dynamic recrystallization degree is higher, and the grain size is smaller. As the strain rate decreases, the deformation heat decreases gradually, and the volume fraction of dynamic recrystallization grains decreases. When deformed at 1100 ℃ and 0.1 s-1, the full dynamic recrystallization occurs in the deformed alloy. Based on the results of the temperature field distribution simulated by Deform-3D software, it can be seen that the hot deformation conditions of low temperature and high strain rate will produce large deformation heat in the deformed alloy. With the increase of deformation temperature and the decrease of strain rate, the value of deformation heat gradually decreases. When the deformation temperature and strain rate are constant, the deformation heat in the alloy increases with the increase of true strain.
    PROCESS RESEARCH
    Hot deformation behavior of metastable β-titanium alloy Ti-1500
    Zhang Shuming, Lin Bochao, Xin Shewei, Wang Junyi, Huang Zhitao, Fu Mingjie
    2023, 48(5):  158-165.  doi:10.13251/j.issn.0254-6051.2023.05.025
    Abstract ( 32 )   PDF (4402KB) ( 24 )  
    The hot deformation behaviors of a new type of metastable β-titanium alloy Ti-1500 were studied through isothermal compression tests at 750-910 ℃ with 0.001-10 s-1. The hyperbolic sine Arrhenius constitutive equation of coupled strain was established. Based on the dynamic material model and Prasad's rheological instability criterion, the hot working diagrams were constructed, and the microstructure after deformation was analyzed. The results show that the flow stress of the alloy decreases as the deformation temperature increases and the strain rate decreases. Under the same conditions, the peak flow stress of the alloy is slightly higher than that of the Ti55531 alloy, but lower than that of the M28 alloy. The average thermal deformation activation energy of the alloy in the two-phase region is 291.36 kJ/mol, which is much higher than the self-diffusion activation energy of pure titanium. The activation energy in the β single-phase region is 153.96 kJ/mol, which is close to the self-diffusion activation energy of pure titanium. The peak value of energy dissipation efficiency in the two-phase region is located at a low strain rate (0.001 s-1), while the peak value of energy dissipation efficiency in the single-phase region lies in the middle and low strain rates (0.01-0.1 s-1). At all test temperatures, deformation instability occurs when the strain rate is higher than 1 s-1. Combined with microstructure analysis, deformation can be divided into three regions, namely low temperature and low strain rate β→α phase transition zone, medium to high temperature and low strain rate β recrystallization zone and unstable region with uneven deformation at high strain rates.
    Effect of sintering temperature on microstructure and properties of hot pressing sintered Ti-6Al-4V alloy
    Li Ji, Cao Zhen, Luo Ping, Xiao Zhitong, Li Jiongli, Wang Xudong
    2023, 48(5):  166-173.  doi:10.13251/j.issn.0254-6051.2023.05.026
    Abstract ( 33 )   PDF (7570KB) ( 26 )  
    Ti-6Al-4V (TC4) alloy with excellent properties was prepared by hot pressing sintering at 800-1100 ℃ under 25 MPa and recrystallization annealing at 780 ℃ for 2 h. The phase structure of the tested alloy and its evolution with temperature were studied, and the effects of different hot pressing sintering temperatures on the sintering density, microstructure and mechanical properties were analyzed. The results show that the starting and finishing temperatures of α→β phase transformation of the prepared Ti-6Al-4V alloy are 627 ℃ and 941 ℃, respectively. The sintering densification cannot be achieved when sintering at 800 ℃. Uniform microstructure is obtained by sintering at 900 ℃, while sintering at 1000 ℃ and 1100 ℃ causes abnormal coarsening of the microstructure. By hot pressing sintering at 900 ℃+annealing, the tensile strength of the Ti-6Al-4V alloy reaches to 894.6 MPa, and the elongation after fracture reaches to 15.7%, the tested alloy obtains excellent strength and plasticity.
    Effect of solution treatment on microstructure and properties of selective laser melted duplex stainless steel
    Yang Zhikai, Zhang Xinyue, Yi Lin, Yan Xingchen, Wang Zhi
    2023, 48(5):  174-183.  doi:10.13251/j.issn.0254-6051.2023.05.027
    Abstract ( 32 )   PDF (6097KB) ( 26 )  
    By designing and optimizing the selective laser melting (SLM) forming process for duplex stainless steel, a duplex stainless steel(21.98wt%Cr-5.37wt%Ni-3.13wt%Mo-1.95wt%Mn) with high accuracy and low defect density was produced. The effect of different solution treatment temperatures on its microstructure and properties was further studied. The results show that the optimal SLM processing parameters obtained through the study of the SLMed specimens under different processing parameters are laser power of 275 W, scanning speed of 700 mm/s, scanning space of 80 μm and thick of powder layer of 50 μm. Solution treatment can effectively regulate the phase composition and proportion of the SLMed duplex stainless steel, and the austenite content of the specimen is significantly higher than that of the as-printed specimen. Solution treatment at lower temperatures can lead to the precipitation of brittle σ phases on the grain boundary, greatly weakening the plasticity of the specimen. When the solution temperature rises to 1020 ℃ or above, σ phase disappears. Higher solution treatment temperatures can also coarsen the grains, not only reducing the strength of the specimen, but also decreasing the plasticity. When solution treated at 1020 ℃, a nearly equilibrium dual-phase structure is obtained in the specimen, of which the tensile strength is 868 MPa and the elongation reaches 35.0%.
    Effect of recovery heat treatment on microstructure and mechanical properties of R26 superalloy bolts
    Han Zhewen, Wang Zhichun, Wang Jiajian, Wang Qibing, Peng Bo, Zuo Yue, Si Mingyu, Kang Ju
    2023, 48(5):  184-190.  doi:10.13251/j.issn.0254-6051.2023.05.028
    Abstract ( 31 )   PDF (5122KB) ( 26 )  
    Recovery heat treatment was carried out for the R26 superalloy bolts which had serviced about 60 000 hours in a power station. The effect of recovery heat treatment on microstructure and mechanical properties of the R26 superalloy bolts was investigated by means of chemical composition analysis, metallographic microstructure observation, mechanical property test and fracture analysis. The results show that the microstructure of the R26 alloy is mainly austenite with a large number of twin crystals. There are discontinuous precipitated carbides along the grain boundaries of the R26 superalloy with abnormal hardness. After recovery heat treatment, the grain is refined and homogenized, and the carbides which locate on the grain boundary are dissolved, moreover, the γ′ phases are precipitated in the grain. The recovery heat treatment can restore the hardness value of the R26 alloy bolts to the standard range, and improve the plasticity and toughness.
    Effect of vacuum heat treatment on microstructure and hardness of BCu35NiMnCoSi copper based filler metal
    Zhao Dong, Dong Zhi, Quan Chunyi, Hu Fuchang, Li Shijian
    2023, 48(5):  191-195.  doi:10.13251/j.issn.0254-6051.2023.05.029
    Abstract ( 27 )   PDF (3438KB) ( 38 )  
    Vacuum heat treatment of BCu35NiMnCoSi copper based filler metal was carried out by different processes, and the effect of vacuum heat treatment on the microstructure and properties was studied by comparing with the traditional air furnace heat treatment process. The results show that the microstructure and hardness of the BCu35NiMnCoSi filler metal after vacuum heat treatment are basically the same as that of traditional air furnace treatment. The vacuum heat treatment process has no effect on the chemical composition of the BCu35NiMnCoSi filler metal, and the surface dilution of some elements is caused by the dilution of raw materials. With the increase of heating temperature and holding time, the microhardness of the filler metal decreases. The ranges of optimized vacuum heat treatment process parameters of the BCu35NiMnCoSi filler metal are from 870 ℃ to 880 ℃, 15 min to 25 min and 890 ℃, 15 min to 20 min. With these parameters to vacuum heat treating the BCu35NiMnCoSi filler metal bar, the brazed stainless steel pipe weld has no defects such as filler metal nodule, pore, burn through and matrix melting erosion, and the welded pipe has good air tightness and meets the usage requirements.
    Effect of homogenization treatment on microstructure and phase evolution behavior of 6061 aluminum alloy
    Cheng Zhiyuan, Wang Jingtao, Guo Fengjia, Sun Ning, Yu Jihai
    2023, 48(5):  196-203.  doi:10.13251/j.issn.0254-6051.2023.05.030
    Abstract ( 40 )   PDF (4253KB) ( 34 )  
    Microstructure of 6061 aluminum alloy sheet as-cast and after homogenization treatment was studied by means of OM, SEM and DSC. The transformation process of precipitated phase particles and the evolution law of composition uniformity in the alloy before and after homogenization were analyzed. The results show that after homogenization at 579 ℃ for 6 h, the low melting point non-equilibrium eutectic phase of the alloy is fully dissolved, the segregation of intracrystalline composition is basically eliminated, and the content of the retained second phase in the alloy is as low as 0.87%. Meanwhile, the acicular iron-rich phase is spheroidized and distributed discontinuously, the homogenization effect of the alloy is excellent, which can provide a reference for the formulation of reasonable heat treatment process in large-scale production.
    Effect of heat treatment on microstructure and hardness of novel Ni-Co based superalloys
    Hu Jiahao, Gao Jiali, Zhang Shangzhou
    2023, 48(5):  204-209.  doi:10.13251/j.issn.0254-6051.2023.05.031
    Abstract ( 33 )   PDF (4957KB) ( 37 )  
    Three novel Ni-Co based superalloys with different (W+Ta) contents were designed by using CALPHAD method, and solution and aging treatment of the alloys were determined by the equilibrium phase diagram. The microstructural characteristics of the Ni-Co based superalloys after heat treatment were analysed by means of OM, SEM and EDS. The results show that the as-cast microstructure of the three Ni-Co based superalloys is composed of γ phase, γ′ phase, γ+γ′ eutectic structure and carbides, and the γ+γ′ eutectic structure is radial. After solution treatment, the as-cast primary γ′ phase is completely eliminated, and tertiary γ′ phases are precipitated after aging at 800 ℃. With the increase of aging time, the size of γ′ phase increases, and the hardness of the alloys also increases, however, the precipitated γ′ phases in the alloy with high W+Ta content aged at 800 ℃ are split, that results in hardness increasing first and then decreasing.
    Effect of austenitizing parameters on deformation behavior of 25Cr3Ni3MoNb steel at 700 ℃
    Lin Xiong, Man Da, Yang Hongtao, Hou Yuchen, Jin Zili, Li Wei
    2023, 48(5):  210-216.  doi:10.13251/j.issn.0254-6051.2023.05.032
    Abstract ( 23 )   PDF (6458KB) ( 25 )  
    By analyzing the microstructure characteristics and precipitation behavior of 25Cr3Ni3MoNb steel for rapid-fire gun barrel, the deformation behavior at 700 ℃ was studied in detail, and the influence of material microstructure on high temperature mechanical properties at 700 ℃ was explored. The results show that there is a competitive relationship between work hardening and dynamic softening during the deformation process at 700 ℃. Meanwhile, the deformation behavior of the 25Cr3Ni3MoNb steel at 700 ℃ is closely related to the austenitizing temperature, and ultimately affects the mechanical properties of the material. As the austenitizing temperature increases from 980 ℃ to 1020 ℃, the density of defects in the material decreases. After tempering, the size of precipitates increases. Then tension at 700 ℃, the tensile strength Rm decreases from 354 MPa to 237 MPa, and the yield strength Rp0.2 decreases from 312 MPa to 221 MPa. The specimen austenitized at 980 ℃ exhibits a greater work hardening rate and smaller dynamic softening rate, because the volume fraction of carbides pinning dislocations are more inside the specimen. The pinning effect also makes the process of dynamic recovery more difficult and thus exhibits higher high-temperature yield strength.
    Effects of hot deformation behavior and dynamic recrystallization on MnS inclusions in low sulfur gear steel
    Liu Shuai, Wang Fuming, Xu Hailun, Liu Shaowei
    2023, 48(5):  217-223.  doi:10.13251/j.issn.0254-6051.2023.05.033
    Abstract ( 25 )   PDF (3253KB) ( 21 )  
    Hot compression test for gear steel FAS3420H was conducted by Gleeble-1500 thermomechanical simulator, and the effects of hot deformation parameters such as deformation amount and deformation temperature on size and relative plasticity of MnS were studied. The results show that during the deformation process, the fragmentation and growth of sulfide occur alternately, and the deformation temperature and deformation amount have a significant impact on the size of MnS inclusions. The change rule is related to the degree of recrystallization of the gear steel matrix. When the deformation temperature is low (900 ℃), with the increase of deformation amount, the amount of sulfides with small aspect ratio first decreases and then increases, and the relative plasticity presents a downward trend, while the dynamic recrystallization fraction gradually increases. When the deformation temperature is high (1200 ℃), with the increase of deformation amount, the amount of sulfides with small aspect ratio first increases and then decreases, and the relative plasticity shows an increasing trend, however, it is generally lower than when rolling at low temperature, and at this time, sufficient dynamic recrystallization occurs at a lower deformation amount. It can be seen that in the actual rolling process, when a higher temperature is selected, the matrix is prone to dynamic recrystallization. Under the interaction of matrix deformation and grain boundary movement during the recrystallization process, smaller and more MnS inclusions can be obtained.
    Optimization of heat treatment process for 34CrNi3MoV steel box
    Zhang Hequan, Xie Zhuanye, Zhu Xin, Cheng Haiying, Ma Hongya, Lü Zhengfeng, Wang Guangyan
    2023, 48(5):  224-228.  doi:10.13251/j.issn.0254-6051.2023.05.034
    Abstract ( 32 )   PDF (2018KB) ( 31 )  
    Heat treatment process and properties of the 34CrNi3MoV steel box were analyzed and compared. The results show that the pre-heat treatment adopts double normalizing, which can homogenize the microstructure, refine the grain, cut off the structure inheritance, and remove hydrogen to prevent white spots. After the pre-heat treatment, the microstructure of the 34CrNi3MoV steel is ferrite matrix with dispersed granular or spheroidal carbides, which realizes the microstructure preparation for the quenching and tempering treatment. The selection of quenching temperature is mainly based on the transverse impact property. When the tempering temperature is set at 605 ℃ and the quenching temperature is set at 850-870 ℃, the transverse impact property is acceptable. When the 34CrNi3MoV steel is quenched and tempered, its microstructure and properties change significantly with the change of tempering temperature. When the quenching temperature is 860 ℃ and the tempering temperature is 605 ℃, the hardness, tensile and impact properties at room temperature meet the requirements, and the comprehensive properties are the best.
    Effect of heat treatment temperature on microstructure of long-term serviced T23 steel weld
    Zhang Zhenhua, Yin Shaohua, Sun Zhiqiang, Wang Chuandong, Zhu Wanjin
    2023, 48(5):  229-235.  doi:10.13251/j.issn.0254-6051.2023.05.035
    Abstract ( 39 )   PDF (4432KB) ( 27 )  
    Butt joints of T23 steel water-cooled wall pipes with a service time of more than 60 000 h were taken as the research object. The welded joints were subjected to heat treatment at different temperatures. The microstructure evolution of the weld zone after heat treatment at different temperatures was deeply studied by means of microhardness analysis, metallographic analysis, scanning electron microscope and energy spectrum analysis. The distribution law of alloy carbides on grain boundaries was analyzed, and the forming mechanism of reheat cracks in weld zone of the T23 steel welded joints was revealed. The results show that the weld structure of the welded specimen of T23 steel is a mixture of coarse lath martensite and bainite, with obvious prior austenite grain boundaries, the maximum grain size exceeding 300 μm, and size of most grains being 150-200 μm. After heat treatment at 580 ℃, the weld zone has obvious secondary hardening phenomenon, and grain refinement and dispersion strengthening are the main reasons for secondary hardening. When heat treated at 720 ℃ and 760 ℃, holes and precipitates appear on the grain boundaries of the T23 steel cap weld zone, and the precipitates are mainly M23C6 and MC. There are two main modes of the positional relationship between precipitates and pores. One is that the pores grow along the grain boundary in the front of the precipitates, and the other is that the pores grow on the side of the precipitates near the inner grain. The formation mechanism needs to be further studied.
    Second phase precipitation strengthening process of vacuum carburizing and quenching
    Lü Huyue, Chen Xuyang, Cong Peiwu, Lu Wenlin, Du Chunhui, Hu Fengjiao
    2023, 48(5):  236-240.  doi:10.13251/j.issn.0254-6051.2023.05.036
    Abstract ( 37 )   PDF (3768KB) ( 32 )  
    Combining the second phase precipitation strengthening principle and adopting the process path based on the saturation value adjustment method, the vacuum carburizing and quenching process was developed with the help of calculation software, and the second phase strengthening carburizing and quenching process test was carried out on 18CrNiMo7-6 steel disc specimens and gears. The surface hardness, depth of hardened layer and microstructure of the disc and gear specimens were measured. The results show that the second phase strengthening carburizing process can cause precipitation of a large amount of dispersed fine and evenly distributed carbides in the carburized layer, which improves the surface hardness of the disc specimen to about 840 HV by second phase strengthening, and makes the high hardness layer deeper and resulting more ideal hardness-layer depth curve. Such kind of second phase strengthening carburizing and quenching process can be successfully applied to gear and other transmission parts to improve the surface hardness.
    Ion nitrocarburizing+post-oxidation combined process for tie rods of large rolling mill
    Fang Ying, Li Bo, Li Shuangxi
    2023, 48(5):  241-245.  doi:10.13251/j.issn.0254-6051.2023.05.037
    Abstract ( 33 )   PDF (1554KB) ( 32 )  
    Aiming to avoid the corrosion and wear problem of the 42CrMo steel tie rods of large rolling mill used in the coastal areas of Southeast Asia, nitrocarburizing and post-oxidation combined treatment was carried out by using a single heat source pulsed ion nitriding furnace. The research results on the pre-oxidation, nitrocarburizing and post-oxidation processes of the simulated specimen show that, the combined treatment process which meets the product requirements is: firstly pre-oxidation at 350 ℃ for 2 h in air furnace, secondly, nitrocarburizing at 550 ℃ for 24 h (furnace pressure of 260 Pa, NH3∶CO2 ratio of 20∶1), thirdly, post-oxidation at 520 ℃ for 2 h (furnace pressure of 300 Pa, NH3∶O2 of 6∶1), then turning the power and penetrating agent off and introducing air into the furnace at a speed of 0.5 L/min until the furnace temperature dropping to 300 ℃, finally, quickly and evenly coating the surface of the specimen with anti-rust oil when the specimen cooled to about 150 ℃. Under this combined process, the depth of the infiltration layer reaches 0.39-0.41 mm, the compound layer reaches 10-12 μm, which is thicker than that under the same process without pre-oxidation. After salt spray testing, corrosion spots appear on the specimen only until 70 h, and the corrosion resistance is higher than that only undergoing nitrocarburizing treatment without post-oxidation treatment.
    Effect of annealing process on microstructure and mechanical properties of FeCrMnNiAl0.1 high-entropy alloy
    Guo Baochang, Jiang Fengyang, Wang Junbo, Liu Jiangnan, Liu Langlang
    2023, 48(5):  246-251.  doi:10.13251/j.issn.0254-6051.2023.05.038
    Abstract ( 31 )   PDF (3407KB) ( 32 )  
    FeCrMnNiAl0.1 high-entropy alloy was prepared by arc melting method. The effects of annealing treatment heating rate and holding time on microstructure and mechanical properties of the five component alloy were studied by means of SEM, XRD, microhardness tester and universal tensile testing machine. The results show that the FeCrMnNiAl0.1 high-entropy alloy consists of FCC phase, BCC phase and tetragonal Cr3Ni2. The prolongation of annealing holding time leads to an increase in lattice distortion and BCC structure content of the alloy. Increasing the heating rate makes the content of BCC structure also increase, but the degree of lattice distortion decrease. The hardness of the non-heat treated alloy is around 190 HV, and the microhardness of the high-entropy alloy increases with the prolongation of the annealing holding time, but the microhardness gradually decreases with the increase of heating rate. With the prolonging of holding time during annealing, the tensile strength of the high-entropy alloy gradually increases, while the ductility decreases. With the increase of heating rate, the tensile strength of the alloy first decreases and then increases, and the ductility becomes better.
    Ti-catalyzed plasma nitriding process of 42CrMo steel
    Zhong Li, Wang Zuoyu, Men Xinhao, Han Xi
    2023, 48(5):  252-258.  doi:10.13251/j.issn.0254-6051.2023.05.039
    Abstract ( 36 )   PDF (3895KB) ( 31 )  
    Effect of titanium on conventional plasma nitriding process of 42CrMo steel under different nitriding time was studied. The microstructure and hardness of the nitrided layers on specimen under different nitriding processes were characterized and analyzed. The results show that the surface hardness and nitrided layer depth of the titanium-catalyzed plasma nitrided specimen are obviously higher than those of the conventional plasma nitrided specimen. Under the process condition of 535 ℃×3 h, the surface hardness and the depth of the nitrided layer reach 887.4 HV0.2 and 400 μm, respectively. The addition of titanium promotes the infiltration and diffusion of nitrogen, and generates high hardness compound TiN on the surface. Compared with the conventional plasma nitriding under the same nitriding time, the surface hardness and the depth of the nitrided layer are increased by 60 HV0.2 and by 80 μm, respectively, and the nitriding efficiency is increased by about 25%. The titanium-catalyzed plasma nitriding process has more significant advantages than conventional plasma nitriding, which not only improves the microstructure and hardness of the nitrided layer, enhances the nitriding effect, but also improves the nitriding efficiency and significantly shortens the nitriding cycle.
    Effect of pretreatment process on microstructure and mechanical properties of medium manganese TRIP steel
    Zhang Guangying, Ding Wei, Li Yan, Feng Jike, Dong Rui
    2023, 48(5):  259-264.  doi:10.13251/j.issn.0254-6051.2023.05.040
    Abstract ( 29 )   PDF (2373KB) ( 31 )  
    Microstructure evolution and change of mechanical properties of the 0.2C-5Mn-1.5Al-0.5Si medium manganese TRIP steel after different pretreatments and intercritical annealing treatment were systematically studied by means of scanning electron microscope (SEM), X-ray diffractometer (XRD) and tensile testing machine. The results show that with the shortening of pretreatment time, the pearlite content does not change, but the ferrite and martensite grains are refined. When intercritically annealed at 730 ℃ for 5 min, two kinds of retained austenite in the form of block and film appear in the microstructure. The grains of austenite and ferrite in the steel under shorter pretreatment time are finer. It is found that the tensile strength and elongation of the tested steel under shorter pretreatment time are generally higher than those under longer pretreatment time. Under the process with a shorter pretreatment time, the optimal mechanical properties are obtained after annealing, with elongation of 34%, the product of strength and elongation of 34.34 GPa·%, and there is no yield extension phenomenon during the tensile process, with good work hardening ability.
    Effect of isothermal quenching temperature in Q-P process on microstructure and mechanical properties of 60Mn2SiCr steel
    Wang Bin, Wang Haoxiang, Wang Jun, Wang Changzhi, Duan Dong, Tang Baming, Wang Dongdong, Hu Yunjie
    2023, 48(5):  265-269.  doi:10.13251/j.issn.0254-6051.2023.05.041
    Abstract ( 37 )   PDF (3059KB) ( 25 )  
    Effect of isothermal quenching temperature during quenching and partitioning (Q-P) process on microstructure and mechanical properties of 60Mn2SiCr steel was studied by means of scanning electron microscope, X-ray diffractometer, impact testing machine, Rockwell hardness tester and tensile testing machine. The relationship between the retained austenite content in the microstructure and the carbon content in the retained austenite of the tested steel after Q-P treatment and the mechanical properties was emphatically analyzed. The results show that when the isothermal quenching temperature increases from 120 ℃ to 180 ℃, the Rockwell hardness, impact absorbed energy, tensile strength and elongation of the specimen decrease with the decrease of content of martensite and retained austenite and carbon content in retained austenite. When the isothermal quenching temperature in Q-P process is 120 ℃, the mechanical properties are optimal, with volume fraction of retained austenite of 13.9%, the carbon content (mass fraction) in the retained austenite of 1.1%, the Rockwell hardness of 58.8 HRC, the impact absorbed energy of 50.7 J, the tensile strength of 1768 MPa and the elongation of 19.6%.
    Effect of quenching-partition time on wear resistance of a medium manganese steel
    Jia Juan, Jiang Xuan, Jiang Jianjiang, Song Xinli
    2023, 48(5):  270-274.  doi:10.13251/j.issn.0254-6051.2023.05.042
    Abstract ( 32 )   PDF (3362KB) ( 26 )  
    A medium manganese steel was treated by two-step quenching-partition process (Q&P). The microstructure evolution and wear resistance of the specimens were observed by means of OM, SEM, XRD and abrasive wear tester. Effect of quenching and partition time on microstructure and properties of the medium manganese steel was analyzed. The results show that the microstructure of the tested steel is mainly composed of lath martensite, massive martensite and retained austenite. When the partitioning time is extended from 5 min to 40 min, the retained austenite content first increases and then decreases, and reaches the maximum value after 20 min. The wear mechanism of the tested steel is mainly micro cutting. Under the smaller load, the wear resistance decreases with the increase of retained austenite content. Under the higher load, the wear resistance becomes better with the increase of retained austenite content.
    Shot peening treatment of chains for mining
    Lu Junling, Zhang Jianbin, Chen Feifei
    2023, 48(5):  275-278.  doi:10.13251/j.issn.0254-6051.2023.05.043
    Abstract ( 27 )   PDF (6000KB) ( 38 )  
    To improve the service life of the mining circular chain, shot peening was carried out on 23MnNiCrMo53K steel chain, and the effect of shot peening on microstructure and fatigue resistance was studied. The results show that the microstructure of the chains is mainly tempered martensite before shot peening, and after shot peening, the surface microstructure is refined to form sub crystals, with a depth of 400 μm from the surface, the microstructure is basically close to that before shot peening. After shot peening, the surface microhardness of the chains increases, and with the increase of the surface layer depth, the microhardness gradually decreases, and the fatigue life of the chains significantly increases.
    Hot deformation behavior and microstructure evolution of TC11 titanium alloy
    Lü Xuechun, Zhao Wenge, Yuan Mingrong, Li Heng
    2023, 48(5):  279-282.  doi:10.13251/j.issn.0254-6051.2023.05.044
    Abstract ( 37 )   PDF (2582KB) ( 59 )  
    Deformation behavior and microstructure evolution of the TC11 titanium alloy at high temperatures were investigated. The results show that the flow stress of the alloy decreases as the deformation temperature increases and the strain rate decreases during deformation, and the degree of softening of the flow stress increases as the strain rate increases. By analysis of the processing map at true strain of 0.6, the highest energy dissipation rate is found at 940 ℃ and 0.001 s-1 and reaching 0.71. The plastic instability zone is found in the range of 920-930 ℃ and 0.9-10 s-1. The dynamic recrystallization of the α-phase during hot deformation of the TC11 titanium alloy is promoted by increase of the strain rate, the deformation volume and the deformation temperature.
    Effect of spheroidization annealing process on austenite grain size of 16MnCr5 steel for carburizing
    Zheng Xiaowei, Lin Zaiyong, Zhang Jianfeng, Jin Tao
    2023, 48(5):  283-286.  doi:10.13251/j.issn.0254-6051.2023.05.045
    Abstract ( 65 )   PDF (1777KB) ( 51 )  
    In order to study the effect of spheroidizing annealing on austenite grain size of 16MnCr5 steel hot rolled wire rods during the process of modification, hot-rolled wire rod specimen and specimens isothermally spheroidizing annealed at 700, 720, 740, 760 and 780 ℃, respectively, for 5 h were subjected to water quenching at 940 ± 5 ℃ for 1 h. The austenite grain size of the specimens was measured and compared. The results show that the “double high” processes (heating temperature of 1200-1250 ℃, finishing rolling temperature of 950-980 ℃) and rapid cooling between 800-600 ℃ (air cooling, cooling rate ≥ 10 ℃/s) are used in the rolling process to ensure that aluminum and nitrogen atoms are in a solid solution state. During the heat treatment process before austenite grain detection, AlN is uniformly and finely precipitated, resulting in fine and uniform austenite grains in the 16MnCr5 steel. When spheroidizing annealed at 700 and 720 ℃, AlN particles are uniformly and finely precipitated. Although Ostwald aging and growth occur, the AlN particles are still smaller than the critical radius, and the austenite grains are still fine and uniform. With the further increase of spheroidizing annealing temperature, the second phase particles undergo Ostwald aging and growth. The second phase particles in local areas exceed the critical radius, and local austenite grains grow abnormally, resulting in mixed grains. In practical production, in order to obtain uniform and fine austenite grains, as well as good spheroidized microstructure and mechanical properties, 16MnCr5 steel is spheroidizing annealed at 720 ℃. Through the above controlled rolling process and spheroidizing annealing process, the austenitic grain size of 16MnCr5 steel can reach 7.5 grade to 7 grade, meeting the requirements of austenitic grain size ≥ 5 grade and without mixed grains.
    Effect of magneto-thermal coupling annealing on Goss grain orientation of CGO steel
    Dong Lili, Liu Yongzhen, Ma Yonglin, Liu Baozhi
    2023, 48(5):  287-290.  doi:10.13251/j.issn.0254-6051.2023.05.046
    Abstract ( 27 )   PDF (876KB) ( 39 )  
    Microstructure, misorientation of Goss oriented grain and magnetic properties of the CGO steel after magneto-thermal coupling tensile leveling annealing under different parameters were investigated and analyzed by means of self-made magnetic-thermal coupling device, X-ray diffractometer and magnetic measuring instrument. The results show that the magneto-thermal coupling annealing can promote the grain growth in the CGO steel and reduce the maximum misorientation of Goss orientated grain, thus improving the magnetic properties. By employing magnetic field with intensity of 12 mT at 750 ℃, the effect of magneto-thermal coupling annealing is the most significant, the maximum misorientation of Goss orientated grain is reduced by 2.76° compared with that without magnetic field, the iron loss value is reduced and the magnetic induction intensity is increased.
    Effect of solution and aging treatment on impact properties of ZL108 aluminum alloy
    Tan Guoyin
    2023, 48(5):  291-293.  doi:10.13251/j.issn.0254-6051.2023.05.047
    Abstract ( 27 )   PDF (1272KB) ( 64 )  
    Impact properties of the ZL108 aluminum alloy after solution aging treatment were studied by means of OM, SEM and impact testing machine. The results show that the as-cast microstructure is mainly composed of α solid solution, coarse eutectic silicon and bulk primary silicon. After solution and aging treatment, the precipitated phase is fine and evenly distributed, with a morphology similar to short rod or coral shaped, which can better pin dislocations and help improve the impact properties of the material. The non-equilibrium distribution of elements in the as-cast specimens results in the production of a large amount of refractory eutectic silicon and bulk primary silicon. After solution and aging treatment, the precipitated phase particles continue to break under high temperature, and most of them are remelted into the matrix. The remaining precipitate particles have smaller sizes, which can better coordinate the deformation of the matrix and improve the impact properties of the specimen by 6.6 times.
    FAILURE ANALYSIS
    Fracture failure analysis of 35CrMo steel high strength bolt
    Wang Pu, Tong Hui
    2023, 48(5):  294-297.  doi:10.13251/j.issn.0254-6051.2023.05.048
    Abstract ( 47 )   PDF (2597KB) ( 75 )  
    35CrMo steel high strength bolt of a heavy tractor broke after being tightened and placed for 2 days. The fractured bolt and the unused bolt of the same batch were studied by fracture analysis, metallographic examination, composition analysis, hardness analysis and mechanical testing. The results show that the harmful hydrogen introduced during the pickling and electroplating process is not effectively and timely removed, which results in the hydrogen accumulating towards the stress concentrated root of the bolt under the preload for tightening, so that the hydrogen induced delayed fracture phenomenon for the bolt occurs.
    Failure analysis on cracking of 7A09 aluminum alloy outer cylinder parts
    Wang Hao, Fu Neng, Feng Kangtun
    2023, 48(5):  298-302.  doi:10.13251/j.issn.0254-6051.2023.05.049
    Abstract ( 43 )   PDF (2278KB) ( 53 )  
    Several 7A09 aluminum alloy outer cylinders of aircraft landing gear were found cracked during machining. The chemical composition, mechanical properties, fracture micromorphology, microstructure and microhardness of the aluminum alloy outer cylinder were analyzed to investigate the essence and causes of the cracks by means of ICP spectrometer, tensile testing machine, scanning electron microscope, optical microscope and energy dispersive spectrometer. The results show that the crack of the 7A09 aluminum alloy outer cylinder is developed from the initial crack source formed by forging at high temperature, and then the overburning microstructure along the parting surface is cracked into visible longitudinal cracks under the interaction of machining stress and thermal stress generated during the subsequent boring and heat treatment process. The main reason for the crack formation may be related to the overburning of the microstructure caused by the excessively high local temperature of the parting surface during the forging process, which belongs to the forging process defect.