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  • MICROSTRUCTURE AND PROPERTIES
    Microstructure and properties of Fe-Cr-Ni gradient alloy steel by direct laser deposition
    Zhan Di, Chen Suiyuan, Song Xiuwen, Chen Xueting, Wang Mei
    2023, 48(2):  1-9.  doi:10.13251/j.issn.0254-6051.2023.02.001
    Abstract ( 96 )   PDF (673KB) ( 138 )  
    An outside-strong but inside-tough 12CrNi2Y-50Cr6Ni2Y-70Cr8Ni2Y gradient alloy steel specimen was prepared by direct laser deposition technology. Then the microstructure, interfacial adhesion, hardness gradient distribution and wear resistance of the specimen were studied by means of metallographic microscope, scanning electron microscope, transmission electron microscope, hardness tester and friction testing machine. The results show that the 12CrNi2Y-50Cr6Ni2Y-70Cr8Ni2Y gradient alloy steel specimen with metallurgical bonding at the gradient transition interface and no crack inclusion defects is successfully prepared under the optimized laser deposition parameters. The microstructure of the specimen shows a change trend from (granular bainite+lath bainite+a small amount of martensite) to (lath bainite+lath martensite) to (lath martensite+plate martensite), the corresponding hardness changes as gradient distribution of 356 HV0.2 → 551 HV0.2 →712 HV0.2, and the volume wear rate as gradient distribution of 2.01×10-4 mm3·N-1·m-1 → 1.33×10-4 mm3·N-1·m-1 → 0.71×10-4 mm3·N-1·m-1. In the prepared gradient alloy steel specimen, due to the increase of C and Cr content, the hardness of the specimen shows a gradient distribution from low to high, and the wear resistance of the surface working layer is improved by nearly 2.8 times, so the outside-strong but inside-tough requirements is realized by gradient distributions of microstructure and properties. The obvious element diffusion of small-size C atoms near the transition interface of gradient alloy steel specimen promotes the metallurgical bonding of gradient interface.
    Influence of Mo content and pressure on properties of CrZrNbTiMox refractory high-entropy alloy calculated by first-principles
    Chen Ba, Li Xinmei, Chen Wenjie, Lu Guochuang, Shang Li, Tian Luyan
    2023, 48(2):  10-16.  doi:10.13251/j.issn.0254-6051.2023.02.002
    Abstract ( 42 )   PDF (605KB) ( 42 )  
    First-principles method based on density functional theory was used to study the influence of Mo content and pressure on phase structure, elastic constants and elastic modulus of CrZrNbTiMox refractory high-entropy alloy. The mixing enthalpy (ΔHmix), mixing entropy (ΔSmix), atomic radius difference (δ), valence electron concentration (VEC) and parameter Ω of the alloy were calculated. The results show that the CrZrNbTiMox refractory high-entropy alloy is mainly composed of a single BCC disordered solid solution structure. With the increase of Mo content, the lattice distortion of the alloy is continuously reduced, but the mechanical properties are stable and the alloy is always bonded with metallic bonds. The addition of Mo greatly improves the volumetric deformation resistance of the alloy, but has less influence on shear strain resistance and stiffness, and the alloy behaves as a ductile material. Under the pressure of 0-25 GPa, the CrZrNbTiMo0.6 alloy exhibits excellent phase stability and mechanical stability, while the increment of bulk elastic modulus (B) is small, the variations of shear elastic modulus (G) and Young's modulus (E) are small, and the Poisson's ratio μ and G/B calculation results show that the alloy is a ductile material.
    Continuous cooling transformation of Cr-Ni-Cu bridge weathering steel and its microstructure and hardness
    Wang Xinzhi, Zhang Ke, Huang Zhong, Xu Dangwei, Du Haiming, Zhang Xiaofeng, Zhang Xi
    2023, 48(2):  17-22.  doi:10.13251/j.issn.0254-6051.2023.02.003
    Abstract ( 36 )   PDF (595KB) ( 49 )  
    In order to understand the changes of microstructure and hardness of Cr-Ni-Cu bridge weathering steel during continuous cooling transformation (CCT) and the causes, the CCT curves and time-temperature-transformation(TTT) curves were simulated and calculated by the JMatPro software. Microstructure and hardness of the Cr-Ni-Cu bridge weathering steel during CCT process were investigated by means of Gleeble-3800 hot-simulated test machine, optical microscope (OM), scanning electron microscope (SEM) and hardness tester, and the influencing mechanisms of cooling rate on microstructure, hardness and phase transformation behavior were discussed. The results show that after 1050 ℃ and 860 ℃ two-stage high temperature deformation, as the cooling rate increases from 0.1 ℃/s to 30 ℃/s, the microstructures of Cr-Ni-Cu bridge weathering steel are successively evolving from polygonal ferrite+pearlite→polygonal ferrite+bainite→granular bainite→granular bainite+martensite, and the hardness increases gradually from 155 HV0.2 to 373 HV0.2. When the cooling rate increases from 0.1 ℃/s to 3 ℃/s, the increase of hardness is mainly due to the refinement of polygonal ferrite grains. While the cooling rate increases from 5 ℃/s to 30 ℃/s, the increase of hardness is attributed to the continuous refinement of bainite microstructure and the consistent increase of martensite content.
    Effect of Bi on surface wettability of molten zinc and X80 steel
    Li Hangzhou, Peng Haoping, Xu Shouwu, Deng Song, Tu Hao, Lei Yun, Su Xuping
    2023, 48(2):  23-29.  doi:10.13251/j.issn.0254-6051.2023.02.004
    Abstract ( 22 )   PDF (599KB) ( 29 )  
    Wetting behavior of Zn-xBi alloy melts (x=0.5, 1.0, 1.5, 2.0) with different substrates at 450 ℃ was studied by improved sessile drop method, and the surface tensions after wetting reaction were calculated. The morphology and structure of the surface and cross-section of the specimens after the wetting reaction were analyzed by means of scanning electron microscope-energy dispersive spectrometer (SEM-EDS). The results show that the surface tension of Zn-Bi alloy melts at 450 ℃ decreases first and then increases with the increase of Bi content. The contact angle between the Zn-1.0Bi alloy melt and X80 steel is the smallest, indicating that the wettability of molten zinc is the best after adding 1.0%Bi (mass fraction). The content of Bi in the Zn-Bi alloy melt affects the interfacial reaction intensity and interface structure, thereby reducing the surface tension and contact angle. The rapid adsorption of Bi element at the initial stage of wetting reduces the surface tension of molten zinc and reduces the contact angle. In the middle stage, it is controlled by the interfacial reaction intensity, which forms a precursor film and promotes the flow of zinc alloy melt on the steel substrate, thereby improving the wettability.
    Stress corrosion behavior of X80 dual-phase pipeline steel under applied potential in simulated coastal soil environment
    Ma Jing, Luo Hong, Wang Shenhao, Tong Anqi, Li Jianhui, Wang Jiangang, Feng Zhihao, Chen Yiqing
    2023, 48(2):  30-35.  doi:10.13251/j.issn.0254-6051.2023.02.005
    Abstract ( 28 )   PDF (595KB) ( 25 )  
    Stress corrosion behavior of X80 dual-phase pipeline steel in the simulated coastal soil environment under different applied potentials was studied by AC impedance spectroscopy, polarization test and slow strain rate tensile test. The tensile fracture and polarized specimens were analyzed by SEM and EDS. The results show that the self-corrosion potential of the X80 dual-phase pipeline steel by fast scanning polarization (simulated crack tip) is more negative and the corrosion current is higher than that of polarization at slow scanning rate (simulated non-crack tip area). Applied cathode potential of -750 mV is right about the self-corrosion potential of crack tip, which is not negative enough to play the role of cathodic protection, so that it is still very sensitive to stress corrosion. When the applied potential is -1050 mV, the cathode reaction rate is significantly higher than that of anode reaction, the hydrogen generated by cathode reaction is absorbed and diffuses in the steel, thus the slow strain tensile specimen breaks without necking, with the fracture being quasi cleavage. When the applied cathode potential is -900 mV, the cathode current effectively inhibits the anodic dissolution reaction, and the slow strain tensile strength and the percentage reduction of area of the X80 pipeline steel in coastal soil solution are the highest, the fracture is characterized by ductile fracture, small side cracks, the largest impedance modulus. Therefore the stress corrosion sensitivity of the X80 dual-phase pipeline steel under -900 mV cathodic potential is the smallest.
    Microstructure and mechanical properties of friction stir welded joint of pure aluminum-iron
    Pei Yu, Gao Kunyuan, Zhang Xiaojun, Huang Hui, Wu Xiaolan, Wen Shengping, Nie Zuoren
    2023, 48(2):  36-42.  doi:10.13251/j.issn.0254-6051.2023.02.006
    Abstract ( 32 )   PDF (594KB) ( 39 )  
    3 mm thickness cold rolled high purity aluminum plate and as-annealed iron plate were selected as the welding base materials, and welding parameters of 300/400/500/600 r/min-100 mm/min and 300 r/min-80/60 mm/min were respectively used to conduct friction stir welding butt welding experiments of aluminum/iron dissimilar metal. The mechanical properties of the joints were tested by microhardness test and tensile test, and the microstructure of the joints was characterized by scanning electron microscope(SEM), energy dispersive spectroscopy(EDS), electron backscattering diffraction (EBSD) and other means. The macroscopic observation of the weld shows that there are holes on the front and back of the weld and burrs on the front of the weld. With the increase of the rotation speed/welding speed ratio, the holes disappear and burrs increase. Tensile test results show that there are three failure modes: defect fracture at the hole location at 300 r/min-100 mm/min, Al/Fe interface fracture at 300 r/min-80/60 mm/min and Al matrix fracture at 400/500/600 r/min-100 mm/min. In this experiment, the maximum welding efficiency of the three modes is 40.1%, 41.0% and 60.4%, respectively, among which the welding efficiency of Al matrix fracture mode is the highest. The hole in the weld zone reduces the joint strength and leads to defect fracture. At the low rotation speed of 300 r/min, the interface fails to achieve effective metallurgical bonding, and the interface strength is lower than the Al matrix strength, leading to the fracture of the Al/Fe interface. The hardness test results show that the hardness of aluminum side decreases first and then increases, and the lowest point of hardness appears in the heat-affected zone 6-7 mm away from the Al-Fe interface, corresponding to the fracture position of Al matrix. With the increase of rotation speed, the interface strength is higher than Al matrix, leading to the fracture of Al matrix.
    High temperature thermo-plasticity of hot rolled Fe-1.80Mn-1.05Al-0.09C low density steel
    Ma Yingjian, Peng Qichun, Yuan Qing, Liang Liang, Qi Jianghua, Xiao Aida, Xue Zhengliang
    2023, 48(2):  43-49.  doi:10.13251/j.issn.0254-6051.2023.02.007
    Abstract ( 25 )   PDF (596KB) ( 30 )  
    High-temperature (760-1200 ℃) thermo-plasticity of a low alloy hot rolled low density steel was studied by means of Gleeble 3500 thermal simulation test machine. The fracture morphology and microstructure near fracture were characterized by optical microscope, stereomicroscope and scanning electron microscope. The results show that with the increase of tensile temperature, the fracture area gradually shrinks and dimples gradually become larger and deeper. The overall percentage reduction of area is good, which can reach more than 80%, showing good high temperature thermo-plasticity. However, when the tested steel is stretched at 900-1000 ℃, there are multiple neck shrinkage phenomena. There is a theoretical low plastic valley at 900-1000 ℃. It is necessary to avoid slab straightening or rolling at 900-1000 ℃.
    Influence of large carbides on rotating bending fatigue of GCr4Mo4V steel
    Cui Yi, Zhang Caidong, Yu Feng, Zhang Yunfei, Zhang Zhiwang, Cao Wenquan, Zhao Yingli, Cui Shaopu
    2023, 48(2):  50-55.  doi:10.13251/j.issn.0254-6051.2023.02.008
    Abstract ( 30 )   PDF (603KB) ( 33 )  
    Annealed hot rolled high temperature bearing steel GCr4Mo4V manufactured by “VIM+ESR” was heated at 1120 ℃ for 30 min before being oil quenched, and then the specimen was tempered at 530 ℃ for 2 h followed with air cooling for 3 times. The rotating bending fatigue experiment was carried out on the heat treated specimen under stress levels of 960, 1000, 1040 and 1080 MPa, respectively. The S-N curve was obtained via the experimental data. A median fatigue limit of 686 MPa is calculated accordingly. Analysis of the fracture morphology indicates that the rotating bending fracture of GCr4Mo4V bearing steel consists of 3 typical zones, which are near surface crack-initiated site, crack propagation zone and stress tearing zone. The distance between the crack initiated site and specimen surface is about 240 μm, and at the center of the crack-initiated site exists large size carbide, the particle size of which distributes in the range of 16.93-53.94 μm. The crack nucleates at the boundary between large size carbide and the matrix, and gradually propagates towards the center of the specimen; in the end, the specimen is teared into two pieces by the torsion stress. The mathematical analysis shows that, the size of the large carbides D shows a perfect linear relation with the logarithm of fatigue life N, and the mathematical relation is lg(N)=-0.053 77D+7.326 82 according to the fitting results. And it is clear that the extreme refinement of the large carbides is absolutely a significant way for life prolonging of GCr4Mo4V bearing steels.
    Influence of sulfur on high cycle fatigue property of 300M ultra-high strength steel
    Wang Fei, Zhao Xin
    2023, 48(2):  56-61.  doi:10.13251/j.issn.0254-6051.2023.02.009
    Abstract ( 27 )   PDF (595KB) ( 33 )  
    Microstructure and mechanical properties of 300M steels with high sulfur and low sulfur contents were systematically studied, and the influencing mechanisms of sulfur content on inclusion characters and high cycle fatigue life of the 300M steel were emphatically analyzed. The results indicate that high sulfur addition will dramatically decrease the high cycle fatigue life of 300M steel. Higher sulfur addition will increase the precipitating temperature and precipitating content of MnS inclusion, then the probability of large size MnS inclusions appearing in the subsurface of the specimen is increased, and the difficulty of high cycle fatigue crack initiation is greatly reduced, thus reducing the high cycle fatigue life of 300M steel.
    Transformations of Y12Cr18Ni9Cu free-cutting steel and precipitation behavior of MnS during equilibrium solidification
    Wang Yinghu, Zheng Huaibei, Liu Tingyao, Song Lingxi, Bai Qingqing
    2023, 48(2):  62-66.  doi:10.13251/j.issn.0254-6051.2023.02.010
    Abstract ( 19 )   PDF (599KB) ( 23 )  
    Thermo Calc thermodynamic software was used to calculate the precipitation phase of Y12Cr18Ni9Cu free-cutting steel in the temperature range from 500 ℃ to 1800 ℃, and the equilibrium solidification transformation path diagram was obtained. The results show that the main equilibrium phases in the Y12Cr18Ni9Cu free-cutting steel are MnS, Liquid, δ-Ferrite, Austenite, M23C6, M2(C, N) and Sigma. The equilibrium phase transition path is as follows: Liquid→Liquid+MnS→Liquid+δ-Ferrite+MnS→Liquid+δ-Ferrite+MnS+Austenite→δ-Ferrite+MnS+Austenite→MnS+Austenite→MnS+M23C6+Austenite→MnS+M23C6+Austenite+M2(C, N)→MnS+M23C6+Sigma+Austenite+M2(C, N). With the increase of S content, the precipitation amount and precipitation temperature of MnS gradually increase. The change of Mn content almost has no effect on the precipitation amount of MnS, but increasing Mn content will increase the precipitation temperature of MnS. The sulfides in the Y12Cr18Ni9Cu free-cutting steel are spherical, ellipsoidal, spindle shape or short-bar-like, and distribute in clusters along the grain boundary, belonging to a type II sulfide. The proportion of sulfides with length-width ratio ≤3 reaches 88.37%, and the sulfide morphology control has achieved good results, which is helpful to improve the cutting performance of the materials.
    Microstructure and mechanical properties of cold-rolled Fe-8Mn-xAl-0.2C medium Mn steel
    Zhang Zhenwei, Jing Songyang, Zhang Jincheng, Zhao Wenzhu, Ding Hua
    2023, 48(2):  67-73.  doi:10.13251/j.issn.0254-6051.2023.02.011
    Abstract ( 34 )   PDF (600KB) ( 29 )  
    Microstructure and mechanical properties of Fe-8Mn-xAl-0.2C(x=0, 3) cold-rolled medium Mn steel were studied by means of field emission scanning electron microscope, electron backscatter diffraction technology, X-ray diffractometer and electronic universal testing machine. The results show that the addition of Al increases the austenitizing temperature significantly, and the equiaxed austenite and ferrite dual-phase structures are obtained after annealing at higher intercritical annealing temperature. The stability of austenite is improved, which affects the strain hardening behavior of the tested steel during deformation, and the ductility of the steel is improved. When the Fe-8Mn-0.2C cold-rolled tested steel is annealed at 625 ℃, a good combination of strength and ductility is obtained with ultimate tensile strength (UTS) of 1220 MPa, tensile elongation (TE) of 44%, and UTS×TE of 54 GPa·%. But for the Fe-8Mn-3Al-0.2C cold-rolled tested steel, the good combination of strength and ductility is obtained with ultimate tensile strength (UTS) of 970 MPa, tensile elongation (TE) of 58%, UTS×TE of 56 GPa·% when annealed at 710 ℃. Furthermore, the addition of Al widens the intercritical annealing temperature window to attain good mechanical properties.
    Martensitic degeneration behavior of P91 steel served for eighty-eight thousand hours in a supercritical unit
    Zhang Anwen, Wang Yang, Zhang Zhibo, Jiang Feng
    2023, 48(2):  74-78.  doi:10.13251/j.issn.0254-6051.2023.02.012
    Abstract ( 21 )   PDF (594KB) ( 22 )  
    Martensite structure differences between P91 steel not in service and in service over 80 000 hours were compared by means of SEM, EBSD and TEM at different scales. The statistical and quantitative comparison of martensitic structure was made, the degradation behavior of martensitic structure in long-term service was analyzed, and the influence mechanism of martensitic structure degradation on mechanical properties was discussed. The results show that the structure of martensite block is coarsened, the average size of block increases by 61.6%, and the vertex value of size normal distribution increases by 70%. The martensite packet structure is also coarsened, the average size increases by 21%, and the normal distribution vertex value increases by 25.4%. The structure coarsening of packet is realized by the coarsening of block, and the degree of coarsening of block is greater than that of packet. The dislocation density decreases, resulting in a decrease of 8.6% in the proportion of structure with misorientation less than 15°. The coarsening of block structure and the decrease of dislocation density in martensitic structure are the important factors leading to the decrease of strength of the P91 steel after long-term service.
    Phase transformation behavior of high-carbon cord steel during cooling
    Chu Feng, Shen Kui, Hu Xianjun, Zhang Jiming
    2023, 48(2):  79-84.  doi:10.13251/j.issn.0254-6051.2023.02.013
    Abstract ( 23 )   PDF (593KB) ( 29 )  
    CCT curves and TTT curves of a high-carbon cord steel were investigated by using the Gleeble-3800 thermal simulator, and the effects of cooling rate and isothermal transformation temperature on microstructure and properties were studied. The results show that during the continuous cooling process, the critical cooling rates for the formation of grain boundary cementite and martensite are 1.5 ℃/s and 11 ℃/s, respectively. For the isothermal transformation, the temperature range of pearlitic transformation is 600-700 ℃, the transformation time is the shortest at 625 ℃. The higher the isothermal temperature, the longer the phase transformation time, but when the isothermal temperature decreases, the abnormal structure bainite forms. By actually using the Stelmor controlled cooling technique, controlling the spinning temperature at 900 ℃, and starting the first five fans with air volume being 100%/100%/80%/50%/30% respectively, so that the phase transformation cooling rate is controlled as 5-7 ℃/s and the network carbide forming interval can be passed through as soon as possible before the phase transformation, then the high-strength cord steel with microstructure and properties meeting the technical requirements can be produced.
    PROCESS RESEARCH
    Effect of austempering on high temperature frictional wear property of Dievar hot working die steel
    Yang Liu, Xie Yixin, Ju Yulin, Wei Qi, Cao Fuyang, Luo Rui, Yuan Zhizhong, Cheng Xiaonong
    2023, 48(2):  85-93.  doi:10.13251/j.issn.0254-6051.2023.02.014
    Abstract ( 45 )   PDF (596KB) ( 53 )  
    Mixed microstructure with different volume fractions of lower bainite and martensite was produced in Dievar steel by austempering, and then the high temperature frictional wear performance and mechanism of the Dievar steel were investigated based on the microstructure identification, hardness evaluation, worn surface morphology and wear rate analysis. The results show that the volume fraction of lower bainite in the Dievar steel increases with the increase of austempering time, where the bainitic volume fractions are 32%, 45% and 63% with isothermal holding for 3, 5 and 10 min respectively. Compared to the conventional oil quenched specimens, the specimens with the mixed microstructure have higher tempering resistance. The hardness values for austempered specimens are higher than that of oil quenched ones. In addition, the austempered specimens exhibit better wear resistance compared to the conventional oil quenched ones under the same wear condition. Under the high temperature friction and wear test conditions of 400-600 ℃, the surface oxides of the Dievar steel are Fe2O3 and Fe3O4. The high temperature wear mechanism at 400-500 ℃ for the Dievar steel is abrasive-slight oxidation wear. As the temperature increases, the size of oxide particles becomes larger and the abrasive wear is strengthened. When the temperature approaches to 600 ℃, the high temperature wear mechanism for the conventional oil quenched specimens is still maintained as abrasive-oxidation wear, mainly abrasive wear, however, it alters to the oxidation wear for the austempered specimens.
    Aging precipitation behavior of Cu-rich particles of low-carbon Cu-bearing medium and heavy steel plate
    Sun Mingxuan, Meng Li, Zhang Ning, Zhang Bo, Liang Fengrui, Luo Xiaobing
    2023, 48(2):  94-102.  doi:10.13251/j.issn.0254-6051.2023.02.015
    Abstract ( 17 )   PDF (594KB) ( 31 )  
    A low-carbon Cu-bearing medium and heavy steel plate was aged at 680 ℃ for different time (15, 30, 45, 75, 90, 120 min). The precipitation and growth mechanism of Cu-rich particles at different positions of medium and heavy steel plate were analyzed by field emission scanning electron microscopy (SEM) and energy disperse spectroscopy (EDS). The results show that after aging treatment, the Cu-rich particles on surface and in core of the tested steel plate are spherical or short rod-shaped, and the size is mainly in the range of 5-60 nm, but the average size of Cu-rich particles in the core is larger than that on the surface. With the increase of aging time, the Cu-rich particles on the surface and in the core grow at the same time, showing a trend of the average size increasing and the total number of particles decreasing. Based on the theoretical calculation, the change of average size of Cu-rich particles satisfies the Ostwald ripening mechanism, and the growth rate of Cu-rich particles in the core is smaller than that on the surface.
    Hot deformation behavior and microstructure evolution of 18CrNiMo7-6 gear steel
    Xie Yikui, Wang Qicheng, Chen Zikun, Wu Xiaodong, Wang Zhongying
    2023, 48(2):  103-109.  doi:10.13251/j.issn.0254-6051.2023.02.016
    Abstract ( 21 )   PDF (569KB) ( 42 )  
    Isothermal single-pass compression test of the 18CrNiMo7-6 gear steel was carried out by Gleeble-3500 thermal simulation testing machine. The hot deformation behavior of the tested steel was studied under the conditions of deformation temperature of 900-1150 ℃, strain rate of 0.01-5 s-1 and strain of 0.76, and the microstructure after hot deformation was analyzed by optical microscope. The Arrhenius constitutive equation is established, and the predicted peak stress is in good agreement with the experimental data. The hot deformation process at high temperature is a competitive process between work hardening and dynamic recovery and dynamic recrystallization. In the process of hot deformation, four types of microstructure including deformed grains, recrystallized grains, equiaxed grains and grown grains are observed. When the strain rate is 0.01 s-1, the higher the temperature, the more sufficient the dynamic recrystallization. However, when the deformation temperature exceeds 1050 ℃, the deformation energy transforms into the driving energy of grain growth, which makes the grains coarsen. When the deformation temperature is constant (1050 ℃), with the increase of strain rate, the dynamic recrystallization occurs incompletely, the resulted grains are mixed of refined, distorted and incompletely recrystallized ones. The larger the deformation degree, the smaller the grain size.
    Effect of deformation and cooling rate on transformation characteristic and nanoscale precipitation in a low carbon Nb micro-alloyed steel
    Liu Yanqiang, Yang Hao, Zhang Zhijun, Jia Shujun, Han Pengbiao
    2023, 48(2):  110-116.  doi:10.13251/j.issn.0254-6051.2023.02.017
    Abstract ( 17 )   PDF (569KB) ( 24 )  
    Effects of austenite recrystallization and unrecrystallization structure on continuous cooling transformation behavior of low carbon Nb micro-alloyed steel were studied by Gleeble 3800 thermal simulator, and the nano precipitation behavior of Nb(C,N) at different deformation temperatures and cooling rates was analyzed. It is found that the plastic deformation in un-recrystallization region of austenite accelerates the ferrite transformation and the ferrite transformation zone is enlarged. The deformation also refines the ferrite grain size. Compared with the single-pass deformation at recrystallizing 1050 ℃, the second deformation in the unrecrystallized zone can promote the precipitation of Nb(C, N), and the precipitation of Nb(C, N) at 910 ℃ is the largest, followed by that at 850 ℃. The increase of cooling rate can inhibit the precipitation of Nb(C, N) in austenite, but can promote its precipitation in ferrite. And the size of precipitates is refined with the increase of cooling rate. When the cooling rate reaches 10 ℃/s, the nucleation of precipitation is totally inhibited during cooling process.
    Intensive quenching and tempering of 40Cr steel
    Yang Denggui, Zhu Xiaoshuo, Fu Yudong, Alinuer·Maimaiti
    2023, 48(2):  117-123.  doi:10.13251/j.issn.0254-6051.2023.02.018
    Abstract ( 38 )   PDF (572KB) ( 37 )  
    CaCl2 aqueous solution was used as quenching medium to carry out intensive quenching process for the 40Cr steel, followed by high temperature tempering. The microstructure, mechanical properties and fracture morphologies were characterized by means of optical microscope, scanning electron microscope, hardness tester, impact and tensile tester, and compared with that of the oil quenching and tempering process. The results show that the fine and uniform tempered martensite can be obtained by intensive quenching with CaCl2 quenching medium and high temperature tempering compared with oil quenching and tempering process. After intensive quenching and tempering, compared with conventional quenching and tempering process, the hardness is increased by 8%-18%, the strength is increased by 3%-5%, and the impact property is increased by 16%-30%, which can meet the requirements of higher service performance. The optimal quenching and tempering process for the 40Cr steel is austenitizing at 850 ℃ for 20 min, followed by intensive quenching with CaCl2 quenching medium, and then tempering at 580 ℃ for 120 min plus air cooling.
    Effect of quenching temperature on microstructure and properties of arc microcast forged AerMet100 steel
    Xu Zhongzhi, Huang Shunzhe, Dai Jianke, Han Shun, Li Yong, Wang Chunxu, Zhang Haiou
    2023, 48(2):  124-130.  doi:10.13251/j.issn.0254-6051.2023.02.019
    Abstract ( 19 )   PDF (627KB) ( 24 )  
    Effect of different quenching temperatures in the range of 885-1150 ℃ on microstructure and mechanical properties of arc microcast forged AerMet100 ultra-high strength steel was investigated by means of OM, XRD, SEM, TEM and mechanical property tests. The results show that the original microstructure of the AerMet100 steel consists mainly of slatted martensite and austenite, and with rapid solidification characteristics. With the increase of quenching temperature, the solidification characteristics of the tested steel disappear gradually, and is almost completely eliminated when the temperature exceeds 1050 ℃. With quenching temperature increasing, the fracture toughness of the tested steel shows an increasing trend, while the tensile and yield strengths do not variation significantly, and the impact absorbed energy shows a tendency of first increasing and then decreasing, reaching a peak at 1050 ℃. In the experimental temperature range, quenching at around 1050 ℃ results in an excellent match of strength and toughness, with a fracture toughness of 82.9 MPa·m1/2, a tensile strength of 2010 MPa, and an impact absorbed energy of 50 J.
    Homogenization treatment and microstructure evolution of Al-2.4Cu-1.3Li alloy micro-alloyed with Yb
    Zheng Zhi, Gao Kunyuan, Wen Shengping, Huang Hui, Wu Xiaolan, Wei Wu, Nie Zuoren
    2023, 48(2):  131-137.  doi:10.13251/j.issn.0254-6051.2023.02.020
    Abstract ( 20 )   PDF (573KB) ( 24 )  
    Microstructure evolution of the Al-2.4Cu-1.3Li-(Yb) alloys during homogenization was analyzed by means of SEM, EDS, DSC and XRD measurements. The SEM observations show obvious dendrite in the as-cast alloys with the average dendrite spacing of 45±6 μm(Al-Cu-Li alloy) and 43±7 μm(Al-Cu-Li-Yb alloy), respectively. The morphology of primary phase is block or strip-like with 2.8% (Al-Cu-Li alloy) and 2.2% (Al-Cu-Li-Yb alloy) in relative ratio of area in SEM images. EDS and XRD results show that primary phases include mainly several types of Al-Cu-(Li) phases and Al8Cu4Yb phase additionally in case of the Al-Cu-Li-Yb alloy. Based on the DSC and homogenization kinetic analysis, the homogenization treatment is determined to be 500 ℃×12 h for remove the dendrite segregation. The corresponding SEM images of the specimens after homogenization treatment demonstrate that the retained phases are gathered tiny spheres of AlCuFe phases and/or skeletal-like Al8Cu4Yb phase, with the area fraction decreasing to 0.93% (Al-Cu-Li alloy) and 0.76% (Al-Cu-Li-Yb alloy), respectively. In order to dissolve more Yb to the matrix, a two-step homogenization treatment for the Al-Cu-Li-Yb alloy is determined experimentally to be 500 ℃×12 h+530 ℃×12 h. The SEM analysis showes the relative ratio of area of retained phases reduces to 0.53%. The morphology is the same as that of one-step homogenization annealing.
    Effect of solution forming process on microstructure and mechanical properties of 6016 aluminum alloy
    Liu Meng, Li Xinya, Zang Yong, Huang Jianghua, Sun Fuzhen, Ren He
    2023, 48(2):  138-143.  doi:10.13251/j.issn.0254-6051.2023.02.021
    Abstract ( 23 )   PDF (568KB) ( 23 )  
    For changing the poor plasticity and low elongation of the aluminum alloy at room temperature, based on the characteristics of aluminum alloy solid solution treatment, a solid solution forming method was investigated. In order to obtain optimum process parameters of the 6016-T6 aluminum alloy solid, tensile strength at different heating temperatures, heat preservation time and different cooling methods were measured by the electronic tensile testing machine and the influence of different process parameters on the mechanical properties were analyzed. The results show that the cooling speed has great influence on microstructure and properties of the materials. When the solution technological parameter is 550 ℃×5 min, water cooling, the tensile strength can reach maximum values, which are more than 300 MPa. The above process parameters have been used to test and verify the lower cross beam of the rear windshield made of the aluminum alloy, and the hot formed parts are trial-produced and qualified, and the tensile strength of these parts could reach 308 MPa.
    Effect of aging temperature on microstructure and mechanical properties of SLM 18Ni300 maraging steel
    Xu Dayang, Chen Wanqi, Wan Jifang, Huang Feng, Zhang Shiqi
    2023, 48(2):  144-149.  doi:10.13251/j.issn.0254-6051.2023.02.022
    Abstract ( 19 )   PDF (571KB) ( 25 )  
    Effect of aging temperature (390, 490, 590 ℃) on microstructure and mechanical properties of selective laser melting (SLM) 18Ni300 maraging steel was investigated by means of tensile test, hardness test and microstructure characterization. The results show that the microstructure of the as-printed SLM 18Ni300 steel specimen is composed mainly of Fe-Ni martensite matrix and cellular substructure, which changes significantly after aging treatment. With the increase of aging temperature, the cellular substructure gradually decomposes, the martensite transforms into reversed austenite, and the fraction of Σ3 grain boundaries decreases. Meanwhile, dispersed nano-sized Ni3X precipitates are formed and coarsen at 590 ℃. With the increase of aging temperature, the strength and hardness of the SLM 18Ni300 maraging steel increase first and then decrease, while the elongation decreases first and then increases. When aged at 490 ℃, the steel has both high strength and good plasticity, which is attributed to the dispersed nano-sized precipitates in the matrix, moderate content of austenite and low fraction of Σ3 grain boundaries.
    Effect of homogenization treatment on microstructure and mechanical properties of GH5188 alloy
    Qi Huilin, Jiang Shichuan, Guo Xulong
    2023, 48(2):  150-157.  doi:10.13251/j.issn.0254-6051.2023.02.023
    Abstract ( 27 )   PDF (577KB) ( 26 )  
    Law of solute element segregation and microstructure evolution during homogenization heat treatment process of GH5188 alloy ingots and the effect of homogenization process on mechanical properties of GH5188 alloy were analyzed by means of JMatPro software, metallurgical microscope, scanning electron microscopy, energy dispersive spectroscopy and high temperature tensile and compression tests. The results show that the main precipitation phases of the GH5188 alloy are M6C and M23C6, the important positive segregation elements are W and Cr, and important negative segregation elements are Ni and Co. 1200 ℃×72 h homogenization treatment can reduce original precipitated phases in as-cast ingots, eliminate W, Cr, Ni, Co, et al element segregation and achieve the most suitable uniformity. After homogenization heat treatment process, the mechanical properties of the GH5188 alloy are improved. Under tensile and compression conditions at 1180 ℃, the tensile strength reaches 158 MPa, and the deformation resistance is 244.29 MPa.
    Effect of annealing treatment on microstructure and mechanical properties of CoCrFeNiB0.05Ti0.6 high entropy alloy
    Jiang Yue, Tan Yaping, Zhu Baixiang, Zhang Tiandong
    2023, 48(2):  158-163.  doi:10.13251/j.issn.0254-6051.2023.02.024
    Abstract ( 25 )   PDF (570KB) ( 25 )  
    The high entropy alloy powder of CoCrFeNiB0.05Ti0.6 was prepared by means of mechanical alloying method, and the CoCrFeNiB0.05Ti0.6 high entropy alloy was sintered by the powder metallurgy method. Then the sintered specimens were annealed at 450, 650 and 850 ℃ for 12 h, respectively. The phase structure of the CoCrFeNiB0.05Ti0.6 high entropy alloy before and after annealing were analyzed by using the X-ray diffractometer, the microstructure morphology and elemental distribution of the CoCrFeNiB0.05Ti0.6 high-entropy alloy before and after annealing were analyzed by SEM and EDS, while the Vickers hardness and compression strength of the specimens were measured by HXD-1000 Vickers hardness tester and WDW-200 universal experimental tester, respectively. The results show that the sintered alloy is mainly FCC phase accompanied by a small amount of HCP and Laves phase. And new phases such as BCC and borides are generated successively as the annealing temperature increasing. Furthermore, it can be seen that the diffusion of the element Cr from light gray dendrites to dark gray dendrites grows gradually, and the element B forms new borides with other elements. The sintered alloy is dendrite and interdendrite structure, and the proportion of interdendrite structure increases and dendrite structure decreases after annealing. In addition, the higher the annealing temperature is, the greater hardness and compressive strength of the CoCrFeNiB0.05Ti0.6high entropy alloy will be, reaching maximum values of 391.40 HV0.2 and 664.6 MPa respectively after annealing at 850 ℃, which is the results of combined effects of solid solution strengthening, fine grain strengthening, and second phase strengthening.
    Inhomogeneity inhibiting embrittlement of Zr-based bulk metallic glass
    Hou Qiqi, Zhou Jialu, Wang Tuo
    2023, 48(2):  164-169.  doi:10.13251/j.issn.0254-6051.2023.02.025
    Abstract ( 18 )   PDF (569KB) ( 30 )  
    Correlation between compressive plasticity at ambient temperature and microstructure of as-cast and annealed Zr47.25Cu47.25Al5.5bulk metallic glass (BMG) was studied. The results show that the compressive plasticity of the as-cast Zr47.25Cu47.25Al5.5BMG is 3.96%, and the compressive plasticity of the alloys is improved after annealing for 0.5, 1.5, 3 and 6 h, respectively. After annealing for 0.5 h, the compressive plasticity is the largest of 5.84%. The microstructure of the as-cast Zr47.25Cu47.25Al5.5BMG presents a network distribution of about 5 nm. After annealing for 6 h, the size of the Cu-rich network zone is about 50 nm with a small amount of crystallization. This microstructure inhomogeneity leads to the plasticity of the as-cast alloy at ambient temperature, and inhibits the embrittlement which is caused by the reduction of free volume during annealing.
    Effect of annealing on microstructure and hardness of AlCuFeNiTiCrx high entropy alloys
    Zhang Xiaorong, Shang Hualong
    2023, 48(2):  170-173.  doi:10.13251/j.issn.0254-6051.2023.02.026
    Abstract ( 26 )   PDF (580KB) ( 31 )  
    AlCuFeNiTiCrx(x=0.5, 1.0, 1.5, 2.0) high entropy alloys were prepared by copper mold suction casting method, then the specimens were annealed at 1000 ℃ for 3 h. Microstructure evolution and hardness of as-cast and as-annealed AlCuFeNiTiCrx(x=0.5, 1.0, 1.5, 2.0) alloys were tested by X-ray diffraction (XRD), optical microscope, Vickers hardness tester, respectively. It is found that both of the as-cast and the as-annealed specimens consist only simple body-centered cubic (BCC) and face-centered cubic (FCC) solid solution phases, while the FCC phase in the as-annealed specimens increases compared with that in the as-cast specimens. There are only dendrite and interdendrite phases for both the as-cast and the as-annealed alloys, though the microstructure becomes more homogeneous after annealing according to the metallographical micrographs. The hardness increases with the increase of Cr content, and the as-annealed hardness values are much higher than the as-cast ones because the increase of FCC phase in the as-annealed specimens.
    Effect of annealing time on microstructure and mechanical properties of medium carbon steel subcritical quenched
    Li Yaguang, Zhang Jiahao, Li Hongbin, Zhao Zhihao, Xu Haiwei, Tian Yaqiang, Chen Liansheng
    2023, 48(2):  174-179.  doi:10.13251/j.issn.0254-6051.2023.02.027
    Abstract ( 39 )   PDF (569KB) ( 22 )  
    The hot-rolled medium carbon steel was subcritical quenched, then cold rolled(deformation of 50%) and annealed at 550 ℃ for different time. The microstructure of annealed specimens was characterized by means of scanning electron microscopy(SEM), X-ray diffraction (XRD) and backscattered electron diffraction (EBSD), and the effect of bimodal structure on mechanical properties was analyzed by means of tensile experiments at room temperature. The results show that the microstructure after annealing is composed of ferrite and cementite, and the ferrite is composed of fine and coarse crystal regions. With the prolongation of time, the peak value of fine crystal increases slightly, the increase is not obvious, but the peak value of coarse crystal decreases. With the increase of annealing time, the tensile strength and yield strength of the specimens show a decreasing trend, while the elongation shows an increasing trend. The size and depth of dimples increase, and small dimples are enriched near large dimples. When the annealing time is 30 min, the mechanical properties are the best.
    Effect of heat treatment on microstructure and precipitate evolution of IN718 alloy prepared by laser additive manufacturing
    Cao Yu, Bai Pucun, Wei Anni, Liu Fei, Hou Xiaohu
    2023, 48(2):  180-188.  doi:10.13251/j.issn.0254-6051.2023.02.028
    Abstract ( 15 )   PDF (572KB) ( 20 )  
    Evolution of microstructure and precipitates of the IN718 alloy after heat treatments was investigated by using solid solution+double aging(SA), homogenization+double aging(HA), homogenization+solid solution+double aging(HAS), respectively. The results show that the microstructure in the as-deposited specimen is a columnar crystal microstructure and runs through multiple sedimentary layers. Recrystallization occurs after SA heat treatment. Recrystallization is significantly improved after heat treatment of HA and HSA. Heat treatment can promote the progressive transformation of columnar crystals into equiaxed crystals. There are γ matrix, Laves segregation phase and some carbides in the as-deposited specimen. After SA heat treatment, most of the Laves segregation phase is dissolved, and a large number of acicular δ phases precipitate between the grain boundaries, the crystals, and the dendrites, and some carbides remain. After HSA heat treatment, the Laves segregation phase is completely dissolved, and some δ phase precipitate at the grain boundary, and a small amount of carbides retain. There is no γ′ and γ″ phase precipitated in the as-deposited specimen, and a large number of γ′ and γ″ phases precipitate in the three heat treatment states.
    Heat treatment process of 00Ni18Co7Mo5Ti steel for belting of star arrow relief lock
    Wang Ping, Tian Shaokun, Zhu Hongwei, Yang Kun, Jin Yuanping, Wang Shuqing, Huang Yanjun, Zhu Jing
    2023, 48(2):  189-194.  doi:10.13251/j.issn.0254-6051.2023.02.029
    Abstract ( 17 )   PDF (572KB) ( 19 )  
    The strength and elongation of the 00Ni18Co7Mo5Ti maraging hardened stainless steel at different aging temperatures were studied by means of universal testing machine and Rockwell hardness tester. The analyses from mechanism show that the strength of the steel increases with the increase of aging temperature, and reaches the peak value at about 500 ℃ because of the precipitation of Ni3Ti and Ni3Mo dispersive phases. As the temperature continues to increase, the strength of the steel gradually decreases, while the elongation gradually increases due to the increase of reversed austenite. At the same time, the experiments and mechanism analysis show that on the premise that the strength of the steel does not be greatly reduced, appropriately increasing the aging temperature or prolonging the aging time can increase the elongation of the steel by increasing the content of reversed austenite, where the microstructure of the steel is mainly martensite and a small amount of reversed austenite, and the main strengthening phases are Ni3Ti, Ni3Mo and other dispersed phases.
    Effect of solution treatment on microstructure and properties of TC11 titanium alloy
    Tong Xiaole, Zhang Mingyu, Yue Xu, Yang Bin, Wang Yujia, Ardak Almas
    2023, 48(2):  195-199.  doi:10.13251/j.issn.0254-6051.2023.02.030
    Abstract ( 31 )   PDF (578KB) ( 28 )  
    Relationship between microstructure and mechanical properties of the TC11 titanium alloy after solution treatment at 955, 975, 995 and 1015 ℃, respectively, was studied by means of optical microscope, scanning electron microscope, X-ray diffraction and room temperature tensile test. The results show that the original as-forged microstructure of the alloy is a bimodal structure formed by forging in the α+β two-phase region, which is dominated by αp phase and β transformation structure. After solution treatment, the twisted and elongated αp phase in the original as-forged structure gradually becomes smaller and rounded with the increase of solution treatment temperature, and the smaller αp phase gradually disappears. When the solution treatment temperature is 995 ℃, the strengths of the alloy reach the maximum, of which the tensile strength (Rm) is 1403 MPa and the yield strength (Rp0.2) is 1158 MPa. When the solution treatment temperature is 955 ℃, the plasticity of the alloy is the best, of which the elongation after fracture (A) is 9.5% and the percentage reduction of area (Z) is 32%. When the solution treatment temperature is in the two-phase region, the tensile fracture morphology is similar, which is mainly dimples. When the solution treatment temperature is in the single-phase region, the fracture morphology is obviously crystalline and has large tearing edges, and there are a large number of small tearing dimples on the rock-like surface.
    Effect of solid solution treatment on secondary phase and hardness of Gd containing stainless steel
    Wang Yurong, Wu Yu, Li Yongwang, Pan Qianfu, Jiang Mingzhong
    2023, 48(2):  200-205.  doi:10.13251/j.issn.0254-6051.2023.02.031
    Abstract ( 18 )   PDF (575KB) ( 26 )  
    The effect of different solid solution treatment temperatures on secondary phase and hardness of the Gd containing stainless steel was studied. The results show that after solid solution treated in the range of 1000-1150 ℃ for 30 min, the continuous secondary phase precipitated along the grain boundary only partially melts, a large number of secondary phases are dispersed in the matrix, and the “bright white” phase is wrapped by the “gray” phase. The element composition and content of “gray” phase are relatively stable. After the solid solution treatment at 1000-1070 ℃ for 30 min, almost all the Ni of the “bright white” phase is dissolved, Gd is concentrated and enriched, its size is reduced, the “gray” phase grows large and slow, and some of the “gray” phase changes to short rod shape. When the solid solution temperature rises to 1150 ℃,while Ni dissolves in the “bright white” phase, Gd diffuses and slightly dissolves, most of the “bright white” phase disappears, the “gray” phase coarsens and spheroids. The hardness of the alloy after solid solution treatment is lower than that before solid solution treatment. With the increase of solid solution temperature, the hardness of the alloy increases.
    Effect of rolling temperature and amount on microstructure and mechanical properties of TB2 titanium alloy
    Zhang Xiong, Jing Ran, Zhang Qing, Liu Yirou, Wu Qian, Li Jianghua, Chui Pengfei
    2023, 48(2):  206-211.  doi:10.13251/j.issn.0254-6051.2023.02.032
    Abstract ( 61 )   PDF (537KB) ( 30 )  
    Effects of rolling temperature and deformation amount on microstructure, phase structure and mechanical properties of the TB2 titanium alloy were studied by means of X-ray diffractometer, optical microscope, scanning electron microscope, hardness tester and universal tensile testing machine. The results show that after rolling at 600 ℃, the TB2 titanium alloy consists of β and α phases. At the same rolling temperature, as the deformation amount increases, the grains in the alloy are elongated, the β phase in the matrix is partially broken, and a large amount of recrystallization grains form on the grain boundaries. When the rolling temperature is 600 ℃ and the deformation is 60%, the maximum tensile strength of the alloy can reach 1360 MPa and the elongation is 5.7%. When the rolling temperature is 600 ℃ and the deformation is 40%, the maximum tensile strength of the alloy reaches 1270 MPa, the elongation is 10.9%, and the comprehensive mechanical properties are better.
    Induction hardening process optimization of microalloyed medium carbon steel 48MnV for crankshaft connecting rod journal
    Mao Xiaofeng, Li Yajun, Deng Shigui, Li Xinkai, Zhao Huan, Wang Rong
    2023, 48(2):  212-218.  doi:10.13251/j.issn.0254-6051.2023.02.033
    Abstract ( 12 )   PDF (535KB) ( 18 )  
    Optimum process of induction heat treatment of microalloyed medium carbon steel 48MnV crankshaft connecting rod journal was studied by means of contrast test with quenching energy, tempering conditions, heating time and cooling time as variables. The results show that the optimized induction heat treatment process consists of quenching power of 165 kW, current frequency of 9 kHz, heating time of 17 s, cooling interval time of 1 s, cooling time of 20 s, and tempering at 210 ℃ for 2.5 h. Under the optimized induction heat treatment process, the microstructure of the hardened layer of connecting rod journal is fine and uniform acicular martensite; the maximum hardness of the journal surface and the position 0.25 mm from the surface of fillet on both sides can reach 720.9, 690.0 and 667.1 HV, respectively, and the wear resistance is significantly improved; the residual stress on the surface of connecting rod journal and fillet is compressive stress, the residual stress of the transition fillet near the spindle end is up to -884.0 MPa, and the residual stress of the transition fillet near the flange end is -831.9 MPa. The fatigue limit load of the specimen is the highest, up to 3750 N·m. The greater the residual compressive stress after induction heat treatment, the better the bending fatigue strength of the crankshaft connecting rod journal.
    Effects of cold deformation and annealing process on microstructure and properties of austenitic stainless steel for low temperature
    Li Yang, Zhang Wei, Yuan Gang
    2023, 48(2):  219-222.  doi:10.13251/j.issn.0254-6051.2023.02.034
    Abstract ( 26 )   PDF (535KB) ( 37 )  
    Effects of cold deformation and annealing process on microstructure and properties of the 304L austenitic stainless steel for low temperature were studied by means of cold rolling test, annealing test, microstructure observation and mechanical properties testing. The results show that with the increase of cold rolling deformation, the cold rolled grains are elongated and broken along the rolling direction, the density of deformation band gradually increases, the strength of cold rolled steel sheet increases and the elongation decreases. With the increase of annealing temperature, the recrystallized grain size increases gradually, the grain growth trend increases obviously when the annealing temperature is higher than 1120 ℃, the strength of the annealed steel sheet decreases, while the elongation increases. During annealing, the apparent activation energy of grain growth increases with the increase of cold deformation. During low temperature annealing, with the increase of cold rolling deformation, the grain size gradually decreases and the strength increases, while the elongation decreases. The trend is just the opposite during high temperature annealing.
    Effect of solution treatment on microstructure and hardness of A286 alloy
    Li Jidong, Wang Yan, Gu Yu, Wang Bin
    2023, 48(2):  223-227.  doi:10.13251/j.issn.0254-6051.2023.02.035
    Abstract ( 25 )   PDF (537KB) ( 28 )  
    Effects of solution treatment temperature (980, 1000, 1020 ℃) and holding time (60, 90, 120 min) on microstructure and hardness of the A286 alloy were studied by means of optical microscope, scanning electron microscope and Rockwell hardness tester. The results show that the hot rolled alloy matrix is a homogeneous recrystallized austenitic grain structure, with primary carbonitrides in it. With the increase of solution treatment temperature and holding time, the recrystallized grains preferentially grow from the surface and gradually expand to the inside, and phosphides with larger size are precipitated on the grain boundary, the hardness of the alloy decreases slightly.
    Stability of reversed austenite in 9%Ni steel after heat treatment
    Chen Rui, Bao Cuimin, Yang Zhipeng, Lin Lin
    2023, 48(2):  228-231.  doi:10.13251/j.issn.0254-6051.2023.02.036
    Abstract ( 18 )   PDF (534KB) ( 24 )  
    Stability of reversed austenite in the 9%Ni steel after heat treatment and cryogenic treatment was studied by means of SEM, TEM, XRD and microhardness tester. The results show that the transformation of unstable reversed austenite is basically completed when the cryogenic temperature is -120 ℃, and the content of reversed austenite changes a little tempered at 520 ℃ after the cryogenic treatment. It is extremely necessary to carry out the cryogenic treatment for the 9%Ni steel.
    NUMERICAL SIMULATION
    Numerical simulation of effect of hot-pressing process on growth of interfacial reaction layer in SiCf/Ti composites
    Tang Hongwu, Zhang Xiaomin, Zhao Zhipeng, Zhang Hengjia
    2023, 48(2):  232-241.  doi:10.13251/j.issn.0254-6051.2023.02.037
    Abstract ( 16 )   PDF (542KB) ( 24 )  
    A phase field model based on strongly coupled thermo-mechano-diffusion-reactional theory was proposed to study the effect of hot-pressing sintering fabrication process on growth law of intermetallic compounds in the continuous silicon carbide fiber reinforced titanium matrix composites. The simulation results show that the thickness of each interface reaction layer is consistent with the experiment at two different temperatures. Further research shows that the applied load can promote the growth of interface reaction layer, but the growth of Ti5Si3 layer is significantly inhibited, which has the lowest tensile strength. With the increase of applied load, the circumferential stress changes from tension to compression. The thickness of Ti3SiC2 layer increases with temperature rising, which has the maximum fracture toughness, as well as the thickness of the total interface reaction layer and Ti5Si3 layer are also increased. Therefore, it is an important way to improve the mechanical properties of SiCf/Ti composites by properly increasing the pressure and selecting the appropriate temperature in the preparation process to obtain the interface reaction layer with the appropriate thickness, meanwhile, making the Ti5Si3 layer thinner and the Ti3SiC2 layer thicker as far as possible.
    Numerical simulation and experimental verification of induction quenching for output flange of 42CrMo steel
    Wang Wei, Zhang Wen, Zhao Jiansen, Zhu Baizhi, Mi Yanjun, Jiang Hongbing, Hu Chengfei
    2023, 48(2):  242-246.  doi:10.13251/j.issn.0254-6051.2023.02.038
    Abstract ( 22 )   PDF (534KB) ( 31 )  
    Based on the electromagnetic-thermal-microstructure-stress coupling model, the temperature, microstructure and stress variation laws of the 42CrMo steel output flange during induction quenching process were studied, and the reliability of the numerical simulation was experimentally verified by hardening profile comparison and hardness testing. The results show that in the heating stage, the upper and lower sharp corners of the arc transition zone reach the austenitizing temperature earlier than that of the middle position. The heating effect gradually decreases after the temperature of the induction zone reaches the Curie point of the material. The microstructure of flange surface changes from original microstructure to austenite with the increase of temperature. The surface stress of flange is compressive stress in the heating stage, which increases rapidly at the beginning of heating, and then decreases gradually with the increase of internal temperature. In the quenching stage, the temperature drops rapidly, and the surface austenite quickly transforms into martensite. The stress at the surface passes through a short period of tensile stress, and then transforms into compressive stress (axial, radial and tangential stresses are all compressive stresses), among which the radial compressive stress is the largest, about 460 MPa.
    SURFACE ENGINEERING
    Static oxidation behavior at high temperature of laser-assisted thermal sprayed NiCoCrAlYTa-Cr2O3-Cu-Mo coating
    Nie Zixing, Wang Changliang, Zhang Ang, Zhang Mei, Guo Mengqiu, Tian Haoliang, Cui Yongjing, Wang Tianying
    2023, 48(2):  247-255.  doi:10.13251/j.issn.0254-6051.2023.02.039
    Abstract ( 16 )   PDF (536KB) ( 23 )  
    NiCoCrAlYTa-Cr2O3-Cu-Mo high temperature lubrication wear-resistant coating was prepared on the GH4065A nickel-based superalloy by laser-assisted plasma spraying (LPHS) technology, and then the high temperature oxidation resistance of the coating at 850-1000 ℃ for 220 h was investigated. The calculated oxidation activation energy is about 128.5 kJ·mol-1, and the oxidation rate constants at 850, 900 and 1000 ℃ are 1.44×10-2, 3.61×10-2, 7.71×10-2 mg2·cm-4·h-1, respectively. The experimental results show that after oxidation at 850 ℃ for 220 h, a continuous and dense oxide film dominated by Al2O3 is formed on the surface, which can prevent the further oxidation inside the coating. After oxidation at 1000 ℃ for 220 h, an oxide film consisting mainly of loose NiO and supplemented by dense Cr2O3·NiO is formed on the surface. The formation of dense oxide film prevents further oxidation of both the coating and the GH4065A superalloy substrate.
    Microstructure and tribological properties of WC-20Cr3C2-7Ni/8YSZ composite coatings by plasma spraying
    Zhu Donglin, Sun Dengyue, Yang Jiahui, Yan Chaopeng, Wu Yanfei, Qing Xiaokang
    2023, 48(2):  256-262.  doi:10.13251/j.issn.0254-6051.2023.02.040
    Abstract ( 18 )   PDF (543KB) ( 23 )  
    In order to improve the service life of the pulling and straightening roller of the continuous caster, WC-20Cr3C2-7Ni+8YSZ composite coatings with different mass ratios were prepared on the surface of H13 steel by plasma spraying technology, and the microstructure, microhardness, scratch resistance, wear resistance and wear form of each coating were analyzed. The results show that the compactness of the composite coating is significantly increased by adding 30wt% or 50wt% 8YSZ into the WC-20Cr3C2-7Ni powder, and the coating grains are obviously refined. WC1-x and W phases appear in WC-20Cr3C2-7Ni coating, and the crystallization strength of WC phase weakens with the addition of 8YSZ. The average hardness of WC-20Cr3C2-7Ni+30wt%8YSZ coating (1172 HV0.2) is not significantly changed relative to that of WC-20Cr3C2-7Ni coating (1152 HV0.2), but the hardness of WC-20Cr3C2-7Ni+50wt%8YSZ coating (1052 HV0.2) is decreased by 8.7% compared to that of WC-20Cr3C2-7Ni coating. The scratch resistance performance of WC-20Cr3C2-7Ni coating is weaker than that of the two composite coatings. The surface morphology of friction and wear changes from a large number of shedding pits to furrows, and the wear form also changes from fatigue wear to abrasive wear. The wear rate of WC-20Cr3C2-7Ni+30wt%8YSZ coating is 2.3×10-5mm3/(N·m), which is about 50% less than WC-20Cr3C2-7Ni and WC-20Cr3C2-7Ni+50wt%8YSZ coatings. The composite coatings are prepared on the surface of the straightening roll of the continuous casting machine and applied in production practice. The test data show that the surface temperature of WC-20Cr3C2-7Ni and the addition of 30wt% and 50wt%8YSZ coatings are reduced by 40.4 ℃, 97.2 ℃ and 127 ℃, respectively. Their working life are increased by 73.3%, 133.3% and 100%, respectively, compared with conventional pull rollers.
    Preparation and antibacterial property of Cu containing functional gradient coating on stainless steel
    Zheng Jiasheng, Huang Tianyang, Tian Linhai, Lin Naiming, Wang Zhenxia, Qin Lin
    2023, 48(2):  263-269.  doi:10.13251/j.issn.0254-6051.2023.02.041
    Abstract ( 17 )   PDF (538KB) ( 34 )  
    In order to improve the wear resistance and antibacterial property of stainless steel, a functional gradient composite modified layer was prepared on AISI316 stainless steel by a modified active screen plasma nitriding (ASPN) technology that the pure copper punching plate was placed on the stainless steel punching plate as top cover of the active screen. The surface nitriding treatment of the AISI316 stainless steel was carried out at low temperature (430 ℃), and at the same time, a functional gradient composite modified coating consisting of Cu containing antibacterial deposition layer and S phase(supersaturated solid solution of nitrogen in austenite γN) hard support layer was formed on the surface. The microstructure, composition and phase structure of the composite modified coating were characterized by means of SEM, EDS, XRD. The microhardness and friction and wear properties of the substrate and composite modified layer were tested by microhardness tester and reciprocating friction and wear tester, and the antibacterial property was evacuated by antibacterial experiment in vitro using Staphylococcus aureus. The results show that when the bias voltage reaches 250 V, a composite modified coating composed of continuously distributed S phase diffusion layer and Cu containing deposition layer is formed. The maximum hardness of the modified coating reaches 928 HV0.05. When ground with Si3N4 small ball, the specific wear rate is about 57.76% lower than that of the substrate, which significantly improves the wear resistance of the stainless steel. The antibacterial test shows that the bactericidal rate of the composite modified coating reaches 98.5% after contacting with Staphylococcus aureus for 24 h. The functional gradient composite modified coating prepared by the improved active screen plasma nitriding technology can effectively improve the wear resistance and antibacterial property of the stainless steel.
    Effect of Cu addition on microstructure of hot dipping aluminized layer on X80 steel
    Wang Qianwen, Peng Haoping, Shen Shengzhe, Li Zhiwei, Zhao Yonggang, Lei Yun, Tu Hao, Wu Changjun
    2023, 48(2):  270-275.  doi:10.13251/j.issn.0254-6051.2023.02.042
    Abstract ( 16 )   PDF (536KB) ( 23 )  
    Microstructure of hot dipping aluminized layer on X80 steel was improved by adding Cu element to the hot dipping aluminizing bath. Diffusion annealing experiments were carried out at different temperatures to investigate the affecting mechanisms of annealing temperature and copper element on microstructure of the aluminized layer by means of scanning electron microscope and X-ray diffractometer. Smile View software was used to measure the thickness of aluminized layer. The results show that during hot dipping aluminizing, the addition of Cu reduces the tongue-and-groove morphology between the alloy layer/X80 steel substrate interface to make the interfacial reaction more uniform. The thickness of the brittle Fe2Al5 alloy layer is minimum when the Cu content is 1% (mass fraction). With the increase of diffusion annealing temperature, the interface uniformity of the specimen with 1%Cu addition increases. When the diffusion annealing temperature is ≥600 ℃, a very thin FeAl phase layer begins to appear in the diffusion layer. When the diffusion annealing temperature is ≥650 ℃, the free layer disappears, the uniform FeAl layer appears in the diffusion layer and the holes appear outside the diffusion layer. When the diffusion annealing temperature is 700 ℃, the middle of the FeAl layer has a hole zone, and the outside of the diffusion layer has large holes. The addition of 1%Cu to the hot dipping aluminizing bath reduces the difference of migration velocities between Al and Fe atoms during diffusion annealing, thereby reducing the concentration gradient between Al and Fe atoms, which results in a more homogeneous interfacial reaction, thus avoiding the appearance of holes in the infiltrated layer.
    Effect of heat treatment on microstructure and properties of stainless steel coating by high-speed laser cladding
    Weng Yiqing, Xue Ruilei, Man Jiao, Gao Feng, Zhou Jianping, Chen Yanhua, Han Yonghong
    2023, 48(2):  276-283.  doi:10.13251/j.issn.0254-6051.2023.02.043
    Abstract ( 15 )   PDF (537KB) ( 22 )  
    Stainless steel coating was prepared on the surface of 27SiMn steel by high-speed laser cladding technology, and the coating was subsequently heat treated. The morphology and microstructure of the coating before and after heat treatment were characterized, and the microhardness, frictional wear properties, impact property and corrosion resistance of the specimens were tested and analyzed. The results show that the coating are mainly composed of α-(Fe,Cr), carbides such as M7C3, M23C6, and Cr3Si reinforced phases. For the coating after heat treatment, the grains of the coating are significantly refined and distributed more uniformly; the hardness is not significantly higher than that without heat treatment, but the hardness distribution is smoother, and the average hardness reaches 446 HV0.2; the wear rate decreases by 1.7×10-5 mm3·(N·m)-1, the impact property increases by 28.6%, and the self corrosion current density is only 9.19% of that before heat treatment.
    Effect of alternating current field on powder oxidizing of commercially pure titanium TA2
    Wang Xinyu, Xie Fei, Pan Jianwei
    2023, 48(2):  284-288.  doi:10.13251/j.issn.0254-6051.2023.02.044
    Abstract ( 14 )   PDF (472KB) ( 20 )  
    Alternating current field (ACF) enhanced powder oxidizing was carried out on commercially pure titanium TA2 at 650 ℃ by applying ACF to pack agents and specimen with a pair of electrodes paralleling with each other set in a process container. The results show that the surface layer, produced by the oxidizing with carbamide as oxygen supplier in the pack agent, consists of mainly TiO2 with few Ti2N and α-Ti with dissolved oxygen. ACF can greatly enhance the oxidizing of TA2. The oxidized layer thickness and hardness increase with the increase of ACF current, which modifies the hardness distribution along the layer depth. After oxidizing for 6 h with pack agent containing 2% carbamide and the ACF with a current of 2 A, an oxidized layer is obtained with thickness of 46 μm and peak hardness of 1150 HV0.01. It is proposed that the ACF's physical effect of enhancing chemical reactions in the agent increases the productivity and activity of oxygen atoms or active oxygen-containing species. By increasing the vacancy concentration in the specimen, the ACF provides more channels for the diffusion of oxygen atoms. These two factors accelerate the diffusion of oxygen atoms into the specimen. This new oxidizing technology can carry out high-efficient oxygen infiltration treatment on titanium at a lower temperature and reduce workpiece distortion.
    Microstructure and properties of laser clad Stellite12 alloy layer on S31000 stainless steel
    Chen Lin, Jiang Yongbing, Shang Hongbao, Li Li, Zhang Pengqi, Jing Renrong
    2023, 48(2):  289-294.  doi:10.13251/j.issn.0254-6051.2023.02.045
    Abstract ( 26 )   PDF (473KB) ( 32 )  
    Aiming at the problems that high-temperature valve sealing pair was easier to be scratched and bruised, Stellite12 alloy layer was prepared on the surface of S31000 stainless steel sealing pair by laser cladding technology. The microstructure, microhardness and uniform corrosion property of the clad layer were studied by optical microscope (OM), scanning electron microscope (SEM), X-ray diffraction, microhardness tester and uniform corrosion full immersion test. The results show that the clad layer forms a good metallurgical bond with the substrate, and the microstructure is mainly composed of dendrite structures of planar crystal, columnar crystal and equiaxed crystal. The microhardness of the clad layer is relatively high, with the average microhardness of 600.68 HV0.3, while the microhardness of the substrate is the lowest, with the average microhardness of 204.57 HV0.3. Compared with that of the S31000 stainless steel substrate, the corrosion rate is significantly reduced after laser cladding the Stellite12 alloy on it. At the same time, the S31000 stainless steel shows the phenomenon of corrosion pits with uneven size, while the Stellite12 alloy layer shows a relatively uniform corrosion behavior, though the corrosion phenomenon on the grain boundary is more obvious than that in the interdendrites.
    TEST AND ANALYSIS
    Effect of hole defect on fracture behavior of γ-TiAl alloy
    Liang Yuehui, Qi Wenjun
    2023, 48(2):  295-302.  doi:10.13251/j.issn.0254-6051.2023.02.046
    Abstract ( 19 )   PDF (476KB) ( 25 )  
    Molecular dynamics simulation was used to investigate the effect of hole defects on crack propagation of polycrystalline γ-TiAl alloy at different temperatures, hole locations and hole sizes. The results show that the polycrystalline γ-TiAl alloy with hole defect is of brittle cleavage fracture at 1-750 K, but of ductile creep fracture at 1000 K and 1200 K. The alloy is more likely to fail when the hole is located on the grain boundary and triple junction. Compared with the perfect crystal, the micropores increase the ductility of the polycrystalline γ-TiAl alloy. When the hole radius is larger than 1.0 nm, the yield stress and yield strain of the alloy decrease sharply, and the time of the alloy failure is advanced. The fracture mode is influenced by the hole size. Intergranular fracture occurs when the hole radius is less than or equal to 0.8 nm. When the hole radius is larger than 0.8 nm, the hole in the polycrystalline γ-TiAl alloy gradually expands and occupies the whole grain, and then transgranular fracture occurs.
    Cause analysis of crack formation of 38CrMoAl round steel bar after quenching and tempering
    Tan Ruisong, Huang Yan, Song Bo, Zuo Xiaotan, Zhu Libin, Liu Wei, Yang Shufeng
    2023, 48(2):  303-307.  doi:10.13251/j.issn.0254-6051.2023.02.047
    Abstract ( 21 )   PDF (472KB) ( 48 )  
    Cracks occurred after quenching and tempering in 38CrMoAl steel bar produced in a domestic steel mill, the crack was sampled, and the cause of cracks was investigated by means of chemical composition, macroscopic detection, microstructure analysis, scanning electron microscopy analysis, etc. The results show that the cracks are induced during quenching. The main reason for this is the presence of metallurgical defects including shrinkage, spot segregation, etc. in the original material round billet, while the effect of structural stress and thermal stress during the quenching and tempering promotes the propagation of the crack.
    Failure analysis of fatigue fracture of engine cylinder head bolts
    Chen Jilin, Zhang Yuming, Meng Yi, Yan Cong, Lin Peng
    2023, 48(2):  308-313.  doi:10.13251/j.issn.0254-6051.2023.02.048
    Abstract ( 31 )   PDF (471KB) ( 44 )  
    Failure analysis of fatigue fracture of SCM435 steel engine cylinder head bolts was carried out by means of fracture (macroscopic) analysis, microstructure analysis, chemical composition detection and hardness test. The results show that the chemical composition and microstructure of the failed SCM435 steel cylinder head bolts are qualified, and the hardness meets the technical requirement. The brittle fracture of the failed specimen 1 is caused by surface decarburization, the width of surface decarburization layer at the fractured part of the bolt is 120 μm. The fracture of the failed specimen 2 is mainly fatigue fracture caused by nonmetallic inclusions, and the near spherical CaS-CaO-Al2O3-MgO composite metallurgical inclusions cause intergranular crack. Suggestions for improving the indicators such as plasticity and toughness, surface decarburization and nonmetallic inclusions of the material are put forward.