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  • MATERIALS RESEARCH
    Effect of thermal deformation on bainite transformation of plastic mould steel SDFT600
    Zhang Zheng, Chen Jinlei, Zhang Min, Qiao Junwei
    2022, 47(8):  1-6.  doi:10.13251/j.issn.0254-6051.2022.08.001
    Abstract ( 120 )   PDF (608KB) ( 78 )  
    Effect of thermal deformation on bainite transformation of plastic mould steel SDFT600 during continuous cooling was analyzed by means of thermal simulation machine, thermal dilatometer, scanning electron microscope, etc. The results show that with the parameters suitable for forging production of large plastic mould steel blocks, thermal deformation promotes bainite transformation. At same continuous cooling rate, the bainite transformation start temperature of dynamic CCT specimen is higher than that of static CCT specimen, at cooling rate of 0.5 ℃/s, the temperature difference reaches 96 ℃. Thermal deformation reduces the stability of retained austenite, and at cooling rate of 0.5 ℃/s, the bainite content of dynamic CCT specimen is higher than that of static CCT specimen. When the continuous cooling rate is less than 0.1 ℃/s, the content of retained austenite of dynamic CCT specimen is lower than that of static CCT specimen. Hardness uniformity under thermal deformation condition is better, which is beneficial to the final quality of mould blocks.
    Effect of austenitizing process on microstructure of Cr14Mo4V high temperature bearing steel
    Zhou Lina, Liu Ming, Gao Xiang, Wang Wenxue, Tong Rui
    2022, 47(8):  7-15.  doi:10.13251/j.issn.0254-6051.2022.08.002
    Abstract ( 77 )   PDF (529KB) ( 52 )  
    Evolution of microstructure with austenitizing parameters of the high temperature bearing steel Cr14Mo4V was studied. The carbides, retained austenite, grain size and hardness of the Cr14Mo4V steel were analyzed by means of OM, XRD, SEM and hardness test. The results show that the microstructure of the quenched high temperature Cr14Mo4V bearing steel mainly includes quenched martensite, retained austenite and band-shaped carbides. The microstructure evolution process is more sensitive to the austenitizing temperature. The content of retained austenite gradually increases with the increase of austenitizing temperature, and the same trend to grain size, the carbides gradually dissolve, and the distribution of alloying elements of band-shaped carbides changes. The hardness of the Cr14Mo4V bearing steel increases slightly at first and then decreases significantly with the increase of austenitizing temperature, which is mainly affected by matrix solid solubility, retained austenite content and grain size.
    High temperature tensile flow constitutive equation of Mg-4Zn-2Y alloy
    Zhai Chuantian, Sun Youping, Li Wangzhen, He Jiangmei, Yang Chunyang
    2022, 47(8):  16-23.  doi:10.13251/j.issn.0254-6051.2022.08.003
    Abstract ( 59 )   PDF (533KB) ( 26 )  
    By conducting high temperature tensile experiments on as-rolled Mg-4Zn-2Y alloy at different thermal deformation temperatures and strain rates, the flow stress changes of the Mg-4Zn-2Y alloy during thermal deformation under different process parameters were studied. And a processing map was drawn. The results show that the flow stress is related to the deformation temperature and strain rate. When the thermal deformation temperature is constant, the maximum flow stress of the alloy increases with the increase of strain rate. When the strain rate is constant, the maximum flow stress decreases as the deformation temperature increases. The deformation activation energy and stress index for the as-rolled Mg-4Zn-2Y alloy determined by using the hyperbolic sine modified constitutive model are Q=242 233.2 J·mol-1 and n=8.09, respectively. The suitable hot working zones of the Mg-4Zn-2Y alloy determined by the processing map are 472.15-545.00 K, 10-3-10-4 s-1 and 545.00-672.15 K, 10-4-10-1 s-1.
    Effect of magnetic field on tempered microstructure and mechanical properties of 25CrMo48V ultra-high strength steel
    Yang Xiaobin, Dong Ji, Tian Chunying, Ning Baoqun, Zhao Qian, Qiao Zhixia, Liu Yongchang
    2022, 47(8):  24-33.  doi:10.13251/j.issn.0254-6051.2022.08.004
    Abstract ( 64 )   PDF (527KB) ( 25 )  
    In order to study the influence of magnetic field heat treatment on microstructure control of ultra-high strength steel and the type, shape, size and evolution of carbides, the effect of magnetic field on structure evolution and mechanical properties of the 25CrMo48V microalloyed ultra-high strength steel contaming Nb,V,Ti was studied by means of OM, SEM, TEM, EBSD and mechanical property test. All the specimens were austenitized at 1000 ℃ for 0.5 h, quenched with water, and then tempered at 200-600 ℃ for 1 h under the action of 1 T magnetic field. The rescuts show that the application of magnetic field will inhibit the merging of martensite laths and promote the precipitation of M23C6 and M7C3 type carbides. When tempered at different temperatures under the action of 1 T magnetic field, the hardness of the specimens is higher than that of the conventional tempering without magnetic field, but the strength is lower.
    In situ observation of continuous cooling transformation of Mn-Cr-Mo bainite rail steel
    Zhang Di, Bao Xirong, Chen Lin, Wang Xiaodong, Zhao Wenqian, Song Ran
    2022, 47(8):  34-39.  doi:10.13251/j.issn.0254-6051.2022.08.005
    Abstract ( 58 )   PDF (530KB) ( 31 )  
    Effects of austenitizing temperature of 1250 ℃, 950 ℃ and cooling rate of 0.8 ℃/s, 1.5 ℃/s on continuous cooling transformation of Mn-Cr-Mo bainite rail steel were studied by in-situ observation. The results show that the bainite plates nucleate and grow up orderly on grain boundaries simultaneously or non-simultaneously, but disorderly non-simultaneously in grain. The nucleated bainite plates on grain boundaries and in the grains grow at approximately the same constant rate, and the plates with different orientation stop growing when colliding grain boundaries or the preformed bainite plates and form a "cross-like" bainite structure. The growth rate of the plates is mainly controlled by the driving force of phase transformation, and the size and strength of austenite are the main factors affecting the length of the final bainite plates. It is concluded that lowering the austenitizing temperature and accelerating the cooling rate of bainite transformation can speed up the growth of the plates, shorten the transformation time and reduce the amount of transformed bainite. As a result, a fine, uniform and stable bainite plate structure can be obtained. Further, the average growth rate of bainite plates in Mn-Cr-Mo bainite rail steel is calculated to be 4.053 μm/s, which supports the diffusion-controlled phase transformation mechanism.
    Carbide dissolution behavior in GCr15 bearing steel during spheroidization annealing under condition of electromagnetic energy
    Shen Lijuan, Xie Gangsheng, Ma Yonglin, Xing Shuqing
    2022, 47(8):  40-45.  doi:10.13251/j.issn.0254-6051.2022.08.006
    Abstract ( 61 )   PDF (538KB) ( 33 )  
    Retained carbide dissolution behavior of the GCr15 bearing steel during holding stage of two-phase zone spheroidization annealing was investigated under traditional heat filed treatment and controllable pulse electromagnetic energy treatment. The morphology of retained carbide under different heat treatments was observed by means of scanning electron microscope. The results show that pulse electromagnetic energy has a great effect on shortening holding time of two-phase zone spheroidization annealing and reduces the number of retained carbide per unit area from 2.6460 μm-2(traditional heat field spheroidization annealed for 60 min)to 0.7839 μm-2(electromagnetic energy spheroidization annealed for 60 min). The kinetic analysis indicates that the applied magnetic field makes the Gtot decrease, and the growth rate of austenite increase, improves the dissolution of carbides, and reduces the spheroidization annealing time.
    Effect of Nb on microstructure and hardness of high Ti weathering steel after continuous cooling
    He Bo, Peng Tianen, Hu Xuewen, Jiang Bo, Guo Rui, Shi Jian, Wang Fei, Wang Haibo
    2022, 47(8):  46-51.  doi:10.13251/j.issn.0254-6051.2022.08.007
    Abstract ( 62 )   PDF (528KB) ( 33 )  
    Effect of Nb on continuous cooling transformation behavior of the high Ti weathering steel was studied by Gleeble thermal simulation testing machine. Microstructure and hardness of the tested steel without Nb addition and that added 0.050% Nb after continuous cooling transformation were observed and analyzed by optical microscope (OM), transmission electron microscope (TEM) and hardness test. The results show that Nb can inhibit ferrite transformation and promote bainite transformation. When the cooling rate increases from 5 ℃/s to 10 ℃/s, the grain refinement effect of the two tested steels is the most significant, and the hardness of the steels without and with Nb addition increases by 22 HV0.2 and 25 HV0.2, respectively. When the cooling rate is 40 ℃/s, the precipitate in the steel without Nb is mainly 6-13 nm spherical Ti(C,N), while the precipitates in the 0.050% Nb-microalloyed steel are mainly 5-12 nm spherical (Ti,Nb) (C,N) and 10-15 nm square (Ti,Nb) (C,N). The amount of precipitates in 0.050% Nb-microalloyed steel is more, so the precipitation strengthening effect is more significant. The effect of Nb on grain refinement is not significant in the high Ti weathering steel. The hardness of 0.050%Nb-microalloyed steel is only slightly higher than that of the steel without Nb at the same cooling rate, the maximum difference is only 11 HV0.2.
    Effect of Nb and Mo on microstructure and phase transformation of steel for mining grinding balls
    Xu Feng, Chen Qian, Lin Zhimin, Cheng Hao, Guan Yijie, Lu Kaijian
    2022, 47(8):  52-57.  doi:10.13251/j.issn.0254-6051.2022.08.008
    Abstract ( 68 )   PDF (530KB) ( 34 )  
    Effect of Nb and Mo on microstructure and phase transformation of grinding ball steel with different alloy composition during heat treatment was studied by using high temperature confocal laser scanning microscope (HT-CLSM) and JMatPro simulation calculation. The results show that the average austenite grain size of the tested steel with 0.051%Nb is the smallest (38.8 μm), that without Nb or Mo addition is the largest (74.1 μm), and that with 0.079% Mo is the intermediate. With Nb element addition, the precipitates are mainly Nb(C, N) and MnS, and the amount of precipitates is the most, which significantly hinder the grain growth of high temperature austenite. While with Mo element addition, the precipitates are mainly MnS and AlN, and the amount of precipitates is the intermediate, which slightly hinder the grain growth of austenite. The addition of Nb and Mo is beneficial to expand the bainite transformation zone, increases the percentage of bainite transformation and increases the martensite transformation start temperature.
    Microstructure and mechanical properties of CrFeCoNiB0.05Tix high-entropy alloy
    Jiang Yue, Zhu Baixiang, Li Xiuming, Tan Yaping
    2022, 47(8):  58-62.  doi:10.13251/j.issn.0254-6051.2022.08.009
    Abstract ( 79 )   PDF (540KB) ( 30 )  
    In order to study the effect of Ti content on microstructure and mechanical properties of high-entropy alloys, the CrFeCoNiB0.05Tix(x=0.2,0.4,0.6,0.8,1.0) high-entropy alloy was prepared by mechanical alloying and spark-plasma sintering, then the microstructure was analyzed by X-ray diffraction, scanning electron microscope observation, energy spectrum analysis, and the properties were analyzed by Vickers hardness test and compressive strength test. The results show that the CrFeCoNiB0.05Tix(x=0.2,0.4,0.6,0.8,1.0) high-entropy alloy is composed of FCC, BCC and α phases. Moreover, when x is 1.0, the alloy changes from BCC structure to HCP structure, and a new Laves phase is precipitated, the alloy has the highest hardness of 416.54 HV0.2. When x is 0.8, the alloy reaches the maximum compressive strength of 586.3 MPa.
    Microstructure and properties of 304/Q235 clad plate joints with high-entropy filler metals
    Liu Dejia, Zha Xuean, Wang Weixiong, Tang Yanchuan, Zhao Longzhi, Xu Hongming
    2022, 47(8):  63-70.  doi:10.13251/j.issn.0254-6051.2022.08.010
    Abstract ( 83 )   PDF (531KB) ( 23 )  
    The 304/Q235 clad plate was welded by using laser deposition welding. The microstructure, phase structure, mechanical properties and electrochemical corrosion resistance of the welded joints by using high-entropy filler metal of CrNi2MnTi0.5Al0.5 and Fe-based filler metal, respectively, were compared and analyzed by means of optical microscope, scanning electron microscope, X-ray diffraction, material universal testing machine and electrochemical corrosion measurement system. The effect of filler metal on microstructure and properties of the stainless steel clad plate joints was explored. The results indicate that dual phase structure of FCC+Ti3Al particles is formed in the weld zone with the CrNi2MnTi0.5Al0.5 filer metals. Hardness value of the weld zone is only 69%-75% of that with the Fe-based filler metals. Two welded joints have good tensile strength, and both are fractured in the base metal. The weld zone with CrNi2MnTi0.5Al0.5 filler metal has the best corrosion resistance, and its corrosion rate is 41% of the 304 stainless steel.
    Precipitation law of carbide containing aluminum in Fe-Mn-Al-C lightweight steel
    Meng Jingzhu, Liu Rendong, Guo Jinyu, Xu Rongjie, Wang Keqiang, Pan Yong
    2022, 47(8):  71-76.  doi:10.13251/j.issn.0254-6051.2022.08.011
    Abstract ( 73 )   PDF (533KB) ( 22 )  
    Precipitation law of aluminous carbide containing aluminum-K phase in the Fe-18Mn-0.8C-0.3Si-xAl(x=3, 6, 9) lightweight steel and its effect on properties under different cooling rates and heating temperatures were investigated by means of OM, SEM, XRD, TEM, EPMA, tensile test and Vickers hardness test. The results show that the factors affecting the precipitation of K phase include Al content, cooling rate and heating temperature. In the case of furnace cooling, when the cooling rate is about 0.020 ℃/s, K phase in lightweight steel with Al content of more than 9% is capable of precipitating on the austenite boundary; K phase is capable of precipitating below 900 ℃, while the heating temperature is higher than 900 ℃, K phase no longer precipitates. The precipitated K phase will affect the mechanical properties of lightweight steel and sharply reduce the plasticity of the lightweight steel. Therefore, the thick K phase should be avoided from precipitation in steel during production, which can be avoided by using faster cooling rate and higher heating temperature(>900 ℃).
    Effect of Si content on microstructure and corrosion resistance of Fe-Cr-Si alloy
    Qin Tieyu, Song Chunyan, Ma Rucheng, Zhang Xuefeng, Hao Wei, Gui Yongliang
    2022, 47(8):  77-82.  doi:10.13251/j.issn.0254-6051.2022.08.012
    Abstract ( 51 )   PDF (533KB) ( 28 )  
    Four Fe-Cr-Si alloys with different Si contents (6wt%, 8wt%, 10wt% and 12wt%) was designed and prepared by arc furnace process, and the effect of Si content on microstructure and corrosion resistance of Fe-Cr-Si alloys was investigated. The results show that the Fe-Cr-Si alloys with different Si contents are composed of primary dendrite and interdendrite matrix, and formation of metal silicide Fe3Si in microstructure is promoted with the increase of Si content. The Fe-Cr-Si alloys show good corrosion resistance in 10% HCl. After soaking for 72 h, SiO2 formed on the surface of the alloy has passivation effect, and the increase of Si content can significantly improve the corrosion resistance of the alloy. When the Si content reaches 12%, the corrosion resistance is 26 times that of 2Cr13 stainless steel.
    Precipitation behavior of σ phase in FeCr16 corrosion resistant soft magnetic alloy
    Hu Gengfu, Tian Yuxin, Zhu Yincun, Lu Jiansheng, Wang Fuming
    2022, 47(8):  83-87.  doi:10.13251/j.issn.0254-6051.2022.08.013
    Abstract ( 44 )   PDF (532KB) ( 19 )  
    In order to study the precipitation behavior of σ phase in the corrosion resistant soft magnetic alloy FeCr16, the equilibrium phase transition diagram was calculated by Thermo-Calc. According to the results of thermodynamic calculation, the effect of aging treatment temperature and Cr content on precipitation behavior of σ phase in the corrosion resistant soft magnetic alloy FeCr16 was investigated by means of optical microscope (OM), scanning electron microscope (SEM) and energy dispersive spectroscopy (EDS), and the magnetic properties of the alloy were tested. The thermodynamic calculation results show that when the temperature is lower than 560 ℃, there is precipitation of σ phase in the alloy. The results of heat treatment experiments show that the size and precipitation amount of the σ phase have the maximu values at 500 ℃, and the magnetic induction intensity of the alloy has a minimum value at 500 ℃, so the large amount of precipitation of σ phase will reduce the magnetic properties of the alloy. The segregation of Cr will promote the precipitation of σ phase in the alloy. With the increase of Cr content, the precipitation temperature range, size and quantity of σ phase increase, and the precipitation position extends from the grain boundary to the grain.
    Mechanical properties and corrosion resistance of 7A41 aluminium alloy
    Chi Haitao, Liu Fubing, Hu Xiaoguang
    2022, 47(8):  88-94.  doi:10.13251/j.issn.0254-6051.2022.08.014
    Abstract ( 59 )   PDF (533KB) ( 50 )  
    Mechanical properties and corrosion resistance of the double-stage aged 7A41 aluminium alloy were tested by the test methods of tensile properties at room temperature, stress corrosion properties and salt spray corrosion properties, respectively. Microstructure of the alloy and the microscopic morphology of tensile fracture were characterized by metallographic microscope, scanning electron microscope(SEM) and transmission electron microscope(TEM). The results show that the tensile strength, yield strength and elongation of the alloy in T6 state are 505 MPa, 474 MPa and 16.3%, respectively. The stress corrosion resistance is excellent, the stress corrosion sensitivity coefficient is 3.98%, and the salt spray corrosion rate of the alloy is 0.0914 mm/y. TEM observation and analysis show that the nano-scale precipitates are uniformly dispersed in the double-stage aged 7A41 alloy grains, and a large number of discontinuous precipitates are distributed on the grain boundaries. The size of the precipitates is 20-50 nm. The discontinuous precipitates effectively hinder the path of intergranular corrosion of the alloy and the good microstructure characteristics ensure the comprehensive properties of the alloy.
    Steel selection design of axis parts based on Bergerhord curve
    Fan Wangzhan, Hai Xianü, Gui Weimin
    2022, 47(8):  95-97.  doi:10.13251/j.issn.0254-6051.2022.08.015
    Abstract ( 37 )   PDF (597KB) ( 22 )  
    Drawing method of Bergerhord curve under the actual cooling condition and the material selection method based on Bergerhord curve were studied. After quenching test, the Bergerhord curve under the actual cooling condition is obtained by combing the hardenability curve of the material, based on which the end quenching point at 3R/4 of the deputy box spindle with the same cooling rate is calculated as J25 mm. The actual production results show that the Bergerhord curve obtained by this method is reliable and scientific for material selection.
    PROCESS RESEARCH
    Effect of cooling method of heat treatment on microstructure and properties of TC10 titanium alloy
    Zhang Mingyu, Yun Xinbing, Fu Hongwang
    2022, 47(8):  98-104.  doi:10.13251/j.issn.0254-6051.2022.08.016
    Abstract ( 84 )   PDF (596KB) ( 33 )  
    TC10 titanium alloy bars heated at different temperatures were treated with three different cooling methods of water cooling, air cooling and furnace cooling, and the microstructure and mechanical properties of the alloy under different cooling methods were studied by means of metallographic microscope, scanning electron microscope, tensile properties and impact property tests. The results show that there are two forms of α phase in the original microstructure of TC10 titanium alloy forging rods, one is primary equiaxed α phase, and the other is secondary α phase. When the heating temperature is lower than the phase transformation point, the formed microstructure is mainly composed of dual-state structure and equiaxed structure. When the temperature is higher than the phase transformation point, the alloy microstructure is mainly composed of full-lamellar β-transformation structure and coarse-lamellar β-transformation structure. Under the three cooling methods, the strength of the alloy after water cooling is the highest, the alloy has the best plasticity after furnace cooling. The alloy has the highest impact property after furnace cooling, followed by air cooling and water cooling. When the heating temperature is in the two-phase zone, the tensile and impact fracture morphologies of the alloy under the three cooling methods include dimples and cleavage planes, with obvious fluctuation. When the heating temperature is in the single-phase zone, the tensile fracture morphology is intergranular, the tearing edge is obvious, and the impact fracture has the characteristics of intergranular fracture.
    Numerical analysis of continuous moving induction heating with dual-loop coil
    Chen Zhuohao, Xie Hui
    2022, 47(8):  105-111.  doi:10.13251/j.issn.0254-6051.2022.08.017
    Abstract ( 57 )   PDF (597KB) ( 26 )  
    Adopting the finite element numerical calculation method, a continuous moving induction heating model of electromagnetic field coupled with temperature field was established by taking the dual-loop coil with a magnetizer as the heat source. The temperature distributions of the shaping surface and cutting edge of die during the induction heating with a dual-loop coil were studied. The results show that stable die quenching temperature can be obtained by continuous moving induction heating with the dual-loop coil. When the shaping surface of the die is quenched, the heat in the skin depth mainly comes from the joule heat generated by the induction eddy current, and its temperature rising shows a double-peak curve with preheating, while the heat outside the skin depth mainly comes from the heat conduction in high temperature region, of which temperature rising curve shows a single-peak. When the cutting edge of the die is quenched, there is an obvious sharp angle effect, of which temperature rising curve shows a single-peak.
    Effect of tempering time on microstructure and properties of 1800 MPa hot stamping steel
    Song Ninghong, Lin Chao, Bi Wenzhen, Wang Wurong, Wei Xicheng
    2022, 47(8):  112-117.  doi:10.13251/j.issn.0254-6051.2022.08.018
    Abstract ( 109 )   PDF (592KB) ( 30 )  
    Effect of tempering time (10-30 min) at 200 ℃ on microstructure and mechanical properties of a 1800 MPa hot stamping steel after flat forming at 930 ℃ for 4 min was studied by scanning electron microscope, electron backscattering diffraction and tensile test at room temperature. The results show that with the extension of tempering time, the tensile strength of the tested steel changes a little, while the yield strength and elongation after fracture both increase first and then decrease. The martensite sub-grain size is the smallest when tempered for 20 min, while the low angle grain boundary is the most when tempered for 10 min. After tempering at 200 ℃ for 10 min, the comprehensive mechanical properties of the hot stamping steel are the best due to the release of residual stress, the decrease of martensite sub-grain size and the increase of low angle grain boundary, of which the tensile strength is 1844 MPa, the elongation increases from 8.27% of quenched tested steel to 11.78%, and the product of strength and elongation reaches more than 21 GPa·%. It is concluded that short-time tempering is beneficial to the improvement of comprehensive properties of the tested ultra-high strength steel and the reliable application of hot stamping parts.
    Effect of induction hardening on hardness and hardened layer depth of Cr12MoV steel roll
    Peng Longsheng, Lin Yinghua, Huang Wei, Chen Hao
    2022, 47(8):  118-122.  doi:10.13251/j.issn.0254-6051.2022.08.019
    Abstract ( 83 )   PDF (592KB) ( 29 )  
    In view of the problem of Cr12MoV steel roll cracking easily and hardened layer depth during induction hardening, the effects of preheating temperature, quenching heating temperature, induction coil moving speed and power frequency on hardness, cracking and hardened layer depth of the Cr12MoV steel roll were studied, and the method of Cr12MoV steel roll with high hardness without cracking and thick hardened layer was explored. The results show that when the quenched and tempered hardness of the Cr12MoV steel roll is lower than 32 HRC and the preheating temperature is higher than 450 ℃, quenching cracking can be avoided. With the increase of induction hardening temperature or the moving speed of the induction coil, the hardness of the hardened Cr12MoV steel roll increases first and then decreases, but the hardened layer depth is not significantly affected. However, with the decrease of induction power frequency, the hardened layer depth of hardened Cr12MoV steel roll increases obviously, but it has little effect on hardness of hardened Cr12MoV steel.
    Grain growth behavior and magnetic property evolution of non-oriented electrical steel during annealing
    Guo Wenyi, Jiao Haitao, Xie Xinxiang, Zhao Longzhi, Zhao Mingjuan, Hu Yong
    2022, 47(8):  123-128.  doi:10.13251/j.issn.0254-6051.2022.08.020
    Abstract ( 48 )   PDF (596KB) ( 27 )  
    Cold rolled Fe-3%Si non-oriented electrical steel sheet was annealed for different time. The grain growth behavior and magnetic properties evolution of the non-oriented electrical steel during annealing were investigated by optical microscope, EBSD and so on. The results indicate that the proportion of Goss and γ texture grains decreases with the increase of annealing time, while the proportion of {114}<841> and {001}<120> texture grains increases gradually. When the annealing time is lower than 20 s, the recrystallization texture is characterized by strong γ and Goss textures. When annealed for 60 s, the growth rate of {001}<120> texture grains increases sharply, and the average grain size reaches about 105 μm. When the annealing time is 240 s, the annealing texture is mainly strong {001}<120> and {114}<841> textures. The magnetic induction intensity along RD and TD rises rapidly during annealing for 30-60 s, and the value along RD reaches the maximum of 1.74 T at 60 s, and value along TD reaches the maximum of 1.67 T at 120 s. After that, the magnetic induction intensity decreases slightly with the increase of annealing time and stabilizes at about 1.72 T (RD) and 1.66 T (TD), respectively. The magnetic induction intensity along the 45° direction increases first and then decreases, reaching the maximum value of 1.67 T at 20 s. The iron loss along each direction decreases with the increase of annealing time, and the magnetic anisotropy also decreases gradually.
    Effect of annealing on microstructure and properties of cold-rolled Cu-Ag alloy
    Chen Jianlan, Zhao Modi, Han Fusheng
    2022, 47(8):  129-134.  doi:10.13251/j.issn.0254-6051.2022.08.021
    Abstract ( 45 )   PDF (595KB) ( 25 )  
    Effect of annealing on microstructure, mechanical properties and electrical properties of the Cu-24%Ag alloy was studied by means of scanning electron microscope, transmission electron microscope, tensile testing and thermoelectric performance analysis system. The conduction mechanism of the alloy was studied by constructing an electron interface scattering model. The results show that the microstructure of the Cu-24%Ag alloy is effectively controlled by annealing, and the comprehensive properties are improved. The tensile strength of the alloy decreases to 95% of that of the cold-rolled alloy and the conductivity increases by 4%IACS after annealing at 350 ℃ for 1 h. After annealing at 450 ℃ for 1 h, the tensile strength decreases significantly and is only about half of that of the cold-rolled alloy due to the dissolution of Ag fibers. In addition, the dissolution of Ag fibers reduces the scattering probability of electrons and improves the conductivity. Therefore, the Cu-24%Ag alloy annealed at 350 ℃ for 1 h has the best comprehensive properties, of which the tensile strength and conductivity are 622 MPa and 81%IACS, respectively.
    Influence of heat treatment process on microstructure and mechanical properties of corrosion resistant 60Si2Mn spring steel for high-speed railway
    Li Jinbo, Wu Hongyan, Gao Xiuhua, Chen Hongwei, Li Shaojie, Zhu Ziying, Du Linxiu
    2022, 47(8):  135-140.  doi:10.13251/j.issn.0254-6051.2022.08.022
    Abstract ( 73 )   PDF (592KB) ( 29 )  
    Corrosion resistant 60Si2Mn spring steel was designed by adding Cr, Ni, Cu elements on the basis of the conventional high-speed railway 60Si2Mn spring steel. The influence of heat treatment process on microstructure and mechanical properties of the corrosion resistant spring steel was studied, and its corrosion resistance was evaluated. The results show that the microstructure of corrosion resistant 60Si2Mn steel after quenching and tempering is tempered troostite. When heated at 870 ℃ for 45 min, oil quenched and tempered at 440 ℃ for 60 min, the comprehensive mechanical properties of the corrosion resistant spring steel are the best, with yield strength of 1606 MPa, tensile strength of 1716 MPa, elongation after fracture of 5.3% and Rockwell hardness of 50.2 HRC. The corrosion resistance of 60Si2Mn steel added with corrosion resistant elements is much higher than that of conventional 60Si2Mn steel.
    Effect of solution treatment temperature and time on corrosion resistance of high nitrogen stainless steel
    Zhang Cunshuai, Liu Jimeng, Li Hao, Zhao Dingguo, Wang Shuhuan, Ni Guolong
    2022, 47(8):  141-147.  doi:10.13251/j.issn.0254-6051.2022.08.023
    Abstract ( 149 )   PDF (593KB) ( 46 )  
    High nitrogen nickel-free austenitic stainless steel with 0.54%N was prepared by vacuum induction furnace+electroslag remelting furnace under 0.08 MPa. After hot rolling, the tested steel was solution treated at 800, 900, 1000, 1100 and 1200 ℃ for different time, respectively. The microstructure and corrosion resistance of the tested steel were studied with different solution treatment processes, in which the corrosion resistance was studied in 3.5% NaCl solution by potentiodynamic polarization curve, and the mass loss ratio and corrosion rate were calculated after soaking in 6% FeCl3 solution for 8 days. The results show that solution treatment has a great influence on microstructure and corrosion resistance of the high nitrogen stainless steel. The tested steel after solution treatment at 1000 ℃ and 1100 ℃ has a single austenite structure. The precipitation phase Cr2N exists in the microstructure of the tested steel without heat treatment and in that solution treated at 800 ℃ and 900 ℃. In the tested steel solution treated at 1200 ℃, the ferrite structure is precipitated from the austenite. The tested steel heated at 1100 ℃ for 1 h has the best corrosion resistance, and the corrosion rate is only 1.35×10-5 g·cm-2·h-1. While the corrosion resistance of the tested steel heated at 800 ℃ for 3 h is the worst, the corrosion rate is as high as 8.18×10-4 g·cm-2·h-1. The corrosion resistance of 316L stainless steel is somewhere in between, and the corrosion rate is 1.24×10-4 g·cm-2·h-1.
    Effect of heat treatment on microstructure and hardness of economic high carbon martensitic stainless steel J50Cr13
    Wei Haixia, Pan Jixiang, Ji Xianbin, Li Zhaoguo, Xu Bin
    2022, 47(8):  148-151.  doi:10.13251/j.issn.0254-6051.2022.08.024
    Abstract ( 42 )   PDF (594KB) ( 22 )  
    High carbon martensitic stainless steel J50Cr13 was treated with different quenching temperatures and cooling modes. Microstructure and hardness of the tested steel were analyzed by optical microscope observation (OM), X-ray diffraction (XRD) analgss and hardness test. The results show that, with the increase of quenching temperature, the martensite structure coarsens, the content of retained austenite increases, and the carbides gradually dissolve into the matrix. With the increase of quenching temperature in 990-1080 ℃, the hardness values of both the water-cooled and air-cooled tested steel specimens increase; while when the quenching temperature increases to 1110 ℃ from 1080 ℃, the hardness values decrease. When quenched at 990 ℃, the difference between the hardness values of water-cooled and air-cooled specimens is the largest and up to 3 HRC, and when the quenching temperature increases, the effect of cooling on the hardness of the tested steel becomes less. When the quenching temperature is 1110 ℃, the hardness values of the water-cooled and air-cooled specimens are almost the same. The optimal quenching temperature of the J50Cr13 high carbon martensitic stainless steel is 1080 ℃, and then water cooling.
    Effect of deep cryogenic treatment on microstructure and corrosion resistance of 440C martensitic stainless steel
    Li Huidong, Zhang Qinyi, Liu Wei, Sun Wei, Wu Dong
    2022, 47(8):  152-157.  doi:10.13251/j.issn.0254-6051.2022.08.025
    Abstract ( 75 )   PDF (592KB) ( 38 )  
    Effect of deep cryogenic treatment on microstructure and corrosion resistance of 440C martensitic stainless steel was investigated. The results show that the hardness of the 440C stainless steel can be increased by 2.3 HRC after liquid nitrogen cryogenic treatment, the retained austenite content is reduced by 11.7%, and there is no obvious pitting on the surface after 72 h neutral salt spray test. The retained austenite content of the 440C stainless steel increases significantly when the room temperature retention time is more than 2 h after quenching, and the hardness and corrosion resistance decrease. It is suggested that the retention time at room temperature after quenching is less than 2 h if the 440C steel is subjected to liquid nitrogen cryogenic treatment.
    Effect of cryogenic treatment on high temperature wear resistance of M2Al high speed steel
    Chen Zhi, Meng Yu, Lan Dongsheng, Yan Xianguo
    2022, 47(8):  158-162.  doi:10.13251/j.issn.0254-6051.2022.08.026
    Abstract ( 45 )   PDF (591KB) ( 16 )  
    Effect of cryogenic treatment temperature on high temperature wear resistance of the M2Al high speed steel was investigated. The results show that the microstructure of the M2Al high speed steel specimen after cryogenic treatment is changed, the retained austenite is transformed into martensite, the carbide is reduced in size and dispersed on the martensite matrix. With the decrease of cryogenic temperature, the size of carbides decreases and the distribution is uniform. The high temperature friction coefficient of the steel after cryogenic treatment is lower than that without cryogenic treatment. The high temperature friction coefficient of -160 ℃ cryogenic treatment specimen is lower than that without cryogenic treatment by 55.7%. The wear loss of the steel after cryogenic treatment is lower than that without cryogenic treatment, and the wear loss after -160 ℃ cryogenic treatment is the smallest. The wear morphology of the steel specimen without cryogenic treatment is rough, and serious adhesive wear occurs. The specimen cryogenic treated at -160 ℃ has shallow wear marks, and the wear form is mainly abrasive wear. The M2Al high speed steel has the best effect of improving the high temperature wear resistance when the cryogenic treatment temperature is -160 ℃.
    Effect of heat treatment on microstructure and mechanical properties of composite cast high chromium high carbon steel/carbon steel wear-resistant materials
    Gao Zhizhe, Chen Xiaoyan, Wang Yongjin, Su Shengrui, Chen Junhao, Li Jiakang, Chen Zhengjia
    2022, 47(8):  163-167.  doi:10.13251/j.issn.0254-6051.2022.08.027
    Abstract ( 85 )   PDF (651KB) ( 28 )  
    High chromium high carbon steel/carbon steel composite wear-resistant steel was prepared by using liquid-solid composite method, and the effect of different heat treatments on microstructure and properties of the composite wear-resistant steel treated by austempering and quenching-tempering was studied by means of scanning electron microscope, hardness tester and impact property test, respectively. The types and contents of the equilibrium phases in the tested steel were calculated by using JMatPro software. The results show that the microstructure of the as-cast high chromium high carbon steel/carbon steel composite wear-resistant layer is composed of network carbide and granular pearlite. The substrate layer is a widmanstatten structure formed by coarse austenite at a faster cooling rate. After austempering, the microstructure of the wear-resistant layer of the tested steel is network carbide+fine-grained carbide+austenite+ferrite, and the substrate layer consists of massive ferrite and pearlite. After quenching and tempering, the microstructure of the wear-resistant layer of the tested steel is network carbide+fine-grained carbide+martensite, and the substrate layer is martensite+upper bainite. The hardness of the wear-resistant layer after austempering is 493 HBW, the impact absorbed energy is 2.6 J, and the impact absorbed energy of the substrate layer is 79.2 J. After quenching and tempering, the hardness of the wear-resistant layer is 629 HBW, the impact absorbed energy is 1.6 J, and the impact absorbed energy of the substrate layer is 20.0 J. Considering that the composite wear-resistant steel needs to resist high impact load, the better heat treatment process is austempering: heating at 880 ℃ for 2 h then cooling to 320 ℃ and at which holding for 5.5 h.
    Microstructure and properties of vacuum chromized layer on PCrNi3Mo steel
    Feng Lingxiao, Jin Hao, Yang Li
    2022, 47(8):  168-172.  doi:10.13251/j.issn.0254-6051.2022.08.028
    Abstract ( 58 )   PDF (594KB) ( 23 )  
    Vacuum chromizing on the surface of PCrNi3Mo steel was performed. The microstructure and properties of the chromized layer were analyzed by means of X-ray diffraction(XRD), scanning electron microscope(SEM), optical microscope, microhardness test, dry sliding friction and electrochemical corrosion test. The results show that the surface of the PCrNi3Mo steel after vacuum chromizing forms a chemical compound coating of Cr23C6, Cr7C3 and (Cr, Fe)7C3, and the chromized layer is dense and well bonded with the substrate. The depth, surface microhardness, wear resistance and electrochemical corrosion resistance of the chromized layer increase with the increase of chromizing time. When chromized for 12 h, the PCrNi3Mo steel has the best comprehensive properties, of which the thickness of chromized layer is about 11 μm, the surface hardness is 1117.1 HV0.5, the friction coefficient is the lowest, the wear mass loss is 0.1225 mg and the self-corrosion current density is 2 orders of magnitude lower than that of the substrate.
    Rare earth induced ion nitriding process of Cr12 steel
    Yu Zetong, Wang Mingli, Niu Yi, Liu Guanjun
    2022, 47(8):  173-176.  doi:10.13251/j.issn.0254-6051.2022.08.029
    Abstract ( 73 )   PDF (592KB) ( 23 )  
    Rare earth induced ion nitriding test was carried out on Cr12 steel. The hardness and depth of the nitrided layer on the specimen surface were measured by microhardness tester, and the phases of the nitrided layer were analyzed by means of XRD. Finally, the friction and wear characteristics of the specimen surface were quantified by friction testing machine. The results indicate that rare earth can affect the effect of ion sputtering nitriding on the Cr12 steel, and the effect decreases sharply with the increase of the distance between them. When the distance is less than 25 mm, the surface hardness of the specimen is obviously lower than that of the ordinary ion nitriding, and the surface friction coefficient and wear rate are also slightly worse, but the thickness of nitriding layer is significantly increased. When the distance exceeds 25 mm, the induction effect of rare earth declines significantly, but the hardness and frictional coefficient of the specimen surface are basically the same as those of ordinary ion nitriding. Meanwhile, the wear rate is obviously increased. The analysis shows that rare earth elements can increase the adsorption capacity of nitrogen ions on the specimen surface and provide path advantages for their infiltration. When the distance between them is too large, rare earth ions are not easy to be adsorbed on the specimen surface, and the rare earth induction effect is disappeared. Meantime, it also causes lattice defects on the surface of the specimen, which reduces the wear resistance of the surface.
    Effect of intercritical continuous annealing temperature on microstructure and properties of Q&P980 steel
    Liu Lin, Xu Haiwei, Li Hongbin, Han Yun, Tian Yaqiang, Zheng Xiaoping, Chen Liansheng
    2022, 47(8):  177-181.  doi:10.13251/j.issn.0254-6051.2022.08.030
    Abstract ( 73 )   PDF (594KB) ( 19 )  
    Taking continuous annealing production of cold rolled Q&P steel as the technological background, the heat treatment process of soaking and heat preservation in two-phase zone+slow cooling+rapid cooling to partitioning between Ms and Mf points was adopted, and the effects of different soaking temperatures in the two-phase zone on microstructure and mechanical properties of low-carbon silicon manganese alloyed Q&P980 high-strength steel were studied. The results show that with the increase of soaking temperature in the two-phase region, the ferrite content decreases, the proportion of martensite and lath size increases, the content of retained austenite first increases to 7.2% and then decreases. With the further increase of soaking temperature, the tensile strength increases monotonically due to the increase of martensite content in the matrix, while the change trend of elongation is similar to that of retained austenite content. When the partitioning temperature is 310 ℃, the best soaking temperature range is 765.24-812.56 ℃. When soaking at 790 ℃, the tensile strength is 1052 MPa, the elongation is 22.9%, and the strength-elongation production is 24 090.8 MPa·%.
    Effect of heat treatment temperature on solidification microstructure and hardness of Al-Gd alloy
    Shi Xiangdong, Li Degui, Cao Alin, Gu Bin, Liang Liuqing
    2022, 47(8):  182-187.  doi:10.13251/j.issn.0254-6051.2022.08.031
    Abstract ( 50 )   PDF (594KB) ( 21 )  
    Al-52%Gd(mass fraction)alloy smelted by vacuum arc furnace was heat treated at different temperatures. The effect of heating temperature on solidification microstructure and hardness of the Al-52%Gd alloy was studied by means of optical microscope, scanning electron microscope, Rockwell hardness tester and so on. The results show that the primary crystal phase changes from coarse developed dendrites to more uniform equiaxed crystals when the heating temperature is 600 ℃. The morphology of eutectic phase transforms from lamellar network to short rod and dot, and the growth mode gradually changes from attaching the primary phase to independence. As the heating temperature increases, the hardness decreases first, then increases and then rapidly decreases. The central hardness value and average hardness value have difference at different heating temperatures, which is mainly determined by the porosity of solidification microstructure as well as the morphology and distribution of primary phase Al3Gd.
    Effect of heat treatment on microstructure and creep behavior of directionally solidified alloy DZ125
    Tian Ning, Zhao Guoqi, Zhang Ping, Xiang Xianli, Tian Sugui, Zhang Shunke, Yan Huajin
    2022, 47(8):  188-193.  doi:10.13251/j.issn.0254-6051.2022.08.032
    Abstract ( 68 )   PDF (595KB) ( 18 )  
    Through creep property test and microstructure observation, the effect of heat treatment on microstructure and creep behavior of directionally solidified alloy DZ125 was studied. The results show that there are many radial eutectic structures in the interdendritic region of the as-cast alloy, and part of the γ′ phases between dendrites and dendrite stems are butterfly shaped, and the sizes of γ′ phase are quite different. The eutectic structures and γ′ phases of the as-cast alloy are dissolved during the solid solution process, and the fine rhombohedral γ′ phase precipitated from the matrix during the subsequent cooling process. During the first aging period, the small γ′ phases similar to rhombus are blunted and grown until it transformed into a cube shape. During the secondary aging, the size of the γ′ phase is basically unchanged, but the cubic degree increases, and the microstructure of the alloy is that the γ′ phase precipitated from the matrix in a coherent manner. During the heat treatment process, the eutectic structures in the alloy are basically eliminated and the cubic degree of the phase is improved, but the structure inhomogeneity in the alloy is not eliminated. The cubic γ′ phase in the dendrite stem region is small in size, while the cubic γ′ phase in the interdendritic region is coarse in size, and the alloy has good anti-creep properties at 980 ℃.
    Effect of recovery heat treatment on microstructure and properties of K403 nickel-based superalloy
    Wu Yeqiong, Lei Yong, Si Yan, Qin Jiang, Wang Yi, Cheng Xiaohong, Chen Xinyue, Yang Hao
    2022, 47(8):  194-199.  doi:10.13251/j.issn.0254-6051.2022.08.033
    Abstract ( 39 )   PDF (631KB) ( 18 )  
    Nickel-based superalloy K403, a typical material for turbine blades, was stress aged to simulate blades used for a period of time, and then the previous stress aged specimens were subjected to recovery heat treatment. Microstructure and properties of the original specimen, the previous stress aged specimen and the recovery heat treated specimen were analyzed and tested by means of scanning electron microscope and mechanical testing machine, respectively. The results show that after recovery heat treatment, the strengthening phase γ′ in the microstructure is obviously refined in the K403 alloy test bar previous stress aged for different time, the morphology is close to cubic, and the high temperature tensile strength and rupture life of the recovered specimens are better than those of the untreated test bar. The longer the previous stress aging time, the higher the increase rate of high temperature rupture life of the alloy test bar after recovery heat treatment.
    Effect of heat treatment on inclusions and microstructure of U76CrRE rare earth heavy rail steel
    Li Xiangchuan, Yang Jichun, Bai Guojun, Fan Zhiming
    2022, 47(8):  200-210.  doi:10.13251/j.issn.0254-6051.2022.08.034
    Abstract ( 43 )   PDF (626KB) ( 18 )  
    U76CrRE billets were heat treated at 1100 ℃, 1200 ℃ and 1300 ℃ for 1 h, 2 h and 3 h, respectively. The inclusions were observed by FEI-QUANTA400 scanning electron microscope, the microstructure and hardness were observed and tested by means of Axiovert Zeiss optical microscope and Qness-Q10A+automatic microhardness tester. The results show that the heat treatment has obvious effect on the inclusions in the U76CrRE rare earth heavy rail steel, and the shape and size of inclusions are significantly improved. With the increase of heating temperature, the morphology and size of MnS and compound inclusions can be further optimized. When heated at 1100 ℃, the size of MnS and compound inclusions decreases with the increase of holding time, and the shape is obviously improved. When heated at 1200 ℃, the size of MnS decreases and the size of compound inclusions increases with the increase of holding time. The grain size of the U76CrRE rare earth heavy rail steel increases obviously with the increase of heating temperature, and the hardness shows a trend of first decreasing and then increasing, while decreases gradually with the extension of holding time. When heated at 1100 ℃, the microstructure of the tested steel is martensite, bainite and retained austenite, and the grain boundary is not obvious. After holding at 1200 ℃ and 1300 ℃ for more than 1 h, the network cementite in the tested steel is obvious. When heat treated at 1300 ℃ for 1 h, the carbon deposition at the grain boundary is serious and the carbides are not effectively dissolved. When held at 1200 ℃ for 1 h, the grains of the tested steel are uniform, the grain boundaries are obvious, the microstructure is mainly retained austenite and pearlite, and the microstructure is uniform.
    Effect of quenching temperature on microstructure and properties of 5Cr15MoV steel by air-cooling quenching
    Tian Chunying, Dong Ji, Wang Jun, Zhang Huixing, Feng Tianjian, Liu Xiaofan
    2022, 47(8):  211-216.  doi:10.13251/j.issn.0254-6051.2022.08.035
    Abstract ( 89 )   PDF (625KB) ( 17 )  
    Air cooling quenching experiment was performed on 5Cr15MoV martensitic stainless steel at a series of heating temperatures ranging from 1000 ℃ to 1200 ℃ at an interval of 50 ℃. The test of microstructure and hardness were performed by means of optical microscope, EBSD and Rockwell hardness tester after quenching at different temperatures. The effect of quenching temperature on microstructure, grain size, retained austenite content and hardness of the tested steel was studied. The results show that the quenched steel consists of martensite, undissolved carbide and retained austenite. With the increase of quenching temperature, the size of martensitic lath increases, the amount of undissolved carbide decreases gradually until it disappears, and the content of retained austenite increases first and then decreases. The hardness of the tested steel increases first and then decreases significantly, and reaches the maximum of 60.8 HRC at 1050 ℃. The hardness of the tested steel is mainly the result of comprehensive effect of carbon content of martensite, grain size, retained austenite content and carbide content.
    Effect of Cu content and T6 treatment on microstructure and properties of aluminum alloy used for electric power fittings
    Zheng Ge, Chen Jie, Niu Kunning, Lin Jianguo, Tan Chaogui, Dai Yilong
    2022, 47(8):  217-222.  doi:10.13251/j.issn.0254-6051.2022.08.036
    Abstract ( 50 )   PDF (626KB) ( 29 )  
    Effect of copper content and aging process on microstructure, mechanical properties and corrosion resistance of the Al-Cu-Mg-Si alloy was investigated. The results show that, with the increase of Cu content, both the quantity and size of Al2Cu phase in as-cast aluminum alloy increase, and the morphology changes from point to coarse network. The strength of the as-cast aluminum alloy also increases, but the corrosion resistance decreases. Within the aging range of 180 ℃×(4-28) h, the overall hardness of the alloy increases first and then decreases, with 0.5%Cu and 1.5%Cu alloys reaching the peak value under 8 h and 2.5%Cu alloy reaching the peak value under 12 h. The Al2Cu phase precipitates from the aluminum alloy after solution treatment at 530 ℃ and aging at 180 ℃ for 8 h, with the increase of Cu content, the content of Al2Cu phase increases, and the hardness shows a significant increase. After solution treatment at 530 ℃ and aging at 180 ℃ for 8 h, the tensile strength of the alloy with 2.5%Cu reaches the peak of 325.0 MPa, the yield strength reaches 258.8 MPa and the elongation is 4.5%, the strength is equivalent to that of traditional cast iron for electric power fittings.
    Annealing process of high-strength hot-dip galvanized structural steel SGC570
    Li Peng, Li Renjie, Yang Xiong, Huang Li
    2022, 47(8):  223-227.  doi:10.13251/j.issn.0254-6051.2022.08.037
    Abstract ( 63 )   PDF (629KB) ( 19 )  
    In accordance with the technical requirements of high-strength hot-dip galvanized structural steel SGC570, a process route of C-Mn chemical composition system, hot continuous rolling+cold rolling+continuous annealing hot-dip galvanizing was selected to study its continuous annealing process. Through thermal simulated annealing experiment, tensile test, hardness test, microstructure observation, it is found that the recrystallization temperature of high-strength hot-dip galvanized structural steel SGC570 product is 550 ℃. In order to improve the yield strength, incomplete annealing process is performed between 530-540 ℃. In the industrial small batch trial production stage, the continuous annealing process is studied by analyzing the relationship between annealing temperature and product microstructure and properties, and it is concluded that the best annealing temperature for industrial production is 530 ℃.
    Tempering for direct quenched 800 MPa grade hydropower steel
    Liu Xiaowei, Zhou Guangjie, Tan Xiaobin
    2022, 47(8):  228-231.  doi:10.13251/j.issn.0254-6051.2022.08.038
    Abstract ( 106 )   PDF (626KB) ( 18 )  
    Tempering treatments for a direct quenched 800 MPa grade hydropower steel were studied, and the effect of three different tempering temperature on microstructure and mechanical properties of the steel was analyzed. The results show that after controlled rolling and rapid water cooling quenching at 770-820 ℃, with the increase of tempering temperature in the range of 620-680 ℃, the yield strength and tensile strength decrease, while the elongation and impact absorbed energy of the steel increase. The best match of strength and impact properties is achieved when tempered at 650 ℃. In the tempering temperature range of 620-680 ℃, the microstructure of the steel is tempered bainite, and as the tempering temperature rising, the carbides gradually grow and are granular distributed, and bainite appears polygonal features.
    Influence of tempering temperature on microstructure and mechanical properties of forged 35CrMo steel with large-scale
    Liao Jia, Fu Tao, Wang Xiaowei, Yu Shengfeng, Wang Ruiqi, Peng Fei
    2022, 47(8):  232-236.  doi:10.13251/j.issn.0254-6051.2022.08.039
    Abstract ( 69 )   PDF (625KB) ( 21 )  
    Influence of tempering temperature on microstructural characteristics and mechanical properties of forged 35CrMo steel with large-scale was investigated after quenching and tempering, especially focusing on the dynamics of cementite precipitation during tempering process and the inhomogeneity of microstructure and mechanical properties. The results show that the banded microstructure of ferrite and pearlite in the forged steel can be completely eliminated after quenching and tempering, the microstructure is mainly composed of tempered martensite with abundant cementite, and some tempered bainite along prior austenite grain boundary is also observed. The kinetics of cementite precipitation can be divided into two stages comprising rapid growth stage controlled by C diffusion and steady size stage controlled by Cr diffusion. The anisotropy of mechanical properties still exists in the forged 35CrMo steel after quenching and tempering. With the increase of tempering temperature, the transverse and longitudinal strengths decrease, while the ductility and toughness are improved concurrently. It is concluded that the optimal combination of strength, ductility and toughness can be obtained when tempered at 570 ℃。
    Effect of solution and aging on microstructure and hardness of 316L stainless steel block formed by SLM
    Zhu Derong, Li Hao, Liu Yi, Wang Lige, Chen Zhiyong, Zhang Huixian, Liang Li
    2022, 47(8):  237-241.  doi:10.13251/j.issn.0254-6051.2022.08.040
    Abstract ( 50 )   PDF (626KB) ( 27 )  
    316L stainless steel block was successfully prepared by selective laser melting (SLM) technology. The effect of aging temperature(650 ℃ and 850 ℃) on microstructure and microhardness of 316L stainless steel block formed by SLM was studied by means of optical microscope (OM), scanning electron microscope (SEM) and Vickers hardness tester. The results show that the microstructure of 316L stainless steel block formed by SLM is mainly composed of fine columnar grains and honeycomb grains. The boundaries of “layer-layer” and “channel-channel” molten pools are clearly visible. After solution and aging, the boundaries of “layer-layer” and “channel-channel” molten pools disappear, but the grain boundaries are clearly visible and the recrystallized grain grows in a combined growth mode. A small amount of M23C6 are distributed at grain boundaries in specimen after aging at 650 ℃, and the microhardness is relatively high. With the increase of aging temperature, the grain of specimen after aging at 850 ℃ grows further, and a large amount of discontinuous M23C6 are formed along the grain boundaries.
    OVERVIEW
    Research progress on laser shock peened microstructure and thermal stability of additive manufactured titanium alloy
    Wang Jun, He Bo, Lei Yiyu, Jia Wenjing, Lan Liang, Gao Shuang
    2022, 47(8):  242-248.  doi:10.13251/j.issn.0254-6051.2022.08.041
    Abstract ( 72 )   PDF (627KB) ( 19 )  
    Firstly, the action mechanism of laser shock peening(LSP) is summarized. Then the research status of laser peening to improve the microstructure and properties of titanium alloys additive manufactured at home and abroad is reviewed. On this basis, it is discussed that the limitation of the application of LSP in additive manufacturing is largely due to the existence of a large number of non-equilibrium structures, which will turn to an equilibrium state to change the properties under thermodynamics. Furthermore, some attempts and problems in thermodynamics and kinetics to stabilize the nanocrystalline structure induced by LSP are summarized, and it is innovatively proposed that nitrides and solid solution atoms can be precipitated by nitriding with good diffusion properties of LSP to hinder the migration of grain boundaries. Finally, the future research direction in this field and the establishment of a database of additive manufacturing titanium alloy-LSP-thermal stability are proposed to promote the development of the field.
    Research progress of chemical heat treatment of titanium alloys
    Liu Gang, Liu Jing, Yang Feng, Xiang Qing
    2022, 47(8):  249-256.  doi:10.13251/j.issn.0254-6051.2022.08.042
    Abstract ( 85 )   PDF (627KB) ( 40 )  
    Due to the dense passivation film, high oxygen affinity and low atomic diffusion coefficient of titanium alloy, the surface strengthening is difficult to achieve. However, the carbonitride and solid solution phase of titanium have excellent properties. The surface structure of titanium alloy can be greatly changed by four chemical heat treatment technologies, such as nitriding, carburizing, boronizing, and diffusion metallizing, and the surface hardness and strength are improved. The common technical characteristics, microstructure, strengthening mechanism and mechanical behavior of the titanium alloy chemical heat treatment were summarized, and the development prospect of chemical heat treatment in the future was forecasted.
    SURFACE ENGINEERING
    Effect of micro-arc surface treatment on corrosion resistance and corrosion fatigue resistance of AZ31B magnesium alloy
    Shen Yi, Xue Yuna, Chen Han, Dai Rong, Wang Miao, Geng Yonghui, Zhang Xinyuan, Jiang Bailing
    2022, 47(8):  257-265.  doi:10.13251/j.issn.0254-6051.2022.08.043
    Abstract ( 49 )   PDF (626KB) ( 21 )  
    Protective coatings with different section structures were prepared on AZ31B magnesium alloy by using micro-arc surface treatment (micro-arc oxidation MAO and micro-arc composite MCC). The electrochemical corrosion and corrosion fatigue properties were studied by electrochemical corrosion and corrosion fatigue tests. The results show that the MAO coating treated for 10 min shows better corrosion resistance. It is observed that there are micro-pores and micro-cracks on the surface of MAO coating on the AZ31B alloy. These micro-pores and micro-cracks are deemed as crack initiation points of fatigue cracks and can accelerate the initiation and propagation of cracks under stress conditions, which lead to a reduction of 55% in the corrosion fatigue life compared with that of the AZ31B alloy substrate. The corrosion fatigue limit of AZ31B alloy with MCC coating is (64.0±5.4) MPa, which is 59% higher than that of the AZ31B alloy substrate. Under low stress condition (<80 MPa), the corrosion fatigue strength of the AZ31B alloy with MCC coating is significantly improved.
    Tribological properties of plasma-sprayed boron nitride nanoplatelet reinforced Ni3Al composite coating
    Lou Xuyao, Zhou Bo, Song Ying, Lu Xiaolong
    2022, 47(8):  266-270.  doi:10.13251/j.issn.0254-6051.2022.08.044
    Abstract ( 57 )   PDF (626KB) ( 22 )  
    Boron nitride nanoplatelet (BNNP) reinforced Ni3Al composite coatings were fabricated by using plasma spray. The results show that the main phases of the coating contain in-situ synthesized Ni3Al and trace amounts of Al2O3. Compared with monolithic Ni3Al coating, the BNNP/Ni3Al composite coating displays a good combination of improved wear resistance and relatively low coefficient of friction, especially the wear resistance of the composite is increased up to 1.5 times. The addition of BNNPs induces a change of the dominant wear mechanisms from brittle fracture and three-body abrasive wear associated with the monolithic Ni3Al coating to mild abrasive wear along with the BNNP/Ni3Al composite coating. Furthermore, the formation of BNNP tribolayer on the worn surface of the composite coating not only contributes to the self-lubrication function but also significantly suppresses contact damage of both the composite coating and its counterpart.
    Effect of scanning speed on mechanical properties and microstructure of ER630 wire repair layer by direct laser deposition
    Yang Laixia, Li Jiale, Xu Chao, Yang Wenxuan
    2022, 47(8):  271-278.  doi:10.13251/j.issn.0254-6051.2022.08.045
    Abstract ( 42 )   PDF (627KB) ( 31 )  
    Effect of scanning speed on mechanical properties and microstructure of ER630 repair layer was studied by direct laser deposition (DLD) on 45 steel substrate. The results show that with the increase of scanning speed, the slag inclusion in the ER630 repair layer gradually increases and the size gradually increases. The effect of scanning speed on the density of ER630 repair layer is negligible. At the scanning speed of 30 mm/s, the microstructure is mainly lath columnar martensite and a small amount of cellular austenite. With the increase of scanning speed, the lath columnar martensite decreases and the cellular austenite gradually increases. The mechanical properties of the laser deposition wire specimen at the scanning speed of 30 mm/s are equivalent to those of the 630 stainless steel aged at 550 ℃. With the increase of scanning speed, the yield strength and hardness show a downward trend. The maximum yield strength is 961.07 MPa at 30 mm/s, and the maximum hardness is 428.88 HV at 40 mm/s. The tensile fracture morphology is dimple fracture or quasi-cleavage fracture, indicating that the DLD process can achieve excellent metallurgical bonding. Compared with the strength change at scanning speed of 30 mm/s, when the deposition efficiency is increased to 2 times, good repair strength can still be obtained.
    Effect of pulsed bias duty ratio on structure and properties of TiSiN film
    Wei Yongqiang, Gu Yanyang, Zhao Zhongqing, Jiang Zhiqiang
    2022, 47(8):  279-286.  doi:10.13251/j.issn.0254-6051.2022.08.046
    Abstract ( 62 )   PDF (630KB) ( 23 )  
    Arc ion plating method was used to deposit TiSiN films on M2 high-speed steel(M2 HSS) and Si wafer substrates by changing the pulsed bias duty ratio. Effect of pulsed bias duty ratio on morphology, element composition, phase structure, nano-hardness and corrosion resistance of the TiSiN films was studied. The results show that when the pulsed bias duty ratio is 30%, the number of macroparticles on the surface of the TiSiN film reaches a maximum of 832, and when the duty ratio is 60%, the number of macroparticles decreases to 451. With the increases of pulsed bias duty ratio from 20% to 50%, the film thickness on the surface of the Si specimen increases from 390.8 nm to 2.339 μm. When the duty ratio is 30%, the content of Si element in the film is up to 13.88at%, the (220) crystal plane is the preferred orientation, the grain size reaches the minimum value of 5.05 nm, the hardness reaches 28.34 GPa, and the self-corrosion current density reaches the minimum value of 0.5306 μA/cm2. When the duty ratio is 40%, the (111) crystal plane is the preferred orientation, the content of Si element is reduced to the minimum value of 0.46at%. When the duty ratio is 50%, the grain size of the (111) crystal plane reaches 13.22 nm, the hardness reaches the maximum value of 42.08 GPa, and the self-corrosion potential reaches the maximum value of -0.324 V (vs SCE). When the duty ratio is more than 40%, the number of macroparticle defects and the Si content in the TiSiN film are reduced. Meanwhile the preferred orientation of grain growth of the TiSiN film changes from (220) to (111), and the hardness and corrosion resistance of the TiSiN films are improved.
    Effect of ion nitriding on microstructure and properties of 304 stainless steel
    Niu Yi, He Zhanxu, Wang Mingli, Zhang Jie, Niu Wenpeng, Liu Guanjun
    2022, 47(8):  287-291.  doi:10.13251/j.issn.0254-6051.2022.08.047
    Abstract ( 47 )   PDF (629KB) ( 31 )  
    In order to improve the service life and the purity of the material when sieving the positive and negative materials of the lithium battery by the rotary vibrating screen, the microstructure, hardness and corrosion resistance of the 304 stainless steel test block ion nitrided at 520 ℃ for different time were studied. The hardness and depth of the nitrided layer were tested by Vickers microhardness and optical microscope, the friction and wear properties of the nitrided layer were tested by ball disc rotary friction and wear tester, the corrosion resistance was tested by electrochemical workstation, and the phase of the nitrided layer was analyzed by X-ray diffractometer. The results show that compared with the untreated 304 stainless steel, the hardness of the nitrided layer at 30 μm on 304 stainless steel is improved by 5-6 times, and the relative wear resistance of the nitrided layer is 24.5 times of that of the untreated 304 stainless steel. Although the salt corrosion resistance of the specimen ion nitrided decreases, the alkaline corrosion resistance improves. Considering the characteristics of alkaline cathode material and neutral cathode material of lithium energy battery, the 304 stainless steel grid and screen frame on the rotary vibrating screen can not only greatly improve the service life of the rotary vibrating screen, but also improve the purity of the screened materials.
    FAILURE ANALYSIS
    Fracture causes analysis of front lifting lug of 30CrMnSiA alloy
    Zheng Hong, Lin Wenqin, Yang Yuanxi, Xu Xinjie, Deng Feng, Wu Jiaxin, Jiang Hongjun
    2022, 47(8):  292-295.  doi:10.13251/j.issn.0254-6051.2022.08.048
    Abstract ( 73 )   PDF (395KB) ( 48 )  
    A front lifting lug made of 30CrMnSiA alloy was broken and failed, whose fracture characteristics were analyzed and the hardness test was carried out. The results show that the fracture of the lifting lug is hydrogen embrittlement fracture and there is a phenomenon of excessive hardness. By combining the lug heat treatment and surface treatment process, it shows that incomplete hydrogen removal during surface treatment is the main cause of hydrogen embrittlement. Excessive hardness not only increases hydrogen embrittlement sensitivity, but also misleads the dehydrogenation process, so it is necessary for the lifting lugs to avoid excessive hardness. At the same time, the failure event reflects the lack of supplier quality control, and it is necessary to strengthen control and audit efforts in special processes and secondary outsourcing.
    Failure analysis of 40CrNiMoA steel transmission shaft spline
    Jin Yuliang, Liu Chunjiang, Wu Binlong, Zhang Hongliang
    2022, 47(8):  296-300.  doi:10.13251/j.issn.0254-6051.2022.08.049
    Abstract ( 74 )   PDF (394KB) ( 40 )  
    Cracks were found in the spline part of 40CrNiMoA steel transmission shaft used in a aero engine during normal inspection. Macro analysis, scanning electron microscopy and energy spectrum analysis, metallographic analysis, hardness analysis and temperature and color contrast experimental analysis were carried out on the fracture site. The results show that the structure of spline crack zone of the 40CrNiMoA transmission shaft is consistent with that of the matrix, and no decarburization phenomenon is observed. The crack is intergranular fracture, and the oxidation of crack surface is obvious. Therefore, it can be inferred that the crack is generated during the heating stage of high-frequency quenching, which results from excessive heating current or uneven heating. It is suggested to reasonably control the high frequency quenching process of transmission shaft.
    EQUIPMENT
    Temperature measurement method of autoclave for nuclear industry
    Yu Zeli, Fang Yongqiang, Bai Xinfang, Yu Sen, Zhang Shuxiang, Duan Guan
    2022, 47(8):  301-306.  doi:10.13251/j.issn.0254-6051.2022.08.050
    Abstract ( 48 )   PDF (393KB) ( 20 )  
    An on-line calibration device was designed to calibrate the temperature uniformity, axial temperature field, radial temperature field and temperature stability of the autoclave, the size of the effective heating area of the autoclave was determined, the source of the measurement result uncertainty of the temperature uniformity of the autoclave was analyzed, and the uncertainty evaluation method was determined. The reliability of the calibration results was verified by comparison with several laboratories. The results show that the calibration tooling used is reasonable and practical, which fundamentally solves the problem of high-pressure high temperature on-line calibration. The comparison results of several laboratories are satisfactory and meet the production needs.