金属热处理 ›› 2023, Vol. 48 ›› Issue (5): 110-115.DOI: 10.13251/j.issn.0254-6051.2023.05.018

• 材料研究 • 上一篇    下一篇

新型N合金化Cr13型耐蚀塑料模具钢的组织性能

张浩1,2, 迟宏宵2, 王成蹊1, 马党参2, 樊译2, 谢官利2   

  1. 1.昆明理工大学 材料科学与工程学院, 云南 昆明 650093;
    2.钢铁研究总院有限公司 特殊钢研究院, 北京 100081
  • 收稿日期:2022-11-01 修回日期:2023-03-24 出版日期:2023-05-25 发布日期:2023-06-21
  • 通讯作者: 王成蹊,副教授,博士,E-mail:cxwang@kust.edu.cn
  • 作者简介:张 浩(1998—),男,硕士研究生,主要研究方向为塑料模具钢,E-mail: zhangkust@163.com。

Microstructure and properties of novel nitrogen-alloyed corrosion resistant plastic die steel Cr13

Zhang Hao1,2, Chi Hongxiao2, Wang Chengxi1, Ma Dangshen2, Fan Yi2, Xie Guanli2   

  1. 1. Faculty of Materials Science and Engineering, Kunming University of Science and Technology, Kunming Yunnan 650093, China;
    2. Research Institute of Special Steels, Central Iron and Steel Research Institute Company Limited, Beijing 100081, China
  • Received:2022-11-01 Revised:2023-03-24 Online:2023-05-25 Published:2023-06-21

摘要: 采用光学显微镜、扫描电镜、硬度试验、冲击试验、盐雾腐蚀试验对新型N合金化Cr13型耐蚀塑料模具钢和传统Cr13型耐蚀塑料模具钢的组织和性能进行对比研究。结果表明,新型N合金化Cr13型耐蚀塑料模具钢除N之外,还添加了Ni、Mo、V等合金元素,新型N合金化Cr13型耐蚀塑料模具钢与传统Cr13型耐蚀塑料模具钢洁净度差异不大,但新型N合金化Cr13型耐蚀塑料模具钢退火组织更为均匀,退火硬度更低,更易机械加工。经相同热处理后,新型N合金化Cr13型耐蚀塑料模具钢的组织更为均匀,未溶碳化物数量减少;新型N合金化Cr13型耐蚀塑料模具钢的硬度为51.8 HRC,冲击吸收能量为12.3 J,而传统Cr13型耐蚀塑料模具钢的硬度为52.7 HRC,冲击吸收能量为6.9 J,两者硬度相当,但新型N合金化Cr13型耐蚀塑料模具钢拥有更好的韧性;经120 h的盐雾腐蚀后,新型N合金化Cr13型耐蚀塑料模具钢表面腐蚀坑较少,腐蚀速率为0.0594 g/(m2·h),传统Cr13型耐蚀塑料模具钢表面有明显的腐蚀坑,腐蚀速率为0.1136 g/(m2·h),新型N合金化Cr13型耐蚀塑料模具钢的耐蚀性更好。

关键词: 耐蚀塑料模具钢, N合金化, 组织, 力学性能, 耐蚀性

Abstract: Microstructure and properties of novel N-alloyed and the traditional Cr13 corrosion resistant plastic die steels were investigated and compared by means of optical microscope, scanning electron microscope, hardness test, impact test and salt spray corrosion test. The results show that the novel N-alloyed Cr13 steel contains, except for the N, other alloying elements such as Ni, Mo and V. The difference in cleanliness between the novel N-alloyed Cr13 steel and traditional Cr13 steel is not significant, but the annealed novel N-alloyed Cr13 steel has a more uniform microstructure, lower hardness and thus the better cutting performance. Under the same heat treatment, the microstructure of the novel N-alloyed Cr13 corrosion resistant plastic die steel is more uniform, the amount of undissolved carbides reduces. The conventional Cr13 steel has a hardness of 52.7 HRC and an impact absorbed energy of 6.9 J, while the novel N-alloyed Cr13 steel has a comparable hardness with the value of 51.8 HRC but a much better toughness (12.3 J). After salt spray corrosion for 120 h, the novel N-alloyed Cr13 steel has fewer corrosion pits and the corrosion rate is 0.0594 g/(m2·h), while there are obvious corrosion pits on surface of the traditional Cr13 corrosion resistant plastic die steel and the corrosion rate is 0.1136 g/(m2·h), which means that the corrosion resistance of the novel N-alloyed Cr13 steel is better than that of the conventional Cr13 steel.

Key words: corrosion resistant plastic die steel, nitrogen-alloying, microstructure, mechanical properties, corrosion resistance

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