加热温度对10CrNiCuSi钢氧化铁皮的影响

doi:10.13251/j.issn.0254-6051.2022.01.011

金属热处理 ›› 2022, Vol. 47 ›› Issue (1): 63-68.DOI: 10.13251/j.issn.0254-6051.2022.01.011

加热温度对10CrNiCuSi钢氧化铁皮的影响

赵蕾¹, 李建铭², 穆晓彪¹, 柴希阳¹, 柴锋¹, 潘涛¹

1.钢铁研究总院工程用钢研究院, 北京 100081;
2.渤海造船厂集团有限公司物资管理部, 辽宁葫芦岛 125000

收稿日期:2021-09-20 修回日期:2021-11-05 出版日期:2022-01-25 发布日期:2022-02-18
通讯作者: 柴希阳,高级工程师,E-mail:chaixiyang0728@163.com
作者简介:赵蕾(1994—),女,硕士研究生,主要研究方向为船舶与海工用钢的表面质量,E-mail:782014934@qq.com。

Effect of heating temperature on oxide scale of 10CrNiCuSi steel

Zhao Lei¹, Li Jianming², Mu Xiaobiao¹, Chai Xiyang¹, Chai Feng¹, Pan Tao¹

1. Research Institute of Structural Steels, Central Iron and Steel Research Institute, Beijing 100081, China;
2. Material Management Department of Bohai Shipyard Group Co., Ltd., Huludao Liaoning 125000, China

Received:2021-09-20 Revised:2021-11-05 Online:2022-01-25 Published:2022-02-18

摘要/Abstract

摘要： 为改善10CrNiCuSi船板钢表面质量粗糙的问题,采用电阻炉开展了1100~1300 ℃高温氧化试验,利用弯曲试验评价了氧化铁皮的剥离性,并研究了不同温度下氧化铁皮的演变规律。结果表明,随着加热温度的升高,氧化速率增大,氧化层厚度明显增加。氧化铁皮主要由Fe₂O₃、Fe₃O₄、FeO和内氧化层组成,而内氧化层主要由FeNiCu、Fe₂SiO₄和FeO相组成。加热过程中Fe₂SiO₄/FeO共晶液相的产生对氧化铁皮的剥离性具有重要影响。在1100 ℃和1150 ℃条件下,内氧化层中的Fe₂SiO₄呈现颗粒状或块状弥散分布,氧化铁皮与基体之间界面平直,氧化铁皮易于剥离;在1200、1250和1300 ℃条件下,Fe₂SiO₄-FeO或Fe₂SiO₄发生熔化形成液相渗入基体和氧化铁皮中,造成界面粗糙,而锚状FeNiCu相与基体及氧化铁皮具有较好的结合力,两者的协同作用造成氧化铁皮难于剥离。因此在1100 ~1150 ℃条件下去除氧化铁皮较为合适。

关键词: 10CrNiCuSi钢, 加热温度, 氧化铁皮, Fe₂SiO₄-FeO, 剥离性

Abstract: In order to improve the surface roughness of 10CrNiCuSi shipbuilding steel, the oxidation experiment at 1100-1300 ℃ under air condition was carried out in a resistance furnace. The exfoliation of the oxide scales was evaluated by bend tests. And the evolution of oxide scales at different temperature was studied. The results show that the oxidation rate and thickness of oxide layer increase with the increase of heating temperature. The scale of the tested steel is mainly composed of Fe₂O₃, Fe₃O₄, FeO and internal oxide layer, and the internal oxide layer consists of FeNiCu, Fe₂SiO₄ and FeO phases. The liquid eutectic Fe₂SiO₄/FeO products have a significant influence on the exfoliation of the oxide scales. At the conditions of 1100 ℃ and 1150 ℃, the Fe₂SiO₄ phases presented with granular or massive shape are dispersed in the internal FeO phases. The interface between the scale and the matrix is relatively straight and the scale is easily exfoliated. At the conditions of 1200, 1250 and 1300 ℃, the eutectic product of Fe₂SiO₄-FeO presents an anchor-like morphology, which is pinned to the interface of oxide scale and substrate resulting in rough bonding interface, and the anchor-like FeNiCu phases have a good bonding properties with substrate and the scale. The synergistic effects cause the oxide scale hard to exfoliate. Therefore, it is more appropriate to remove the oxide scales at 1100-1150 ℃.

Key words: 10CrNiCuSi steel, heating temperature, oxide scale, Fe₂SiO₄-FeO, exfoliation

中图分类号:

TG156.1

赵蕾, 李建铭, 穆晓彪, 柴希阳, 柴锋, 潘涛. 加热温度对10CrNiCuSi钢氧化铁皮的影响[J]. 金属热处理, 2022, 47(1): 63-68.

Zhao Lei, Li Jianming, Mu Xiaobiao, Chai Xiyang, Chai Feng, Pan Tao. Effect of heating temperature on oxide scale of 10CrNiCuSi steel[J]. Heat Treatment of Metals, 2022, 47(1): 63-68.

参考文献

[1]张清东, 张勃洋, 李瑞, 等. 钢板微观表面质量控制理论与技术研究进展[J]. 机械工程学报, 2016, 52(10): 32-45.
Zhang Qingdong, Zhang Boyang, Li Rui, et al. Advances in theory and technology for microscopic surface quality control of steel strip[J]. Journal of Mechanical Engineering, 2016, 52(10): 32-45.
[2]秦玉荣. 钢材表面质量及智能检测发展综述[J]. 南钢科技与管理, 2020(2): 32-33.
Qin Yurong. Steel surface quality and development of intelligent detection[J]. Technology and management of Nangang, 2020(2): 32-33.
[3]侯登义. 高表面质量中厚钢板表面麻点缺陷的成因与预防措施[J]. 宽厚板, 2014, 20(5): 14-17.
Hou Dengyi. Causes and preventive measures of surface pitting for high surface quality steel plat[J]. Wide and Heavy Plate, 2014, 20(5): 14-17.
[4]马国金, 王雪松, 王飞. 中厚板热处理表面质量缺陷分析与控制[J]. 中国冶金, 2018, 28(8): 60-62.
Ma Guojin, Wang Xuesong, Wang Fei. Analysis and control of surface quality defects in heat treatment of heavy plate[J]. China Metallurgy, 2018, 28(8): 60-62.
[5]Fukagawa T, Okada H, Maehara Y. Mechanism of red scale defect formation in Si-added hot-rolled steel sheets[J]. ISIJ International, 1994, 34(11): 906-911.
[6]王松涛, 李敏, 朱立新, 等. Si 含量对热轧板卷表面红色氧化铁皮的影响[J]. 热加工工艺, 2011, 40(16): 50-52.
Wang Songtao, Li Min, Zhu Lixin, et al. effect of silicon content on red scale of hot rolling coil[J]. Hot Working Technology, 2011, 40(16): 50-52.
[7]刘翊之, 杨才福, 柴锋, 等. 高铜镍结构钢高温氧化层和内表层缺陷研究[J]. 材料科学与工艺, 2013, 21(6): 78-83.
Liu Yizhi, Yang Caifu, Chai Feng, et al. Study on oxidation layer and interior surface defect under high temperature of high Cu-Ni structural steel[J]. Materials Science and Technology, 2013, 21(6): 78-83.
[8]Okada H, Fukagawa T, Ishihara H, et al. Prevention of red scale formation during hot rolling of steels[J]. ISIJ International, 1995, 35(7): 886-891.
[9]于洋, 王畅, 王林, 等. 基于高温氧化特性的含 Si 钢红铁皮缺陷研究[J]. 轧钢, 2016, 33(2): 10-15.
Yu Yang, Wang Chang, Wang Lin, et al. The red scale defect formation mechanism of contain Si steel based on its high temperature oxidation characteristics[J]. Steel Rolling, 2016, 33(2): 10-15.
[10]孙彬, 尤宏广, 郝明欣, 等. Fe-Si合金的高温氧化行为[J]. 沈阳大学学报(自然科学版), 2019, 31(4): 263-267.
Sun Bin, You Hongguang, Hao Mingxin, et al. High temperature behavior of Fe-Si alloy[J]. Journal of Shenyang University(Natural Science), 2019, 31(4): 263-267.
[11]Yuan Q, Xu G, Zhou M, et al. The effect of the Si content on the morphology and amount of Fe₂SiO₄ in low carbon steels[J]. Metals, 2016, 6(4): 94.
[12]Suárez L, Rodríguez-Calvillo P, Houbaert Y, et al. Oxidation of ultra low carbon and silicon bearing steels[J]. Corrosion Science, 2010, 52(6): 2044-2049.
[13]Asai T, Soshiroda T, Miyahara M. Influence of Ni impurity in steel on the removability of primary scale in hydraulic descaling[J]. ISIJ International, 1997, 37(3): 272-277.
[14]陆关福, 顾建忠, 吴光亚. 少量 Ni, Cr元素对低碳钢氧化铁皮粘附性的影响[J]. 金属学报, 1985, 21(5): 31-36.
Lu Guanfu, Gu Jianzhong, Wu Guangya. Effect of minor Ni or/and Cr contents on coherence of oxidized layer with low carbon steel substrate[J]. Acta Metallurgica Sinica, 1985, 21(5): 31-36.
[15]Melfo W, Bolt H, Rijnders M, et al. Experimental study on primary scale formation and descalability on steels containing Ni and Ni+Si[J]. ISIJ International, 2013, 53(5): 866-873.

加热温度对10CrNiCuSi钢氧化铁皮的影响

Effect of heating temperature on oxide scale of 10CrNiCuSi steel

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