金属热处理 ›› 2021, Vol. 46 ›› Issue (4): 16-19.DOI: 10.13251/j.issn.0254-6051.2021.04.003

• 材料研究 • 上一篇    下一篇

Sn-Co合金热处理过程中的CoSn2→CoSn4相变

吕冠辰, 梁文雷, 索玉松, 李磊   

  1. 东北大学 材料电磁过程研究教育部重点实验室, 辽宁 沈阳 110819
  • 收稿日期:2020-10-02 出版日期:2021-04-25 发布日期:2021-05-08
  • 通讯作者: 李磊,副教授,博士生导师,E-mail:lilei@epm.neu.edu.cn
  • 作者简介:吕冠辰(1995—),男,硕士研究生,主要研究方向为Sn-Co合金组织及相变,E-mail:1390025139@qq.com。
  • 基金资助:
    国家自然科学基金(51874092);中央高校基本科研业务费(N180905009)

CoSn2→CoSn4 phase transformation of Sn-Co alloy during heat treatment

Lü Guanchen, Liang Wenlei, Suo Yusong, Li Lei   

  1. Key Laboratory of Electromagnetic Processing of Materials, Ministry of Education, Northeastern University, Shenyang Liaoning 110819, China
  • Received:2020-10-02 Online:2021-04-25 Published:2021-05-08

摘要: 对Sn-1.3wt%Co合金进行215 ℃下保温5、10、15 min并淬火的热处理,借助光学显微镜、扫描电镜和能谱仪研究了原始CoSn2相的相变产物和形貌变化。结果发现:热处理导致Sn-1.3wt%Co合金发生了CoSn2→CoSn4相变;原始CoSn2相局部溶解且生成的CoSn4相相较于原始CoSn2相位置有所扩展;两相相似的晶体结构和原子排列是CoSn2相易转变为CoSn4相的重要原因。

关键词: Sn-Co合金, 热处理, CoSn2相, CoSn4相, 固态相变

Abstract: Phase transformation products and morphologies of the original CoSn2 phase in Sn-1.3wt%Co alloy which was heat treated at 215 ℃ for 5, 10, 15 min and water quenched respectively were studied by means of OM, SEM and EDS. The results show that CoSn2→CoSn4 phase transformation occurs due to the heat treatment. The original CoSn2 phase is partially dissolved and the position of resulting CoSn4 phase is somewhat expanded relative to that of the original CoSn2 phase. The similarity of crystal structure and atomic arrangement of the two phases are the important reasons for the transformation of CoSn2 phase into CoSn4 phase.

Key words: Sn-Co alloy, heat treatment, CoSn2 phase, CoSn4 phase, solid-state phase transformation

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