金属热处理 ›› 2025, Vol. 50 ›› Issue (11): 103-109.DOI: 10.13251/j.issn.0254-6051.2025.11.015

• 综述 • 上一篇    下一篇

超晶格型稀土储氢合金结构与气固储氢性能的研究进展

刘克明1, 徐杰凯1,2, 章天锋1, 邹晋2   

  1. 1.江西水利电力大学 精密驱动与装备江西省重点实验室, 江西 南昌 330099;
    2.江西省科学院应用物理研究所 铜基新材料江西省重点实验室, 江西 南昌 330096
  • 收稿日期:2025-06-16 修回日期:2025-10-04 发布日期:2025-12-16
  • 通讯作者: 邹 晋,研究员,E-mail:niatzou@126.com
  • 作者简介:刘克明(1974—),男,教授,博士,主要研究方向为高性能金属基复合材料,E-mail:jokeyliu@163.com。
  • 基金资助:
    国家重点研发计划(2022YFB3504700);江西省学科学术带头人项目(20232BCJ22053);铜基新材料江西省重点实验室项目(2024SSY05021)

Research progress on structure and gas-solid hydrogen storage properties of superlattice-type rare earth hydrogen storage alloys

Liu Keming1, Xu Jiekai1,2, Zhang Tianfeng1, Zou Jin2   

  1. 1. Jiangxi Province Key Laboratory of Precision Drive and Equipment, Jiangxi University of Water Resources and Electric Power, Nanchang Jiangxi 330099, China;
    2. Jiangxi Key Laboratory of Advanced Copper-based Materials, Institute of Applied Physics, Jiangxi Academy of Sciences, Nanchang Jiangxi 330096, China
  • Received:2025-06-16 Revised:2025-10-04 Published:2025-12-16

摘要: 超晶格型稀土储氢合金凭借其独特的晶体结构和优异的储氢性能被广泛应用于镍氢电池、固态储氢系统和加氢站等领域。但随着应用场景的复杂化和性能需求的多样化,一些高新技术领域对超晶格型稀土储氢合金的气固储氢性能提出了更高要求。由此,分析了超晶格型稀土储氢合金的结构特征和目前气固储氢性能的研究现状,总结了超晶格型稀土储氢合金气固储氢性能提升的主要方法如元素替代、退火处理等,着重探讨了各方法对超晶格型稀土储氢合金结构和气固储氢性能的影响,展望了超晶格型稀土储氢合金气固储氢性能研究的未来方向。

关键词: 超晶格型稀土储氢合金, 晶体结构, 气固储氢性能, 元素替代, 退火处理

Abstract: Superlattice-type rare earth hydrogen storage alloys have been widely used in Ni-MH batteries, solid state hydrogen storage systems and hydrogen refueling stations based on their unique crystal structure and excellent hydrogen storage properties. However, with the complexity of application scenarios and diversification of performance requirements, some high-tech fields have put forward higher requirements for gas-solid hydrogen storage properties of superlattice-type rare earth hydrogen storage alloys. Therefore, the structure characteristics of superlattice-type rare earth hydrogen storage alloys and the current research status of gas-solid hydrogen storage properties were analyzed. The main methods for improving gas-solid hydrogen storage properties of superlattice-type rare earth hydrogen storage alloys were summarized, such as element substitution, annealing treatment. The effects of these methods on the structure and gas-solid hydrogen storage properties of superlattice-type rare earth hydrogen storage alloys were emphatically discussed. The future research direction of gas-solid hydrogen storage properties of superlattice-type rare earth hydrogen storage alloys was envisioned.

Key words: superlattice-type rare earth hydrogen storage alloys, crystal structure, gas-solid hydrogen storage properties, element substitution, annealing treatment

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