形变热处理对Cu-6Ni-3Ti合金组织和性能的影响

doi:10.13251/j.issn.0254-6051.2023.07.016

金属热处理 ›› 2023, Vol. 48 ›› Issue (7): 91-96.DOI: 10.13251/j.issn.0254-6051.2023.07.016

形变热处理对Cu-6Ni-3Ti合金组织和性能的影响

靖青秀, 韦丹丹, 魏渺, 杨雪晴, 肖翔鹏, 黄晓东

江西理工大学材料冶金化学学部, 江西赣州 341000

收稿日期:2022-12-26 修回日期:2023-05-08 出版日期:2023-07-25 发布日期:2023-09-04
通讯作者: 黄晓东,副教授,硕士,E-mail:huangmail3@126.com
作者简介:靖青秀(1975—),女,副教授,博士,主要研究方向为铜基新材料研发,E-mail:1315335810@qq.com。

Effect of deformation heat treatment on microstructure and properties of Cu-6Ni-3Ti alloy

Jing Qingxiu, Wei Dandan, Wei Miao, Yang Xueqing, Xiao Xiangpeng, Hang Xiaodong

Faculty of Materials Metallurgy and Chemistry, Jiangxi University of Science and Technology, Ganzhou Jiangxi 341000, China

Received:2022-12-26 Revised:2023-05-08 Online:2023-07-25 Published:2023-09-04

摘要/Abstract

摘要： 采用X射线衍射仪(XRD)、扫描电镜(SEM)和透射电镜(TEM)对Cu-6Ni-3Ti合金形貌和成分进行表征,研究了形变热处理对合金组织与性能的影响。结果表明,铸态合金组织呈明显的树枝状结构,主要由α-Cu和CuNiTi相组成,热处理后合金硬度显著降低;随着冷变形量的增加,时效后合金的导电率显著升高,但也导致峰值硬度后合金的硬度大幅降低;90%变形量+450 ℃时效2 h 后,合金的硬度与导电率分别为203 HV0.5和52%IACS。

关键词: Cu-6Ni-3Ti合金, CuNiTi相, 显微组织硬度, 导电率

Abstract: Morphology and composition of Cu-6Ni-3Ti alloy were characterized by means of X-ray diffractometer(XRD), scanning electron microscope(SEM) and transmission electron microscope(TEM). The effect of deformation heat treatment on microstructure and properties of the alloy was studied. The results show that microstructure of the as-cast alloy is dendritic and mainly composes of α-Cu and CuNiTi phases. The hardness of the alloy decreases significantly after heat treatment. With the increase of cold deformation, the conductivity of the alloy increases significantly after aging, but the hardness of the alloy decreases greatly after peak hardness. After aging at 450 ℃ for 2 h with 90% deformation, the hardness and conductivity of the alloy are 203 HV0.5 and 52%IACS, respectively.

Key words: Cu-6Ni-3Ti alloy, CuNiTi phase, microstructure, hardness, conductivity

中图分类号:

TG146.1

靖青秀, 韦丹丹, 魏渺, 杨雪晴, 肖翔鹏, 黄晓东. 形变热处理对Cu-6Ni-3Ti合金组织和性能的影响[J]. 金属热处理, 2023, 48(7): 91-96.

Jing Qingxiu, Wei Dandan, Wei Miao, Yang Xueqing, Xiao Xiangpeng, Hang Xiaodong. Effect of deformation heat treatment on microstructure and properties of Cu-6Ni-3Ti alloy[J]. Heat Treatment of Metals, 2023, 48(7): 91-96.

参考文献

[1]耿永锋, 张毅, 田保红, 等. 形变热处理对Cu-0.80Cr-0.30Zr-0.03P合金时效性能的影响[J]. 材料热处理学报, 2019, 40(8): 69-75.
Geng Yongfeng, Zhang Yi, Tian Baohong, et al. Effects of thermo-mechanical treatment on aging properties of Cu-0.80Cr-0.30Zr-0.03P alloy[J]. Transactions of Materials and Heat Treatment, 2019, 40(8): 69-75.
[2]赵冬梅, 董企铭, 刘平, 等. 超高强度Cu-Ni-Si合金时效过程研究[J]. 材料热处理学报, 2002, 23(2): 20-23.
Zhao Dongmei, Dong Qiming, Liu Ping, et al. Study on the ageing process of a super high-strength Cu-Ni-Si alloy[J]. Transactions of Materials and Heat Treatment, 2002, 23(2): 20-23.
[3]董琦祎, 汪明朴, 贾延琳, 等. 磷含量对Cu-Fe-P合金组织与性能的影响[J]. 材料热处理学报, 2013, 34(6): 75-79.
Dong Qiyi, Wang Mingpu, Jia Yanlin, et al. Effect of P content on microstructure and property of Cu-Fe-P alloys[J]. Transactions of Materials and Heat Treatment, 2013, 34(6): 75-79.
[4]徐晓岑, 李家智, 丁桦, 等. 组合形变热处理工艺对Cu-Cr-Zr-Si合金组织性能及抗软化特性的影响[J]. 材料热处理学报, 2021, 42(7): 57-64.
Xu Xiaocen, Li Jiazhi, Ding Hua, et al. Effect of combined thermo-mechanical treatment on microstructure, properties and softening resistance of Cu-Cr-Zr-Si alloy[J]. Transactions of Materials and Heat Treatment, 2021, 42(7): 57-64.
[5]从善海, 韩芳, 汪旭超. 超高强Cu-Ni-Sn合金的热处理工艺与组织性能[J]. 金属热处理, 2010, 35(6): 43-47.
Cong Shanhai, Han Fang, Wang Xuchao. Heat treatment process, microstructure properties of super high strength Cu-Ni-Sn alloy[J]. Heat Treatment of Metals, 2010, 35(6): 43-47.
[6]Yang Y H, Li S Y, Cui Z S, et al. Microstructure and properties of high-strength Cu-Ni-Si-(Ti) alloys[J]. Rare Metals, 2021, 40(11): 3251-3260.
[7]饶劢攀, 刘勇, 田保红, 等. Cu-Ni-Si-Co-Zr合金的热压缩行为[J]. 材料热处理学报, 2021, 42(8): 48-53.
Rao Maipan, Liu Yong, Tian Baohong, et al. Hot compression behavior of Cu-Ni-Si-Co-Zr alloy[J]. Transactions of Materials and Heat Treatment, 2021, 42(8): 48-53.
[8]沈斌, 程建奕, 李海英. Cu-Cr-Zr-Mg合金的相变动力学[J]. 材料热处理学报, 2014, 35(9): 121-125.
Shen Bin, Cheng Jianyi, Li Haiying. Dynamics of phase transformation of Cu-Cr-Zr-Mg alloy[J]. Transactions of Materials and Heat Treatment, 2014, 35(9): 121-125.
[9]任维佳. 导电弹性Cu-Ti-Ni-X(Ag,Y)合金组织与性能研究[D]. 西安: 西安理工大学, 2016.
Ren Weijia. Investigation on microstructure and properties of conductive elastic Cu-Ti-Ni-X(Ag,Y) alloys[D]. Xi'an: Xi'an University of Technology, 2016.
[10]王剑, 阙仲萍, 陈津, 等. Zn对Cu-Ni-Ti合金导电率和硬度的影响研究[J]. 太原理工大学学报, 2015, 46(1): 35-39.
Wang Jian, Que Zhongping, Chen Jin, et al. Effect of zinc on electrical conductivity and mechanical properties of Cu-Ni-Ti alloy[J]. Journal of Taiyuan University of Technology, 2015, 46(1): 35-39.
[11]王剑, 陈津, 阙仲萍. 合金元素Sn对Cu-Ni-Ti合金微观组织和性能的影响[J]. 太原理工大学学报, 2018, 49(4): 517-524.
Wang Jian, Chen Jin, Que Zhongping. Effect of Sn on microstructure and properties of Cu-Ni-Ti alloy[J]. Journal of Taiyuan University of Technology, 2018, 49(4): 517-524.
[12]Liu J, Liu J, Wang X, et al. Phase-transformation dynamics and characterization of precipitates in the Cu-3Ti-3Ni-0.5Si alloy[J]. Materials and Technology, 2021, 55(4): 483-489.
[13]Kim H G, Lee T W, Kim S M, et al. Effects of Ti addition and heat treatments on mechanical and electrical properties of Cu-Ni-Si alloys[J]. Metals and Materials International, 2013, 19(1): 61-65.
[14]黄富, 余方新, 冯桄波, 等. 高强铜钛合金的发展与应用[J]. 特种铸造及有色合金, 2020, 40(5): 502-506.
Huang Fu, Yu Fangxin, Feng Guangbo, et al. Development and application of high strength and high elasticity copper-titanium alloy[J]. Special Casting and Nonferrous Alloys, 2020, 40(5): 502-506.
[15]满绪存. Ni、Ti原子比例及含量对Cu-Ni-Ti合金组织性能的影响[D]. 赣州: 江西理工大学, 2021.
Man Xucun. Effect of atomic ratio and content of Ni and Ti on microstructure and properties of Cu-Ni-Ti alloys[D]. Ganzhou: Jiangxi University of Science and Technology, 2021.
[16]Liu J, Wang X, Guo T, et al. Microstructure and properties of Cu-Ti-Ni alloys[J]. International Journal of Minerals, Metallurgy, and Materials, 2015, 22(11): 1199-1204.
[17]刘佳, 王献辉, 冉倩妮, 等. 深冷处理对Cu-3Ti-5Ni合金组织与性能的影响[J]. 金属热处理, 2015, 40(11): 160-164.
Liu Jia, Wang Xianhui, Ran Qianni, et al. Effect of cryogenic treatment on microstructure and properties of Cu-3Ti-5Ni alloy[J]. Heat Treatment of Metals, 2015, 40(11): 160-164.
[18]Zhang P, Li Y, Lei Q, et al. Microstructure and mechanical properties of a Cu-Ni-Ti alloy with a large product of strength and elongation[J]. Journal of Materials Research and Technology, 2020, 9(2): 2299-2307.
[19]Liu J, Wang X, Ran Q, et al. Microstructure and properties of Cu-3Ti-1Ni alloy with aging process[J]. Transactions of Nonferrous Metals Society of China, 2016, 26(12): 3183-3188.
[20]康军伟, 周延军, 宋克兴, 等. 高强高导Cu-Cr-X合金退火态组织性能[J]. 材料热处理学报, 2020, 41(6): 62-68.
Kang Junwei, Zhou Yanjun, Song Kexing, et al. Microstructure and properties of annealed high strength and high conductivity Cu-Cr-X alloy[J]. Transactions of Materials and Heat Treatment, 2020, 41(6): 62-68.

形变热处理对Cu-6Ni-3Ti合金组织和性能的影响

Effect of deformation heat treatment on microstructure and properties of Cu-6Ni-3Ti alloy

PDF

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	吴凡, 龚清华, 谢伟滨, 吴语, 陈辉明, 汪航. 微量Ni元素添加对Cu-Cr合金析出行为及性能的影响[J]. 金属热处理, 2023, 48(7): 49-53.
[2]	胡武, 吴艳梅, 黄显赞, 黄炎毅, 廖斌. 预处理对6082铝合金型材性能的影响[J]. 金属热处理, 2023, 48(7): 143-147.
[3]	仇晨, 荣莉, 魏午, 王为, 文胜平, 黄晖, 董阳, 王玉刚. 缓慢升温时效处理对Al-Zn-Mg-Er-Zr合金性能的影响[J]. 金属热处理, 2023, 48(3): 8-11.
[4]	赵宇, 魏午, 黄晖, 刘贞山, 任思蒙, 董阳, 王玉刚, 石薇. 6070铝合金的均匀化热处理[J]. 金属热处理, 2023, 48(3): 51-56.
[5]	陈俭兰, 赵莫迪, 韩福生. 退火对冷轧Cu-Ag合金组织及性能的影响[J]. 金属热处理, 2022, 47(8): 129-134.
[6]	陈保安, 张静媛, 祝志祥, 韩钰, 潘学东, 张磊, 陈素红. 化学成分对高强Al-Mg-Si合金组织和性能的影响[J]. 金属热处理, 2022, 47(4): 30-38.
[7]	靖青秀, 魏渺, 肖翔鹏, 孙玉晴, 彭勇, 黄晓东. Ni含量对Cu-xNi-3Ti-0.1Zr合金组织和性能的影响[J]. 金属热处理, 2022, 47(12): 146-151.
[8]	曾延琦, 余辉辉, 李洁, 邹晋, 姜江, 刘琦, 胡晓娜. 退火工艺对Cu-2Ag-0.075Y合金线坯组织和性能的影响[J]. 金属热处理, 2022, 47(11): 156-159.
[9]	靖青秀, 孙玉晴, 肖翔鹏, 魏渺, 彭勇, 黄晓东. 形变热处理对Cu-Ti-Fe-Sn合金组织与性能的影响[J]. 金属热处理, 2022, 47(10): 24-30.
[10]	曾延琦, 余辉辉, 陆德平, 张友亮, 胡强, 郭军力, 胡斐斐, 邹晋. 成品退火工艺对Cu-20wt%Fe原位复合带材组织和性能的影响[J]. 金属热处理, 2022, 47(10): 169-172.
[11]	马玉霞, 党淑娥, 陈慧琴. 固溶处理对Cu-Cr-Zr合金组织与性能的影响[J]. 金属热处理, 2022, 47(1): 163-166.
[12]	朱婷, 鹿宪珂, 杨森. 退火处理对铜导线晶界特征分布及导电性能的影响[J]. 金属热处理, 2021, 46(9): 85-89.
[13]	韩茜, 李茂扬, 秦国飞, 李旭东, 董超, 张美丽, 代卫丽. 固溶时效处理对8030铝合金导线组织性能的影响[J]. 金属热处理, 2021, 46(8): 125-132.
[14]	胡晓梅, 刘立宁, 苏凤, 王家明, 陈祥光, 许浩. 电线电缆用Al-Fe-Cu-0.25La-Zr耐热合金的导电性能[J]. 金属热处理, 2021, 46(8): 197-200.
[15]	潘雪新, 姜海昌, 封辉, 李学斌, 鲁衍任, 胡小锋, 付鸿. 高强高导电CuCrZr合金时效过程中析出相的演化规律[J]. 金属热处理, 2021, 46(7): 7-12.