工艺参数对WC颗粒增强表层复合材料与钢基界面组织的影响

doi:10.13251/j.issn.0254-6051.2021.11.020

金属热处理 ›› 2021, Vol. 46 ›› Issue (11): 131-136.DOI: 10.13251/j.issn.0254-6051.2021.11.020

工艺参数对WC颗粒增强表层复合材料与钢基界面组织的影响

张展展¹, 宁家庆¹, 左玲立², 廖海洋¹

1.湖南工业大学机械工程学院, 湖南株洲 412007;
2.中国机械科学研究总院集团有限公司北京机科国创轻量化科学研究院有限公司, 北京 100083

收稿日期:2021-08-21 出版日期:2021-11-25 发布日期:2021-12-08
通讯作者: 廖海洋,讲师,博士,E-mail:haiyangliao1990@163.com
作者简介:张展展(1986—),女,讲师,博士,主要研究方向为模具材料和复合材料组织与性能,E-mail:zhangzhanzhan0510@163.com
基金资助:
湖南省教育厅科学研究项目(18C0485);湖南省自然科学基金(2019JJ50116)

Effect of process parameters on interfacial microstructure of WC particle reinforced surface composite and steel substrate

Zhang Zhanzhan¹, Ning Jiaqing¹, Zuo Lingli², Liao Haiyang¹

1. School of Mechanical Engineering, Hunan University of Technology, Zhuzhou Hunan 412007, China;
2. Beijing National Innovation Institute of Lightweight Ltd., China Academy of Machinery Science and Technology Group Co., Ltd., Beijing 100083, China

Received:2021-08-21 Online:2021-11-25 Published:2021-12-08

摘要/Abstract

摘要： 以45钢为基材,通过放电等离子烧结和铸造工艺成功制备了WC颗粒增强表层复合材料,研究不同浇铸工艺参数对表层WC/Fe复合材料与基材之间的界面结合及微观组织的影响。结果表明:随着浇铸量的增加,锭模的数值模拟温度可达1493 ℃,高温停留时间约734 s,为实现钢液与WC/Fe复合材料冶金结合提供有利条件,但是过高的浇铸量使WC/Fe复合材料的组织发生明显的变化,几乎观察不到WC增强相,组织出现大量鱼骨状碳化物Fe₃W₃C。当浇铸量控制在锭模体积的2/5时,可得到良好的WC/Fe复合材料与基材的宏观界面,界面反应产物Fe₃W₃C增加,但是增强颗粒仍保留了浇铸前的原始形貌。

关键词: WC/Fe表层复合材料, 45钢, 界面组织, 铸造, 数值模拟

Abstract: WC particle reinforced surface composite was prepared on 45 steel as substrate material by spark plasma sintering and then casting process. The effects of various casting process parameters on the interface bonding and microstructure between the WC/Fe composite and the steel substrate were studied. The results show that when the casting amount increases, the numerical simulation ingot mold temperature may reach 1493 ℃, and the high temperature residence duration is about 734 s, providing favorable conditions for realizing the metallurgical bonding of molten steel and WC/Fe composite material. However, due to the large casting quantity, the microstructure of the WC/Fe composite material changes noticeably, and the WC strengthened phase is hardly observed, while a lot of fishbone carbide Fe₃W₃C appears in the microstructure. When the casting quantity is set to 2/5 of the mold volume, a good macroscopic interface between the WC/Fe composite and the steel substrate is formed, and the interface reaction product Fe₃W₃C increases, but the original morphology of the reinforced particles is still preserved.

Key words: WC/Fe surface composite, 45 steel, interfacial microstructure, casting, numerical simulation

中图分类号:

TG174.4

张展展, 宁家庆, 左玲立, 廖海洋. 工艺参数对WC颗粒增强表层复合材料与钢基界面组织的影响[J]. 金属热处理, 2021, 46(11): 131-136.

Zhang Zhanzhan, Ning Jiaqing, Zuo Lingli, Liao Haiyang. Effect of process parameters on interfacial microstructure of WC particle reinforced surface composite and steel substrate[J]. Heat Treatment of Metals, 2021, 46(11): 131-136.

参考文献

[1]Niu Libin, Hojamberdiev Mirabbos, Xu Yunhua, et al. Preparation of in situ-formed WC/Fe composite on gray cast iron substrate by a centrifugal casting process[J]. Journal of Materials Processing Technology, 2010, 210(14): 1986-1990.
[2]Li Zulai, Jiang Yehua, Zhou Rong, et al. Dry three-body abrasive wear behavior of WC reinforced iron matrix surface composites produced by V-EPC infiltration casting process[J]. Wear, 2007, 262(5/6): 649-654.
[3]Tomita T, Tatatani Y, Kobayashi Y, et al. Durability of WC/Co sprayed coatings in molten pure zinc[J]. ISIJ International, 1993, 33(9): 982-988.
[4]张蕾涛, 李海涛, 贾润楠, 等. 激光重熔Ni60/50%WC复合涂层的制备及性能[J]. 金属热处理, 2021, 46(5): 229-234.
Zhang Leitao, Li Haitao, Jia Runnan, et al. Preparation and properties of laser remelted Ni60/50%WC composite coating[J]. Heat Treatment of Metals, 2021, 46(5): 229-234.
[5]Bolelli Giovanni, Boerner Tim, Milanti Andrea, et al. Tribological behavior of HVOF-and HVAF-sprayed composite coatings based on Fe-alloy+WC-12%Co[J]. Surface and Coatings Technology, 2014, 248: 104-112.
[6]Li Bo, Yao Jianhua, Zhang Qunli, et al. Microstructure and tribological performance of tungsten carbide reinforced stainless steel composite coatings by supersonic laser deposition[J]. Surface and Coatings Technology, 2015, 275: 58-68.
[7]陆海峰, 潘晨阳, 覃恩伟, 等. 45钢表面激光熔覆WC/Ni基合金复合覆层的组织和性能[J]. 金属热处理, 2019, 44(12): 19-24.
Lu Haifeng, Pan Chenyang, Qin Enwei, et al. Microstructure and properties of laser clad WC/Ni-based alloy composite coating on 45 steel surface[J]. Heat Treatment of Metals, 2019, 44(12): 19-24.
[8]Lou D, Hellman J, Luhulima D, et al. Interactions between tungsten carbide (WC) particulates and metal matrix in WC-reinforced composites[J]. Materials Science and Engineering A, 2003, 340(1-2): 155-162.
[9]Zhang Zhanzhan, Chen Yunbo, Zhang Yang, et al, Tribology characteristics of ex-situ and in-situ tungsten carbide particles reinforced iron matrix composites produced by spark plasma sintering[J]. Journal of Alloys and Compounds, 2017, 704: 260-268.
[10]Zhang Zhanzhan, Chen Yunbo, Zuo Lingli, et al. The effect of volume fraction of WC particles on wear behavior of in-situ WC/Fe composites by spark plasma sintering[J]. International Journal of Refractory Metals and Hard Materials, 2017, 69: 196-208.
[11]张展展, 陈蕴博, 张洋, 等. 4放电等离子烧结 WC/Fe复合材料摩擦磨损性能[J]. 复合材料学报, 2017, 34(10): 2288-2295.
Zhang Zhanzhan, Chen Yunbo, Zhang Yang, et al. Tribology characteristics of WC/Fe composites by spark plasma sintering[J]. Acta Materiae Compositae Sinica, 2017, 34(10): 2288-2295.
[12]Zhang Zhanzhan, Chen Yunbo, Zuo Lingli, et al. In situ synthesis WC reinforced iron surface composite produced by spark plasma sintering and casting[J]. Materials Letters, 2018, 210: 227-230.
[13]汪亚飞, 谢敬佩, 王文焱, 等. 热处理工艺对碳钢/不锈钢双液铸造复合板界面显微组织的影响[J]. 金属热处理, 2018, 43(9): 166-170.
Wang Yafei, Xie Jingpei, Wang Wenyan, et al. Effect of heat treatment on interface microstructure of carbon steel/stainless steel dual-liquid casting composite plate[J]. Heat Treatment of Metals, 2018, 43(9): 166-170.
[14]Zhou Shengfeng, Zeng Xiaoyan. Growth characteristics and mechanism of carbides precipitated in WC-Fe composite coatings by laser induction hybrid rapid cladding[J]. Journal of Alloys and Compounds, 2010, 505: 685-691.
[15]Antoni-Zdziobek A, Shen J Y, Durand-Charre M. About one stable and three metastable eutectic microconstituents in the Fe-W-C system[J]. International Journal of Refractory Metals and Hard Materials, 2008, 26: 372-382.
[16]Hackenberg R E, Shiflet G J. Transitions in carbide morphology in a ternary Fe-CW steel[J]. Metallurgical and Materials Transactions A, 1998, 29(8): 2087-2100.
[17]Wang Jiandong, Li Liqun, Tao Wang. Crack initiation and propagation behavior of WC particles reinforced Fe-based metal matrix composite produced by laser melting deposition[J]. Optics and Laser Technology, 2016, 82: 170-182.
[18]Zhou Shengfeng, Zeng Xiaoyan. Growth characteristics and mechanism of carbides precipitated in WC-Fe composite coatings by laser induction hybrid rapid cladding[J]. Journal of Alloys and Compounds, 2014, 596: 48-54.
[19]Yuan Youlu, Li Zhuguo. Microstructure and tribology behaviors of in-situ WC/Fe carbide coating fabricated by plasma transferred arc metallurgic reaction[J]. Applied Surface Science, 2017, 423: 13-24.
[20]李鑫, 付永红, 刘金颂, 等. 扩散反应制备WC/Fe复合层的断裂韧性[J]. 金属热处理, 2019, 44(8): 95-99.
Li Xin, Fu Yonghong, Liu Jinsong, et al. Fracture toughness of WC/Fe composite layer through in situ reaction[J]. Heat Treatment of Metals, 2019, 44(8): 95-99.
[21]张宁, 倪琪. 电冶熔铸WC颗粒增强钢基复合材料的干滑动摩擦磨损性能[J]. 金属热处理, 2017, 42(8): 11-15.
Zhang Ning, Ni Qi. Dry sliding friction and wear behavior of WC particle reinforced steel matrix composites by electroslag melting and casting[J]. Heat Treatment of Metals, 2017, 42(8): 11-15.
[22]Pan Yafei, Liu Aijun, Huang Lei, et al. Effects of metal binder content and carbide grain size on the microstructure and properties of SPS manufactured WC-Fe composites[J]. Journal of Alloys and Compounds, 2019, 784: 519-526.

工艺参数对WC颗粒增强表层复合材料与钢基界面组织的影响

Effect of process parameters on interfacial microstructure of WC particle reinforced surface composite and steel substrate

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