45钢激光熔覆TiC涂层的制备及性能

doi:10.13251/j.issn.0254-6051.2024.03.044

金属热处理 ›› 2024, Vol. 49 ›› Issue (3): 269-274.DOI: 10.13251/j.issn.0254-6051.2024.03.044

45钢激光熔覆TiC涂层的制备及性能

刘志玲¹, 常明丰¹, 韩贵生¹, 戴姣燕², 徐金富^1,2

1.长安大学材料科学与工程学院, 陕西西安 710061;
2.宁波工程学院材料与化学工程学院, 浙江宁波 315211

收稿日期:2023-09-03 修回日期:2024-02-06 出版日期:2024-03-25 发布日期:2024-04-24
通讯作者: 徐金富,教授,博士,E-mail: xjf7413@sina.com
作者简介:刘志玲(1995—),女,硕士研究生,主要研究方向为金属材料成型及控制,E-mail:273315627@qq.com。
基金资助:
宁波市重点研发计划(2023Z024)

Preparation and properties of TiC coating on 45 steel by laser cladding

Liu Zhiling¹, Chang Mingfeng¹, Han Guisheng¹, Dai Jiaoyan², Xu Jinfu^1,2

1. School of Materials Science and Engineering, Chang'an University, Xi'an Shaanxi 710061, China;
2. School of Materials Science and Chemical Engineering, Ningbo University of Technology, Ningbo Zhejiang 315211, China

Received:2023-09-03 Revised:2024-02-06 Online:2024-03-25 Published:2024-04-24

摘要/Abstract

摘要： 利用Ni60+TiC梯度层结构,通过CO₂恒流激光器在45钢表面制备了TiC涂层,研究了工艺参数(激光功率、搭接率和扫描速率)对TiC涂层组织和性能的影响。结果表明,随着激光功率和扫描速率的增加,涂层表面裂纹先减后增,当激光功率为4.0 kW,扫描速率为400 mm/min时,涂层表面裂纹消失;随着搭接率的增加,涂层表面裂纹先增后减,搭接率至50%时,涂层表面裂纹消失。最佳工艺参数为:激光功率4.0 kW、扫描速率400 mm/min、搭接率50%,其处理后的TiC梯度涂层厚度约为1.2 mm,与基体层呈冶金结合,最表层组织为树枝状TiC及少量Ni基固溶体,梯度层组织为TiC+Ni基固溶体,TiC含量由表及里呈梯度减少,Ni基固溶体含量由表及里呈梯度增加;TiC涂层的显微硬度由表及里从1968 HV0.2梯度下降至240 HV0.2;TiC涂层的磨损率为1.757×10^-15 m³/(N·m)。

关键词: TiC涂层, 梯度层, 工艺参数, 摩擦磨损

Abstract: TiC coatings were cladded on the surface of 45 steel by a CO₂ constant current laser using Ni60+TiC gradient layer structure. The effect of process parameters(laser power, scanning rate and overlap rate) on the microstructure and properties of TiC coatings was investigated. The results show that the surface cracks of the coating decrease and then increase with the increase of laser power and scanning rate. The surface cracks disappear when the laser power is 4.0 kW and the scanning rate is 400 mm/min. With the increase of the overlap rate, the surface cracks of the coating increase and then decrease, and the surface cracks of the coating disappear when the overlap rate is 50%. The optimal process parameters are laser power 4.0 kW, scanning rate 400 mm/min, and overlap rate 50%. The thickness of TiC gradient coating is about 1.2 mm after the best process, and it is metallurgically bonded with the base layer. The microstructure of the most superficial layer is dendritic TiC and a small amount of Ni-based solid solution, the microstructure of the gradient layer is TiC+Ni-based solid solution, TiC content from the surface to the inside is in a gradient decrease, Ni-based solid solution content from the surface to the inside is in a gradient increase. The hardness of TiC coating decreases from 1968 HV0.2 to 240 HV0.2. In addition, the wear rate of the TiC coating is 1.757×10^-15m³/(N·m).

Key words: TiC coating, gradient layer, process parameters, frictional wear

中图分类号:

TG335.3

刘志玲, 常明丰, 韩贵生, 戴姣燕, 徐金富. 45钢激光熔覆TiC涂层的制备及性能[J]. 金属热处理, 2024, 49(3): 269-274.

Liu Zhiling, Chang Mingfeng, Han Guisheng, Dai Jiaoyan, Xu Jinfu. Preparation and properties of TiC coating on 45 steel by laser cladding[J]. Heat Treatment of Metals, 2024, 49(3): 269-274.

参考文献

[1]Zhuang Q Q, Zhang P L, Li M C, et al. Microstructure, wear resistance and oxidation behavior of Ni-Ti-Si coatings fabricated on Ti6Al4V by laser cladding[J]. Materials, 2017, 10(11): 1248-1262.
[2]张坚, 吴文妮, 赵龙志. 激光熔覆研究现状及发展趋势[J]. 热加工工艺, 2013, 42(6): 131-134, 139.
Zhang Jian, Wu Wenni, Zhao Longzhi. Research progress and development trend of laser cladding[J]. Hot Working Technology, 2013, 42(6): 131-134, 139.
[3]Guo C, Chen J, Zhou J, et al. Effects of WC-Ni content on microstructure and wear resistance of laser cladding Ni-based alloys coating[J]. Surface and Coating Technology, 2012, 206(8/9): 2064-2071.
[4]Barbosa M, Bischoff R, Strauβ W, et al. Less CO₂ and fine dust emissions in automotive: High-power laser cladding as a cost-effective rotor coating solution[J]. Photonies Views, 2020, 17(4): 46-49.
[5]王志东, 张佳豪, 王明静, 等. 激光熔覆TiC增强镍基熔覆层的微观组织与耐磨性研究[J]. 矿冶工程, 2023, 43(1): 137-140.
Wang Zhidong, Zhang Jiahao, Wang Mingjing, et al. Microstructure and wear resistance of TiC reinforced Ni-based coating by laser cladding[J]. Mining and Metallurgical Engineering, 2023, 43(1): 137-140.
[6]李传强, 陈少克. 45钢表面激光熔覆Ni/TiC性能研究[J]. 装备制造技术, 2011(8): 20-22.
Li Chuanqiang, Chen Shaoke. Research on properties of Ni/TiC on 45 steel surface preparaed by laser cladding[J]. Equipment Manufacturing Technology, 2011(8): 20-22.
[7]程才, 师文庆, 吴腾, 等. TiC含量对激光熔覆Fe基涂层形貌与力学性能研究[J]. 激光与光电子学进展, 2023, 60 (19): 158-163.
Cheng Cai, Shi Wenqing, Wu Teng, et al. Study of the effect of TiC content on the morphology and mechanical properties of laser cladding Fe-base coatings[J]. Laser and Optoelectronics Progress, 2023, 60 (19): 158-163.
[8]张蕾涛, 李海涛, 贾润楠, 等. 激光重熔Ni60/50%WC复合涂层的制备及性能[J]. 金属热处理, 2021, 46(5): 229-234.
Zhang Leitao, Li Haitao, Jia Runnan, et al. Preparation and properties of laser remelted Ni60/50%WC composite coating[J]. Heat Treatment of Metals, 2021, 46(5): 229-234.
[9]张蕾涛. 45钢激光熔覆Ni60/WC涂层的裂纹成因及控制研究[D]. 西安: 长安大学, 2021.
[10]周建波, 张晶, 张蕾涛, 等. 激光工艺参数对Ni60/WC涂层裂纹率及组织的影响[J]. 金属热处理, 2021, 46(9): 252-257.
Zhou Jianbo, Zhang Jing, Zhang Leitao, et al. Effect of laser process parameters on crack rate and microstructure of Ni60/WC clad coating[J]. Heat Treatment of Metals, 2021, 46(9): 252-257.
[11]崔岗, 韩彬, 崔娜, 等. 扫描速度对激光熔覆Ni基WC合金涂层组织与性能的影响[J]. 中国表面工程, 2014, 27(4): 82-88.
Cui Gang, Han Bin, Cui Na, et al. Effect of scanning speed on microstructure and properties of laser cladding Ni-based WC alloy coating[J]. China Surface Engineering, 2014, 27(4): 82-88.
[12]栾景飞. 工艺因素对激光熔敷层裂纹率的影响[J]. 材料科学与工程, 2002(3): 349-353.
Luan Jingfei. Effect of processing factors on crack ration of laser clad layer[J]. Journal of Materials Science and Engineering, 2002(3): 349-353.
[13]Liu H M, Li M B, Qin X P, et al. Numerical simulation and experimental analysis of wide-beam laser cladding[J]. The International Journal of Advanced Manufacturing Technology, 2019, 100: 237-249.
[14]杨光, 王向明, 王维, 等. 激光熔覆制备TiC颗粒增强涂层的组织和性能[J]. 红外与激光工程, 2014, 43(3): 795-799.
Yang Guang, Wang Xiangming, Wang Wei, et al. Microstructure and property of laser cladding TiC reinforced composition coating[J]. Infrared and Laser Engineering, 2014, 43(3): 795-799.
[15]曹金龙, 杨学锋, 王守仁, 等. 45钢表面激光熔覆Ni60-TiC陶瓷涂层的耐磨耐蚀性能[J]. 稀有金属材料与工程, 2020, 49(2): 611-617.
Cao Jinlong, Yang Xuefeng, Wang Shouren, et al. Wear and corrosion resistance of laser-melted Ni60-TiC ceramic coating on 45 steel surface[J]. Rare Metal Materials and Engineering, 2020, 49(2): 611-617.

45钢激光熔覆TiC涂层的制备及性能

Preparation and properties of TiC coating on 45 steel by laser cladding

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